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We extend a model of two-center interference to include the superposition of opposite orientations in aligned polar molecules. We show that the position of the minimum in the harmonic spectrum from both aligned and oriented CO depends…

Atomic Physics · Physics 2011-09-07 Adam Etches , Mette B. Gaarde , Lars Bojer Madsen

We propose an array of ultracold polar molecules as a platform to study alignment transport between molecules. We envision a polar molecule being aligned with an intense off-resonant laser field whose alignment migrates to a nearby molecule…

Chemical Physics · Physics 2024-02-27 Jonathan Smucker , Jesus Pérez-Ríos

Absorption spectra of small molecular aggregates (oligomers) are considered. The dipole-dipole interaction between the monomers leads to shifts of the oligomer spectra with respect to the monomer absorption. The line-shapes of monomer as…

Chemical Physics · Physics 2011-02-03 Jan Roden , Walter T. Strunz , Alexander Eisfeld

The interaction between an atom and the quantized electromagnetic field depends on the position of the atom. Then the atom experiences a force which is the minus gradient of this interaction. Through the Heisenberg equations of motion and…

Quantum Physics · Physics 2021-11-11 Li Ge

We study the angular deflection of the circular polarized components of a linearly polarized probe field in a weakly birefringent atomic system in tripod configuration. A spatially inhomogeneous control field incident obliquely onto an…

Quantum Physics · Physics 2016-12-06 Pardeep Kumar , Shubhrangshu Dasgupta

We study the interaction of a light beams carrying angular momentum with a single, trapped and well localized ion. We provide a detailed calculation of selection rules and excitation probabilities for quadrupole transitions. The results…

Atomic Physics · Physics 2012-04-24 Christian Tomás Schmiegelow , Ferdinand Schmidt-Kaler

We investigate the angle-resolved photoelectron spectra from laser-assisted photoionization for helium and neon atoms using an \textit{ab initio} method based on time-dependent surface flux and configuration interaction singles. We find…

Atomic Physics · Physics 2020-08-26 Mattias Bertolino , David Busto , Felipe Zapata , Jan Marcus Dahlström

Generalizing the mode-coupling theory for ideal liquid-glass transitions, equations of motion are derived for the correlation functions describing the glassy dynamics of a diatomic probe molecule immersed in a simple glass-forming system.…

Soft Condensed Matter · Physics 2009-10-31 S. -H. Chong , W. Gotze , A. P. Singh

We theoretically investigate the interference effect of high-order harmonics generated from molecules at different alignment angles. It is shown that the interference of the harmonic emissions from molecules aligned at different angles can…

Optics · Physics 2015-02-27 Meiyan Qin , Xiaosong Zhu , Yang Li , Qingbin Zhang , Pengfei Lan , Peixiang Lu

Following excitation by a strong ultra-short laser pulse, molecules develop coordinated rotational motion, exhibiting transient alignment along the direction of the laser electric field, followed by periodic full and fractional revivals…

Quantum Physics · Physics 2007-05-23 Sharly Fleischer , Ilya. Sh. Averbukh , Yehiam Prior

We analyze theoretically the interplay between the torsional and the rotational motion of an aligned biphenyl-like molecule. To do so, we consider a transition between two electronic states with different internal torsional potentials,…

Chemical Physics · Physics 2017-02-08 Juan J. Omiste , Lars Bojer Madsen

We develop two novel models of the H$_2^+$ molecule and its isotopes from which we assess quantum-mechanically and semi-classically whether the molecule anti-aligns with the field in the first excited electronic state. The results from both…

Chemical Physics · Physics 2021-02-24 Sebastián Carrasco , José Rogan , Juan Alejandro Valdivia , Ignacio Sola

Observational studies of magnetic fields are crucial. We introduce a process "ground state alignment" as a new way to determine the magnetic field direction in diffuse medium. The alignment is due to anisotropic radiation impinging on the…

Astrophysics of Galaxies · Physics 2013-02-15 Huirong Yan , A. Lazarian

The relation between high-harmonic spectra and the geometry of the molecular orbitals in position and momentum space is investigated. In particular we choose two isoelectronic pairs of homonuclear and heteronuclear molecules, such that the…

Atomic Physics · Physics 2015-05-19 B. B. Augstein , C. Figueira de Morisson Faria

The properties of molecule-optical elements such as lenses or prisms based on the interaction of molecules with optical fields depend in a crucial way on the molecular quantum state and its alignment created by the optical field. However,…

Chemical Physics · Physics 2016-08-02 Lee Yeong Kim , Ju Hyeon Lee , Hye Ah Kim , Sang Kyu Kwak , Bretislav Friedrich , Bum Suk Zhao

Supersonic beams of polar molecules are deflected using inhomogeneous electric fields. The quantum-state selectivity of the deflection is used to spatially separate molecules according to their quantum state. A detailed analysis of the…

We introduce a new optical tool - a "two-dimensional optical centrifuge", capable of aligning molecules in extreme rotational states. Unlike the conventional centrifuge, which confines the molecules in the plane of their rotation, its…

Chemical Physics · Physics 2016-05-18 A. A. Milner , A. Korobenko , V. Milner

When light is passed through aberrated optical systems, the resulting degradation in amplitude and phase has deleterious effects, for example, on resolution in imaging, spot sizes in focussing, and the beam quality factor of the output…

Optics · Physics 2022-01-19 Wagner Tavares Buono , Jacuqueline Tau , Isaac Nape , Andrew Forbes

The rich information content of measurements in the molecular frame rather than the laboratory frame has motivated the development of several methods for aligning gas phase molecules in space. Even so, for asymmetric tops the problem of…

Atomic Physics · Physics 2016-11-23 Varun Makhija , Xiaoming Ren , Drue Gockel , Anh-Thu Le , Vinod Kumarappan

We demonstrate experimentally a method of varying the degree of directionality in laser-induced molecular rotation. To control the ratio between the number of clockwise and counter-clockwise rotating molecules (with respect to a fixed…

Chemical Physics · Physics 2021-05-05 Alexander A. Milner , Valery Milner