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We computationally demonstrate a new method for coherently controlling the rotation-axis direction in asymmetric top molecules with an optical centrifuge. Appropriately chosen electric-field strengths and the centrifuge's acceleration rate…

Chemical Physics · Physics 2021-06-16 Emil J. Zak , Andrey Yachmenev , Jochen Küpper

The second order optical response of centrosymmetric materials manifests itself mostly at their surface, being strongly suppressed in their bulk. However, the overall surface response is also suppressed in nanoparticles with a…

Optics · Physics 2021-09-22 Raksha Singla , W. Luis Mochán

Both the translational diffusion coefficient $D$ and the electrophoretic mobility $\mu$ of a short rod-like molecule (such as dsDNA) that is being pulled towards a nanopore by an electric field should depend on its orientation. Since a…

Biological Physics · Physics 2020-06-25 Le Qiao , Gary W. Slater

Globally optimal solution describing a phase conjugated field of Raman scattering on the resonant $B\gets X$ transition of iodine $I_2$ is studied. Maximum optical coherence is found as a top eigenvalue problem. A reversibility theorem has…

Optics · Physics 2009-09-29 V. M. Akulin , V. A. Dubovitskii , A. M. Dykhne , A. G. Rudavets

We present a general theory of liquid crystals under inhomogeneous electric field in a Ginzburg-Landau scheme. The molecular orientation can be deformed by electric field when the dielectric tensor is orientation-dependent. We then…

Soft Condensed Matter · Physics 2009-11-11 Lionel Foret , Akira Onuki

Observational studies of magnetic fields are vital as magnetic fields play a crucial role in various astrophysical processes, including star formation, accretion of matter, transport processes (e.g., transport of heat), and cosmic rays. We…

Astrophysics of Galaxies · Physics 2015-06-04 Huirong Yan , A. Lazarian

In recent years it became possible to align molecules in free space using ultrashort laser pulses. Here we explore two schemes for controlling molecule-surface scattering process, which are based on the laser-induced molecular alignment. In…

Chemical Physics · Physics 2015-05-28 Yuri Khodorkovsky , J. R. Manson , Ilya Sh. Averbukh

When an electromagnetic wave is obliquely incident on an inhomogeneous high density plasma, it will be absorbed resonantly as long as it is polarized in the plane of incidence and has an electric field component along the plasma electron…

Plasma Physics · Physics 2009-01-27 S J Pestehe , M Mohammadnejad

We numerically examine a system of monodisperse self-propelled particles interacting with each other via simple steric forces and aligning torques moving through a periodic array of obstacles. Without obstacles, this system shows a…

Soft Condensed Matter · Physics 2025-02-27 Daniel Canavello , C. Reichhardt , C. J. O Reichhardt , Clécio C. de Souza Silva

We theoretically investigate optical absorption of molecules embedded nearby metallic antennas by using discrete dipole approximation method. It is found that the spectral peak of the absorption is shifted due to the radiation-induced…

Mesoscale and Nanoscale Physics · Physics 2015-10-01 Yoshiki Osaka , Nobuhiko Yokoshi , Hajime Ishihara

The orientation of luminescent molecules in organic light-emitting diodes (OLEDs) strongly influences device performance. However, our understanding of the factors controlling emitter orientation is limited as current measurements only…

A new mechanism is described, analyzed and visualized, for the dissipation of suprathermal rotation energy of molecules in magnetic fields, a necessary condition for their alignment. It relies upon the Lorentz force perturbing the motion of…

Astrophysics of Galaxies · Physics 2016-02-17 Renaud Papoular

A moderately intense $450$ fs laser pulse is used to create rotational wave packets in gas phase $\rm{I_2}$ molecules. The ensuing time-dependent alignment, measured by Coulomb explosion imaging with a delayed probe pulse, exhibits the…

We study polar molecules with long-range dipole-dipole interactions confined to move on a two-leg ladder for different orientations of the molecular dipole moments with respect to the ladder. Matrix product states are employed to calculate…

Quantum Gases · Physics 2014-01-14 Søren Gammelmark , Nikolaj Thomas Zinner

When circularly polarized light is scattered from a rotating target, a rotational Doppler shift (RDS) emerges from an exchange of angular momentum between the spinning object and the electromagnetic field. Here, we used coherently spinning…

We consider optical properties of a gas of molecules that are brought to fast unidirectional spinning by a pulsed laser field. It is shown that a circularly polarized probe light passing through the medium inverts its polarization…

Optics · Physics 2015-06-17 Uri Steinitz , Yehiam Prior , Ilya Sh. Averbukh

We present a theoretical study of the mixed-field-orientation of asymmetric top molecules in tilted static electric field and non-resonant linearly polarized laser pulse by solving the time-dependent Schr\"odinger equation. Within this…

Chemical Physics · Physics 2016-12-21 Juan J. Omiste , Rosario González-Férez

Dimers of carbon disulfide (CS$_2$) molecules embedded in helium nanodroplets are aligned using a moderately intense, 160ps, non-resonant, circularly polarized laser pulse. It is shown that the intermolecular carbon-carbon (C-C) axis aligns…

Chemical Physics · Physics 2019-04-10 James D. Pickering , Benjamin Shepperson , Lars Christiansen , Henrik Stapelfeldt

Sub-cycle electromagnetic pulses in the Terahertz region are considered to be one of the best ways to orient molecules. The simplest option corresponds to half-cycles pulses in the sudden regime, for which the pulse duration is much shorter…

Chemical Physics · Physics 2012-05-14 Juan Ortigoso

By means of non-adiabatic quantum molecular dynamics it is shown, that the amount of energy deposited into $\text{C}_{60}$ by a short laser field strongly depends on the molecular orientation with respect to the laser polarization…

Atomic and Molecular Clusters · Physics 2015-06-18 M. Fischer , J. Handt , G. Seifert , R. Schmidt
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