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Over the years, several schemes have been proposed to describe multireference systems with Kohn-Sham Density Functional Theory. Problematic is the combination of two aspects: the Kohn-Sham reference wavefunction is usually taken to be a…

Strongly Correlated Electrons · Physics 2019-08-01 Pablo Ramos , Michele Pavanello

The general procedure underlying Hartree-Fock and Kohn-Sham density functional theory calculations consists in optimizing orbitals for a self-consistent solution of the Roothaan-Hall equations in an iterative process. It is often ignored…

Chemical Physics · Physics 2017-03-16 Alain C. Vaucher , Markus Reiher

We study one-quasiproton excitations in the rare-earth region in the framework of the nuclear Density Functional Theory in the Skyrme-Hartree-Fock-Bogoliubov variant. The blocking prescription is implemented exactly, with the time-odd mean…

Nuclear Theory · Physics 2010-04-06 N. Schunck , J. Dobaczewski , J. McDonnell , J. More , W. Nazarewicz , J. Sarich , M. V. Stoitsov

The leading terms in the large-$R$ asymptotics of the functional of the one-electron reduced density matrix for the ground-state energy of the H$_2$ molecule with the internuclear separation $R$ is derived thanks to the solution of the…

Chemical Physics · Physics 2023-03-14 Jerzy Cioslowski , Christian Schilling , Rolf Schilling

Some general features of the spectrum of the Hartree-Fock-Bogoliubov equations are examined. Special attention is paid to the asymptotic behavior of the single quasiparticle wave functions (s.qp.w.fs.), matter density distribution and…

Nuclear Theory · Physics 2007-05-23 Aurel Bulgac

A set of hadronic equations of state derived from covariant density functional theory and constrained by terrestrial experiments, and astrophysical observations, in particular by the NICER experiment inferences is used to explore the…

Nuclear Theory · Physics 2023-08-22 Jia Jie Li , Armen Sedrakian , Fridolin Weber

A series of relativistic one-boson-exchange potentials for two-nucleon system, denoted as OBEP$\Lambda$, is constructed with a momentum cutoff $\Lambda$ ranging from $\infty$ to 2 fm$^{-1}$. These potentials are developed by simultaneous…

Nuclear Theory · Physics 2023-12-07 Chencan Wang , Sibo Wang , Hui Tong , Jinniu Hu , Jiangming Yao

We develop a systematic approach to construct energy functionals of the one-particle reduced density matrix (1RDM) for equilibrium systems at finite temperature. The starting point of our formulation is the grand potential $\Omega…

Other Condensed Matter · Physics 2018-11-20 Klaas J. H. Giesbertz , Anna-Maija Uimonen , Robert van Leeuwen

We consider circular particle motion under the action of an unspecified force in a static spherically symmetric spacetime. We derive the machinery that allows one to find the force acting on a circular particle and deduce whether its…

General Relativity and Quantum Cosmology · Physics 2026-03-30 Hryhorii Ovcharenko , O. B. Zaslavskii

We show that classical density functional theory can be based on the constrained search method [M. Levy, Proc. Natl. Acad. Sci. 76, 6062 (1979)]. From the Gibbs inequality one first derives a variational principle for the grand potential as…

Statistical Mechanics · Physics 2011-04-21 Wipsar Sunu Brams Dwandaru , Matthias Schmidt

The expression of the free energy density of a classical crystalline system as a gradient expansion in terms of a set of order parameters is developed using classical density functional theory. The goal here is to extend and complete an…

Statistical Mechanics · Physics 2009-11-11 James F. Lutsko

Density functional theory is a preferred microscopic method for calculation of nuclear properties over the whole nuclear chart. Besides ground-state properties, which are calculated by Hartree-Fock theory, nuclear excitations can be…

Nuclear Theory · Physics 2020-06-02 Anton Repko

The problem of stability of saturated and non-saturated ferromagnetism in the Hubbard model is considered in terms of the one-particle Green's functions. Approximations by Edwards and Hertz and some versions of the self-consistent…

Strongly Correlated Electrons · Physics 2009-11-07 V. Yu. Irkhin , A. V. Zarubin

Reconstructing a density of states or similar distribution from moments or continued fractions is an important problem in calculating the electronic and vibrational structure of defective or non-crystalline solids. For single bands a…

Strongly Correlated Electrons · Physics 2015-05-20 Roger Haydock , C. M. M. Nex

The quantum de Finetti theorem asserts that the k-body density matrices of a N-body bosonic state approach a convex combination of Hartree states (pure tensor powers) when N is large and k fixed. In this note we review a construction due to…

Mathematical Physics · Physics 2014-08-25 Mathieu Lewin , Phan Thành Nam , Nicolas Rougerie

We present the spectral analysis of a one-dimensional Hubbard model with a parabolic potential, using a real-space cluster perturbation theory (rCPT) designed to study spatially inhomogeneous electron systems with strong correlation. It is…

Strongly Correlated Electrons · Physics 2025-07-31 Kaito Matsuki , Chisa Hotta , Kenichi Asano

The Hohenberg-Kohn theorem of density-functional theory (DFT) is broadly considered the conceptual basis for a full characterization of an electronic system in its ground state by just the one-body particle density. In this Part~II of a…

We compute the ground-state properties of finite systems of neutrons in an external harmonic trap, interacting via the Minnesota potential, using the "exact-exchange" form of orbital-dependent density functional theory. We compare our…

Nuclear Theory · Physics 2011-07-28 Joaquín E. Drut , Lucas Platter

We present a novel route to constructing cost-efficient semi-empirical approximations for the non-additive kinetic energy in subsystem density functional theory. The developed methodology is based on the use of Slater determinants composed…

Chemical Physics · Physics 2025-01-13 Larissa Sophie Eitelhuber , Denis G. Artiukhin

Occupation numbers of natural orbitals capture the physics of strong electron correlations in momentum space. A Natural Orbital Density Functional Theory based on the antisymmetrized geminal product provides these occupation numbers and the…

Strongly Correlated Electrons · Physics 2014-05-06 B. Barbiellini