Boltzmann entropy of a freely expanding quantum ideal gas
Abstract
We study the time evolution of the Boltzmann entropy of a microstate during the non-equilibrium free expansion of a one-dimensional quantum ideal gas. This quantum Boltzmann entropy, , essentially counts the "number" of independent wavefunctions (microstates) giving rise to a specified macrostate. It generally depends on the choice of macrovariables, such as the type and amount of coarse-graining, specifying a non-equilibrium macrostate of the system, but its extensive part agrees with the thermodynamic entropy in thermal equilibrium macrostates. We examine two choices of macrovariables: the -macrovariables are local observables in position space, while the -macrovariables also include structure in momentum space. For the quantum gas, we use a non-classical choice of the -macrovariables. For both choices, the corresponding entropies and grow and eventually saturate. As in the classical case, the growth rate of depends on the momentum coarse-graining scale. If the gas is initially at equilibrium and is then released to expand to occupy twice the initial volume, the per-particle increase in the entropy for the -macrostate, , satisfies for fermions, and for bosons. For the same initial conditions, the change in the entropy for the -macrostate is greater than when the gas is in the quantum regime where the final stationary state is not at thermal equilibrium.
Keywords
Cite
@article{arxiv.2303.12330,
title = {Boltzmann entropy of a freely expanding quantum ideal gas},
author = {Saurav Pandey and Junaid Majeed Bhat and Abhishek Dhar and Sheldon Goldstein and David A. Huse and Manas Kulkarni and Anupam Kundu and Joel L. Lebowitz},
journal= {arXiv preprint arXiv:2303.12330},
year = {2024}
}
Comments
31 pages, 14 figures