English

The Atomic Density on the Thomas--Fermi Length Scale for the Chandrasekhar Hamiltonian

Mathematical Physics 2021-02-05 v1 math.MP

Abstract

We consider a large neutral atom of atomic number ZZ, modeled by a pseudo-relativistic Hamiltonian of Chandrasekhar. We study its suitably rescaled one-particle ground state density on the Thomas--Fermi length scale Z1/3Z^{-1/3}. Using an observation by Fefferman and Seco (1989), we find that the density on this scale converges to the minimizer of the Thomas--Fermi functional of hydrogen as ZZ\to\infty when Z/cZ/c is fixed to a value not exceeding 2/π2/\pi. This shows that the electron density on the Thomas--Fermi length scale does not exhibit any relativistic effects.

Keywords

Cite

@article{arxiv.1810.00632,
  title  = {The Atomic Density on the Thomas--Fermi Length Scale for the Chandrasekhar Hamiltonian},
  author = {Konstantin Merz and Heinz Siedentop},
  journal= {arXiv preprint arXiv:1810.00632},
  year   = {2021}
}