Related papers: Boltzmann entropy and chaos in a large assembly of…
To illustrate Boltzmann's construction of an entropy function that is defined for a microstate of a macroscopic system, we present here the simple example of the free expansion of a one dimensional gas of non-interacting point particles.…
On a fine grained scale the Gibbs entropy of an isolated system remains constant throughout its dynamical evolution. This is a consequence of Liouville's theorem for Hamiltonian systems and appears to contradict the second law of…
In this work we study the evolution of Boltzmann's entropy in the context of free expansion of a one dimensional interacting gas inside a box. Boltzmann's entropy is defined for single microstates and is given by the phase-space volume…
We consider several low--dimensional chaotic maps started in far-from-equilibrium initial conditions and we study the process of relaxation to equilibrium. In the case of conservative maps the Boltzmann-Gibbs entropy S(t) increases linearly…
Finding reduced models of spatially-distributed chemical reaction networks requires an estimation of which effective dynamics are relevant. We propose a machine learning approach to this coarse graining problem, where a maximum entropy…
We study the time evolution of the Boltzmann entropy of a microstate during the non-equilibrium free expansion of a one-dimensional quantum ideal gas. This quantum Boltzmann entropy, $S_B$, essentially counts the "number" of independent…
The past two decades have seen a revolution in statistical physics, generalizing it to apply to systems of arbitrary size, evolving while arbitrarily far from equilibrium. Many of these new results are based on analyzing the dynamics of the…
The Boltzmann kinetic equation is obtained from an integro-differential master equation that describes a stochastic dynamics in phase space of an isolated thermodynamic system. The stochastic evolution yields a generation of entropy,…
The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…
Observational entropy -- a quantity that unifies Boltzmann's entropy, Gibbs' entropy, von Neumann's macroscopic entropy, and the diagonal entropy -- has recently been argued to play a key role in a modern formulation of statistical…
The concept of entropy connects the number of possible configurations with the number of variables in large stochastic systems. Independent or weakly interacting variables render the number of configurations scale exponentially with the…
We develop the framework of classical Observational entropy, which is a mathematically rigorous and precise framework for non-equilibrium thermodynamics, explicitly defined in terms of a set of observables. Observational entropy can be seen…
A large class of technically non-chaotic systems, involving scatterings of light particles by flat surfaces with sharp boundaries, is nonetheless characterized by complex random looking motion in phase space. For these systems one may…
By considering general Markov stochastic dynamics and its coarse-graining, we study the framework of stochastic thermodynamics for the original and reduced descriptions corresponding to different scales. We are especially concerned with the…
We investigate the time evolution of the Boltzmann entropy of a dilute gas of N particles, N>>1, as it undergoes a free expansion doubling its volume. The microstate of the system, a point in the 4N dimensional phase space, changes in time…
Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…
Many experimentally relevant systems are quasi-one-dimensional, consisting of nearly decoupled chains. In these systems, there is a natural separation of scales between the strong intra-chain interactions and the weak interchain coupling.…
Entropy, its production, and its change in a dynamical system can be understood from either a fully stochastic dynamic description or from a deterministic dynamics exhibiting chaotic behavior. By taking the former approach based on the…
We study the time evolution of eleven microscopic entropy definitions (of Boltzmann-surface, Gibbs-volume, canonical, coarse-grained-observational, entanglement and diagonal type) and three microscopic temperature definitions (based on…
Starting from a many-body classical system governed by a trace-form entropy we derive, in the stochastic quantization picture, a family of non linear and non-Hermitian Schroedinger equations describing, in the mean filed approximation, a…