English

Boltzmann entropy of a freely expanding quantum ideal gas

Statistical Mechanics 2024-02-14 v1 Quantum Gases Quantum Physics

Abstract

We study the time evolution of the Boltzmann entropy of a microstate during the non-equilibrium free expansion of a one-dimensional quantum ideal gas. This quantum Boltzmann entropy, SBS_B, essentially counts the "number" of independent wavefunctions (microstates) giving rise to a specified macrostate. It generally depends on the choice of macrovariables, such as the type and amount of coarse-graining, specifying a non-equilibrium macrostate of the system, but its extensive part agrees with the thermodynamic entropy in thermal equilibrium macrostates. We examine two choices of macrovariables: the UU-macrovariables are local observables in position space, while the ff-macrovariables also include structure in momentum space. For the quantum gas, we use a non-classical choice of the ff-macrovariables. For both choices, the corresponding entropies sBfs_B^f and sBUs_B^U grow and eventually saturate. As in the classical case, the growth rate of sBfs_B^f depends on the momentum coarse-graining scale. If the gas is initially at equilibrium and is then released to expand to occupy twice the initial volume, the per-particle increase in the entropy for the ff-macrostate, ΔsBf\Delta s_B^f, satisfies log2ΔsBf2log2\log{2}\leq\Delta s_B^f\leq 2\log{2} for fermions, and 0ΔsBflog20\leq\Delta s_B^f\leq\log{2} for bosons. For the same initial conditions, the change in the entropy ΔsBU\Delta s_B^U for the UU-macrostate is greater than ΔsBf\Delta s_B^f when the gas is in the quantum regime where the final stationary state is not at thermal equilibrium.

Keywords

Cite

@article{arxiv.2303.12330,
  title  = {Boltzmann entropy of a freely expanding quantum ideal gas},
  author = {Saurav Pandey and Junaid Majeed Bhat and Abhishek Dhar and Sheldon Goldstein and David A. Huse and Manas Kulkarni and Anupam Kundu and Joel L. Lebowitz},
  journal= {arXiv preprint arXiv:2303.12330},
  year   = {2024}
}

Comments

31 pages, 14 figures