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For a previously published study of the titanium hcp (alpha) to omega (omega) transformation, a tight-binding model was developed for titanium that accurately reproduces the structural energies and electron eigenvalues from all-electron…

Materials Science · Physics 2008-07-24 D. R. Trinkle , M. D. Jones , R. G. Hennig , S. P. Rudin , R. C. Albers , J. W. Wilkins

Finite-temperature calculations are relevant for rationalizing material properties yet they are computationally expensive because large system sizes or long simulation times are typically required. Circumventing the need for performing many…

Using the model of hexagonal clusters we express the surface, curvature and Gauss curvature coefficients of the nuclear binding energy in terms of its bulk coefficient. Using the derived values of these coefficients and a single fitting…

Nuclear Theory · Physics 2020-12-22 V. V. Sagun , K. A. Bugaev , A. I. Ivanytskyi

The formal link between the linear combination of atomic orbitals approach to density functional theory and two-center Slater-Koster tight-binding models is used to derive an orthogonal $d$-band tight-binding model for iron with only two…

Materials Science · Physics 2015-03-19 Georg K. H. Madsen , Eunan J. McEniry , Ralf Drautz

A recent tight-binding scheme provides a method for extending the results of first principles calculations to regimes involving $10^2 - 10^3$ atoms in a unit cell. The method uses an analytic set of two-center, non-orthogonal tight-binding…

mtrl-th · Physics 2008-02-03 Michael J. Mehl , Dimitrios A. Papaconstantopoulos

In this paper we propose a tight-binding molecular dynamics with parameters fitted to first-principles calculations on the smaller clusters and with an environment correction, to be a powerful technique for studying large transition/noble…

Atomic and Molecular Clusters · Physics 2009-11-10 Mukul Kabir , Abhijit Mookerjee , A. K. Bhattacharya

Semi-Empirical Tight Binding (TB) is known to be a scalable and accurate atomistic representation for electron transport for realistically extended nano-scaled semiconductor devices that might contain millions of atoms. In this paper an…

Materials Science · Physics 2015-06-18 Ganesh Hegde , Michael Povolotskyi , Tillmann Kubis , Timothy Boykin , Gerhard Klimeck

The tight binding model is a minimal electronic structure model for molecular modelling and simulation. We show that the total energy in this model can be decomposed into site energies, that is, into contributions from each atomic site…

Numerical Analysis · Mathematics 2015-06-19 Huajie Chen , Christoph Ortner

In this work we have applied the recently formulated self-compressed inhomogeneous stabilized jellium model [M. Payami and T. Mahmoodi, Can. J. Phys. {\bf 89}, 967 (2011)] to describe the equilibrium electronic and geometric properties of…

Materials Science · Physics 2017-09-22 M. Payami , T. Mahmoodi

We report on the structures of aluminum hydrides derived from a tetrahedral aluminum Al4 cluster using ab initio quantum chemical calculation. Our calculation of binding energies of the aluminum hydrides reveals that stability of these…

Atomic and Molecular Clusters · Physics 2011-09-15 Kazuhide Ichikawa , Yuji Ikeda , Ayumu Wagatsuma , Kouhei Watanabe , Pawel Szarek , Akitomo Tachibana

A transferable tight-binding potential has been constructed for heteroatomic systems containing carbon and hydrogen. The electronic degree of freedom is treated explicitly in this potential using a small set of transferable parameters which…

chem-ph · Physics 2008-02-03 Yang Wang , C. H. Mak

In order to control and tailor the properties of nanodots, it is essential to separate the effects of quantum confinement from those due to the surface, and to gain insight into the influence of preparation conditions on the dot physical…

Materials Science · Physics 2009-10-31 Laurent Pizzagalli , Giulia Galli , John E. Klepeis , Francois Gygi

Simple application of the Einstein model combined with the elastic description of solid state is developed. The frequency of quantum oscillators has been assumed as volume dependent and, furthermore, elastic energy terms of static character…

Statistical Mechanics · Physics 2013-04-09 Tadeusz Balcerzak , Karol Szałowski , Michal Jaščur

The low-energy spectra, electric quadrupole transitions and moments for the germanium isotopes are studied in the formalism of the IBM-2 with configuration mixing. The calculated observables reproduce well the available experimental…

Nuclear Theory · Physics 2007-05-23 E. Padilla-Rodal , O. Castanos , R. Bijker , A. Galindo-Uribarri

In this work, transferable empirical tight binding parameters of strained group IV and III-V semiconductors are generated from ab-initio calculations. The empirical tight binding parameters show good transferability when applied to strained…

Materials Science · Physics 2015-04-28 Yaohua P. Tan , Michael Povolotskyi , Tillmann Kubis , Timothy B. Boykin , Gerhard Klimeck

We construct a generalized transfer matrix corresponding to noninteracting tight-binding lattice models, which can subsequently be used to compute the bulk bands as well as the edge states. Crucially, our formalism works even in cases where…

Other Condensed Matter · Physics 2016-04-11 Vatsal Dwivedi , Victor Chua

A detailed simple model is applied to study a metallic cluster. It is assumed that the ions and delocalized electrons are distributed randomly throughout the cluster. The delocalized electrons are assumed to be degenerate. A spherical ball…

Materials Science · Physics 2011-03-01 Yuri Kornyushin

The capacities of various interatomic potentials available for elemental germanium, with the scope to choose the potential suitable for the modeling of germanene (2D germanium) allotropes were investigated. Structural and mechanical…

Materials Science · Physics 2023-11-14 Marcin Maździarz

The ground state geometries of some small clusters have been obtained via ab initio molecular dynamical simulations by employing density based energy functionals. The approximate kinetic energy functionals that have been employed are the…

Condensed Matter · Physics 2009-10-28 Dinesh Nehete , Vaishali Shah , D. G. Kanhere

The bulk properties (lattice constants, bulk moduli, and cohesive energies) of alkali, alkaline-earth, and transition metals are studied within the framework of the recently developed meta-GGA (meta-Generalized Gradient Approximation)…

Materials Science · Physics 2018-11-14 Subrata Jana , Kedar Sharma , Prasanjit Samal
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