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Related papers: The large-Z behaviour of pseudo-relativistic atoms

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We consider a large atom with nuclear charge $Z$ described by non-relativistic quantum mechanics with classical or quantized electromagnetic field. We prove that the absolute ground state energy, allowing for minimizing over all possible…

Mathematical Physics · Physics 2015-05-13 Laszlo Erdos , Jan Philip Solovej

We give the asymptotic behavior of the ground state energy of Engel's and Dreizler's relativistic Thomas-Fermi-Weizs\"acker-Dirac functional for heavy atoms for fixed ratio of the atomic number and the velocity of light. Using a variation…

Mathematical Physics · Physics 2021-01-19 Heinz Siedentop

It is shown that the ground state energy of heavy atoms is, to leading order, given by the non-relativistic Thomas-Fermi energy. The proof is based on the relativistic Hamiltonian of Brown and Ravenhall which is derived from quantum…

Mathematical Physics · Physics 2007-05-23 Roch Cassanas , Heinz Siedentop

We prove that the ground state energy of an atom confined to two dimensions with an infinitely heavy nucleus of charge $Z>0$ and $N$ quantum electrons of charge -1 is $E(N,Z)=-{1/2}Z^2\ln Z+(E^{\TF}(\lambda)+{1/2}c^{\rm H})Z^2+o(Z^2)$ when…

Mathematical Physics · Physics 2011-06-17 Phan Thanh Nam , Fabian Portmann , Jan Philip Solovej

For heavy atoms (large atomic number $Z$) described by no-pair operators in the Furry picture we find the ground state's leading energy correction. We compare the result with (semi-)empirical values and Schwinger's prediction showing more…

Mathematical Physics · Physics 2015-10-09 Michael Handrek , Heinz Siedentop

The purpose of this paper is to derive sharp asymptotics of the ground state energy for the heavy atoms and molecules in the relativistic settings, and, in particular, to derive relativistic Scott correction term and also Dirac, Schwinger…

Spectral Theory · Mathematics 2017-08-24 Victor Ivrii

We prove the first correction to the leading Thomas-Fermi energy for the ground state energy of atoms and molecules in a model where the kinetic energy of the electrons is treated relativistically. The leading Thomas-Fermi energy,…

Mathematical Physics · Physics 2013-10-30 Jan Philip Solovej , Thomas Østergaard Sørensen , Wolfgang L. Spitzer

We consider relativistic many-particle operators which - according to Brown and Ravenhall - describe the electronic states of heavy atoms. Their ground state energy is investigated in the limit of large nuclear charge and velocity of light.…

Mathematical Physics · Physics 2010-08-31 Rupert L. Frank , Heinz Siedentop , Simone Warzel

Outer crusts of neutron stars and interiors of cool white dwarfs consist of bare atomic nuclei, arranged in a crystal lattice and immersed in a Fermi gas of degenerate electrons. We study electrostatic properties of such Coulomb crystals,…

Plasma Physics · Physics 2021-04-21 A. A. Kozhberov , A. Y. Potekhin

The purpose of this paper is to derive sharp asymptotics of the ground state energy for the heavy atoms and molecules in the relativistic settings, with the self-generated magnetic field, and, in particular, to derive relativistic Scott…

Spectral Theory · Mathematics 2017-08-28 Victor Ivrii

We investigate the ground state energy of an electron coupled to a photon field. First, we regard the self-energy of a free electron, which we describe by the Pauli-Fierz Hamiltonian. We show that, in the case of small values of the…

Mathematical Physics · Physics 2016-11-23 Christian Hainzl

A Thomas-Fermi-Weizsaecker type theory is constructed, by means of which we are able to give a relatively simple proof of the stability of relativistic matter. Our procedure has the advantage over previous ones in that the critical value of…

Condensed Matter · Physics 2007-05-23 E. H. Lieb , M. Loss , H. Siedentop

We study atomic ground state energies for neutral atoms as the nuclear charge $Z$ is large in the no-pair formalism. We show that for a large class of projections defining the underlying Dirac sea -- covering not only the physical…

Mathematical Physics · Physics 2025-07-01 Long Meng , Heinz Siedentop

The ground state energy of the Mueller functional of large (neutral) atoms of atomic number Z agrees with the quantum mechanical ground state energy up to order o(Z to the 5/3). ----- Die Grundzustandsenergie des Muellerfunktionals von…

Mathematical Physics · Physics 2009-01-22 Heinz Siedentop

We describe atoms by a pseudo-relativistic model that has its origin in the work of Chandrasekhar. We prove that the leading energy correction for heavy atoms, the Scott correction, exists. It turns out to be lower than in the…

Mathematical Physics · Physics 2008-02-12 Rupert L. Frank , Heinz Siedentop , Simone Warzel

We prove within the Hartree-Fock theory of pseudo-relativistic atoms that the maximal negative ionization charge and the ionization energy of an atom remain bounded independently of the nuclear charge Z and the fine structure constant…

Mathematical Physics · Physics 2010-11-12 Anna Dall'Acqua , Jan Philip Solovej

Using the Pauli-Fierz model of non-relativistic quantum electrodynamics, we calculate the binding energy of an electron in the field of a nucleus of charge $Z$ and in presence of the quantized radiation field. We consider the case of small…

Mathematical Physics · Physics 2007-05-23 Christian Hainzl , Robert Seiringer

In this article we prove the absence of relativistic effects in leading order for the ground-state energy according to Brown-Ravenhall operator. We obtain this asymptotic result for negative ions and for systems with the number of electrons…

Mathematical Physics · Physics 2011-06-21 Xiao Liu

We consider a large neutral atom of atomic number $Z$, modeled by a pseudo-relativistic Hamiltonian of Chandrasekhar. We study its suitably rescaled one-particle ground state density on the Thomas--Fermi length scale $Z^{-1/3}$. Using an…

Mathematical Physics · Physics 2021-02-05 Konstantin Merz , Heinz Siedentop

We consider a large neutral molecule with total nuclear charge $Z$ in a model with self-generated classical magnetic field and where the kinetic energy of the electrons is treated relativistically. To ensure stability, we assume that $Z…

Mathematical Physics · Physics 2015-06-03 Laszlo Erdos , Soren Fournais , Jan Philip Solovej
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