Related papers: Spectroscopic Interpretation: The High Vibrations …
We extract the dynamics implicit in an algebraic fitted model Hamiltonian for the hydrogen chromophore's vibrational motion in the molecule $CF_3CHFI$. The original model has 4 degrees of freedom, three positions and one representing…
We study the intramolecular vibrational energy redistribution (IVR) dynamics of an effective spectroscopic Hamiltonian describing the four coupled high frequency modes of CDBrClF. The IVR dynamics ensuing from nearly isoenergetic…
In this work we set up a model Hamiltonian to study the excited state quantum dynamics of 1,1-difluoroethylene, a molecule that has equivalent atoms exchanged by a torsional symmetry operation leading to equivalent minima on the potential…
A time dependent variational principle is used to dequantize a second order quadrupole boson Hamiltonian. The classical equations for the generalized coordinate and the constraint for angular momentum are quantized and then analytically…
We consider a one-dimensional optical lattice of three-dimensional Harmonic Oscillators which are loaded with neutral fermionic atoms trapped into two hyperfine states. By means of a standard variational coherent-state procedure, we derive…
We show that a vibrational interpretation and good U(5) symmetry are maintained for the majority of low-lying normal states in $^{110,112,114,116}$Cd isotopes, consistent with the empirical data. The observed deviations from this paradigm…
We study a general problem of the translational/rotational/vibrational/electronic dynamics of a diatomic molecule exposed to an interaction with an arbitrary external electromagnetic field. The theory developed in this paper is relevant to…
The aim of this article is a comprehensive description of normal modes of molecular vibrations. The starting point is chosen to be a general molecular system with separated center of mass and an arbitrary embedding of body-fixed axes. This…
Ultrafast laser excitation can trigger multiplex coherent dynamics in molecules. Here, we report attosecond transient absorption experiments addressing simultaneous probing of electronic and vibrational dynamics in a prototype molecule,…
We construct normalizable, semi-classical states for the previously proposed model of quantum gravity which is formulated as a spectral triple over holonomy loops. The semi-classical limit of the spectral triple gives the Dirac Hamiltonian…
The empirical spectra and $E2$ decay rates in $^{110,112,114,116}$Cd are shown to be consistent with a vibrational interpretation for low-lying normal states, coexisting with a single deformed $\gamma$-soft band of intruder states. The…
We study the translational motions of homonuclear diatomic molecules prepared in their ${}^3\Sigma$ electronic states, deeply bound vibrational states, and rotational states of well-defined parity. The trapping potential arises due to the…
The motion of metastable helium atoms travelling through a standing light wave is investigated with a semi-classical numerical model. The results of a calculation including the velocity dependence of the dipole force are compared with those…
We develop a density matrix formalism to describe coupled electron-nuclear dynamics. To this end we introduce an effective Hamiltonian formalism that describes electronic transitions and small (quantum) nuclear fluctuations along a…
A finite-dimensional pseudo-unitary framework is set up for describing the dynamics of free elementary particles in a purely relativistic quantum mechanical way. States of any individual particles or antiparticles are defined as suitably…
Multi-dimensional spectroscopy represents a particularly insightful tool for investigating the interplay of nuclear and electronic dynamics, which plays an important role in a number of photophysical processes and photochemical reactions.…
The dynamical algebra of the q-deformed harmonic oscillator is constructed. As a result, we find the free deformed Hamiltonian as well as the Hamiltonian of the deformed oscillator as a complicated, momentum dependent interaction…
We present an extension of the Hamiltonian of the two dimensional limit of the vibron model encompassing all possible interactions up to four-body operators. We apply this Hamiltonian to the modeling of the experimental bending spectrum of…
The quadrupole collective Hamiltonian, based on relativistic energy density functionals, is extended to include a pairing collective coordinate. In addition to quadrupole shape vibrations and rotations, the model describes pairing…
Analytical expressions for spectra and wave functions are derived for a Bohr Hamiltonian, describing the collective motion of deformed nuclei, in which the mass is allowed to depend on the nuclear deformation. Solutions are obtained for…