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To illustrate Boltzmann's construction of an entropy function that is defined for a microstate of a macroscopic system, we present here the simple example of the free expansion of a one dimensional gas of non-interacting point particles.…

Statistical Mechanics · Physics 2022-09-20 Subhadip Chakraborti , Abhishek Dhar , Sheldon Goldstein , Anupam Kundu , Joel L. Lebowitz

In this work we study the evolution of Boltzmann's entropy in the context of free expansion of a one dimensional interacting gas inside a box. Boltzmann's entropy is defined for single microstates and is given by the phase-space volume…

Statistical Mechanics · Physics 2023-03-29 Subhadip Chakraborti , Abhishek Dhar , Anupam Kundu

We investigate the time evolution of the Boltzmann entropy of a dilute gas of N particles, N>>1, as it undergoes a free expansion doubling its volume. The microstate of the system, a point in the 4N dimensional phase space, changes in time…

Statistical Mechanics · Physics 2024-10-08 P. L. Garrido , S. Goldstein , D. A. Huse , J. L. Lebowitz

We investigate, via computer simulations, the time evolution of the (Boltzmann) entropy of a dense fluid not in local equilibrium. The macrovariables $M$ describing the system are the (empirical) particle density $f=\{f(\un{x},\un{v})\}$…

Statistical Mechanics · Physics 2009-11-10 P. L. Garrido , S. Goldstein , J. L. Lebowitz

We introduce a high dimensional symplectic map, modeling a large system consisting of weakly interacting chaotic subsystems, as a toy model to analyze the interplay between single-particle chaotic dynamics and particles interactions in…

Chaotic Dynamics · Physics 2011-11-10 Massimo Falcioni , Luigi Palatella , Simone Pigolotti , Lamberto Rondoni , Angelo Vulpiani

Boltzmann defined the entropy of a macroscopic system in a macrostate $M$ as the $\log$ of the volume of phase space (number of microstates) corresponding to $M$. This agrees with the thermodynamic entropy of Clausius when $M$ specifies the…

Statistical Mechanics · Physics 2009-11-10 S. Goldstein , Joel L. Lebowitz

We consider an isolated system in an arbitrary state and provide a general formulation using first principles for an additive and non-negative statistical quantity that is shown to reproduce the equilibrium thermodynamic entropy of the…

Chemical Physics · Physics 2013-04-18 P. D. Gujrati

A way to construct Boltzmann entropy, i.e., the entropy as a function of a microscopic pure state, for quantum field systems is proposed. Operators that shift the field in wavevector space are used in the construction. By employing an…

Statistical Mechanics · Physics 2020-03-25 Kyo Yoshida

Increasing the number $N$ of elements of a system typically makes the entropy to increase. The question arises on {\it what particular entropic form} we have in mind and {\it how it increases} with $N$. Thermodynamically speaking it makes…

Statistical Mechanics · Physics 2009-11-11 Constantino Tsallis

Quantum turbulence deals with the phenomenon of turbulence in quantum fluids, such as superfluid helium and trapped Bose-Einstein condensates (BECs). Although much progress has been made in understanding quantum turbulence, several…

Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…

General Physics · Physics 2009-11-13 David Sands

We consider the ideal Fermi gas of indistinguishable particles without spin but with electric charge, confined to a Euclidean plane $\mathbb R^2$ perpendicular to an external constant magnetic field of strength $B>0$. We assume this…

Mathematical Physics · Physics 2023-03-01 Hajo Leschke , Alexander V. Sobolev , Wolfgang Spitzer

In this paper we obtain an analytical solution of the relativistic Boltzmann equation under the relaxation time approximation that describes the out-of-equilibrium dynamics of a radially expanding massless gas. This solution is found by…

High Energy Physics - Phenomenology · Physics 2016-01-06 Jorge Noronha , Gabriel S. Denicol

We take the view that the standard von Neumann definition, in which the entropy $S^{vN}$ of a pure state is zero, is in evident conflict with the statement of the second law that the entropy of the universe $S_{univ}$ increases in…

Quantum Physics · Physics 2018-10-25 George L. Barnes , Phillip C. Lotshaw , Michael E. Kellman

A thermodynamic system of non-interacting quantum particles changes its statistical distribution formulas if there is a universal limitation for the size of energetic quantum leaps (magnitude of quantum leaps smaller than Planck energy). By…

General Relativity and Quantum Cosmology · Physics 2015-03-17 Rainer Collier

Observational entropy -- a quantity that unifies Boltzmann's entropy, Gibbs' entropy, von Neumann's macroscopic entropy, and the diagonal entropy -- has recently been argued to play a key role in a modern formulation of statistical…

Quantum Physics · Physics 2026-03-24 Teruaki Nagasawa , Kohtaro Kato , Eyuri Wakakuwa , Francesco Buscemi

Regardless of studies and debates over a century, the statistical origin of the second law of thermodynamics still remains illusive. One essential obstacle is the lack of a proper theoretical formalism for non-equilibrium entropy. Here I…

Statistical Mechanics · Physics 2017-10-18 Xiangjun Xing

We develop the framework of classical Observational entropy, which is a mathematically rigorous and precise framework for non-equilibrium thermodynamics, explicitly defined in terms of a set of observables. Observational entropy can be seen…

Statistical Mechanics · Physics 2020-09-09 Dominik Šafránek , Anthony Aguirre , J. M. Deutsch

This paper generalizes the entropy maximization problem leading to the Boltzmann-Gibbs distribution through the nonadditive entropy $S_{q,s}(p)=k_{s}\sum^{W}_{i\geq1}p_{i}\ln_{q}1/p_{i}$, $q\in(0,1)$, which is a rescaled version of $S_{q}$…

Mathematical Physics · Physics 2025-12-02 Leandro Lyra Braga Dognini

The most rigorous physical description of non-equilibrium gas dynamics is rooted in the numerical solution of the Boltzmann equation. Yet, the large number of degrees of freedom and the wide range of both spatial and temporal scales render…

Computational Physics · Physics 2024-10-25 Anthony Chang , Narendra Singh , Marco Panesi
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