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We discuss the thermodynamics of closed quantum systems driven out of equilibrium by a change in a control parameter and undergoing a unitary process. We compare the work actually done on the system with the one that would be performed…

Quantum Physics · Physics 2015-01-20 F. Plastina , A. Alecce , T. J. G. Apollaro , G. Falcone , G. Francica , F. Galve , N. Lo Gullo , R. Zambrini

Using the quasi-equilibrium Helmholtz energy (qHE), defined as the thermodynamic work in a quasi-static process, we investigate the thermal properties of both an isothermal process and a transition process between the adiabatic and…

Statistical Mechanics · Physics 2022-07-06 Shoki Koyanagi , Yoshitaka Tanimura

Adiabatic (or reversible) processes are the key concept unifying our understanding of thermodynamics and dynamical systems. Reversibility in the thermodynamic sense is understood as entropy-preserving processes, such as in the idealized…

Quantum Physics · Physics 2026-02-27 Rohan Banerjee , Shahyad Khamnei , Anatoli Polkovnikov , Stewart Morawetz

The purpose of this work is to discuss recent progress in deriving the fundamental laws of thermodynamics (0th, 1st and 2nd-law) from nonequilibrium quantum statistical mechanics. Basic thermodynamic notions are clarified and different…

Mathematical Physics · Physics 2007-05-23 Walid K. Abou Salem

We study driven finite quantum systems in contact with a thermal reservoir in the regime in which the system changes slowly in comparison to the equilibration time. The associated isothermal adiabatic theorem allows us to control the full…

Mathematical Physics · Physics 2016-09-22 Tristan Benoist , Martin Fraas , Vojkan Jaksic , Claude-Alain Pillet

Quantum thermodynamics aims at investigating both the emergence and the limits of the laws of thermodynamics from a quantum mechanical microscopic approach. In this scenario, thermodynamic processes with no heat exchange, namely, adiabatic…

A process, carried out in a stepwise manner, becomes quasi-static when the number of intermediate steps tends to infinity. Usually, the net entropy production approaches zero under this limiting condition. Hence, such cases are termed…

Chemical Physics · Physics 2009-11-30 Debasis Mukhopadhyay , Kamal Bhattacharyya

We explore the thermodynamics of quantum processes (quantum channels) by axiomatically introducing the free energy for channels, defined via the quantum relative entropy with an absolutely thermal channel whose fixed output is in…

Quantum Physics · Physics 2026-01-23 Himanshu Badhani , Dhanuja G. S. , Siddhartha Das

The evolution of a driven quantum system is said to be adiabatic whenever the state of the system stays close to an instantaneous eigenstate of its time-dependent Hamiltonian. The celebrated quantum adiabatic theorem ensures that such pure…

Quantum Physics · Physics 2021-10-04 Nikolai Il`in , Anastasia Aristova , Oleg Lychkovskiy

An attempt toward the operational formulation of quantum thermodynamics is made by employing the recently proposed operations forming positive operator-valued measures for generating thermodynamic processes. The quantity of heat as well as…

Statistical Mechanics · Physics 2015-06-04 Sumiyoshi Abe , Yuki Aoyaghi

It is a central question in quantum thermodynamics to determine how irreversible is a process that transforms an initial state $\rho$ to a final state $\sigma$, and whether such irreversibility can be thought of as a useful resource. For…

Quantum Physics · Physics 2018-08-09 Álvaro M. Alhambra , Stephanie Wehner , Mark M. Wilde , Mischa P. Woods

The second law of thermodynamics for adiabatic operations -- constraints on state transitions in closed systems under external control -- is one of the fundamental principles of thermodynamics. On the other hand, it is recently established…

Statistical Mechanics · Physics 2026-02-09 Yuuya Chiba , Yasushi Yoneta , Ryusuke Hamazaki , Akira Shimizu

The relationship between thermodynamics and statistical physics is valid in the thermodynamic limit - when the number of particles becomes very large. Here, we study thermodynamics in the opposite regime - at both the nano scale, and when…

Quantum Physics · Physics 2014-10-28 Michał Horodecki , Jonathan Oppenheim

A model computational quantum thermodynamic network is constructed with two variable temperature baths coupled by a linker system, with an asymmetry in the coupling of the linker to the two baths. It is found in computational simulations…

Statistical Mechanics · Physics 2021-11-10 Phillip C. Lotshaw , Michael E. Kellman

We investigate a quasi-adiabatic thermal process for preparing finite-temperature ensembles in the thermodynamic limit. The process gradually transforms a thermal ensemble of a noninteracting system into that of an interacting system of…

Statistical Mechanics · Physics 2026-05-12 Tatsuhiko Shirai

We experimentally realize quasistatic adiabatic processes using a single optically-trapped micro- sphere immersed in water whose effective temperature is controlled by an external random electric field. A full energetic characterization of…

Statistical Mechanics · Physics 2015-06-03 Ignacio A. Martínez , Édgar Roldán , Luis Dinis , Dmitri Petrov , Raúl A. Rica

Operational quantum stochastic thermodynamics is a recently proposed theory to study the thermodynamics of open systems based on the rigorous notion of a quantum stochastic process or quantum causal model. In there, a stochastic trajectory…

Quantum Physics · Physics 2020-03-04 Philipp Strasberg

There is evidence that taking the time average of the work performed by a thermally isolated system effectively "transforms" the adiabatic process into an isothermal one. This approach allows inherent quantities of adiabatic processes to be…

Statistical Mechanics · Physics 2025-10-03 Pierre Nazé

Energy is often partitioned into heat and work by two independent paths corresponding to the change in the eigenenergies or the probability distributions of a quantum system. The discrepancies of the heat and work for various quantum…

Quantum Physics · Physics 2018-08-01 Shan-He Su , Jin-Fu Chen , Yu-Han Ma , Jin-Can Chen , Chang-Pu Sun

Let a general quantum many-body system at a low temperature adiabatically cross through the vicinity of the system's quantum critical point. We show that the system's temperature is significantly suppressed due to both the entropy…

Statistical Mechanics · Physics 2009-08-27 Shi-Jian Gu
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