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We study the dynamics of a molecule's nuclear wave-function near an avoided crossing of two electronic energy levels, for one nuclear degree of freedom. We derive the general form of the Schroedinger equation in the n-th superadiabatic…

Mathematical Physics · Physics 2015-05-13 Volker Betz , Benjamin D. Goddard , Stefan Teufel

A model Hamiltonian describing a two-level system with a crossing plus a pairing force is investigated using technique of large-amplitude collective motion. The collective path, which is determined by the decoupling conditions, is found to…

Nuclear Theory · Physics 2009-10-30 Takashi Nakatsukasa , Niels R. Walet

We consider the time evolution of the adiabatic particle number in both time-dependent electric fields and in de Sitter spaces, and define a super-adiabatic particle number in which the (divergent) adiabatic expansion is truncated at…

High Energy Physics - Theory · Physics 2014-07-23 Robert Dabrowski , Gerald V. Dunne

In quantum mechanics it is often required to describe in a semiclassical approximation the motion of particles moving within a given energy band. Such a representation leads to the appearance of an analogues of fictitious forces in the…

Statistical Mechanics · Physics 2017-10-11 Eldad Bettelheim

It is known that for multi-level time-dependent quantum systems one can construct superadiabatic representations in which the coupling between separated levels is exponentially small in the adiabatic limit. For a family of two-state systems…

Mathematical Physics · Physics 2009-11-10 Volker Betz , Stefan Teufel

The adiabatic Born-Oppenheimer approximation is considered to be a robust approach that very rarely breaks down. Consequently, it is predominantly utilized to address various electron-phonon properties in condensed matter physics. By…

Superconductivity · Physics 2023-03-01 Nina Girotto , Dino Novko

We establish adiabatic theorems with and without spectral gap condition for general -- typically dissipative -- linear operators $A(t): D(A(t)) \subset X \to X$ with time-independent domains $D(A(t)) = D$ in some Banach space $X$. Compared…

Mathematical Physics · Physics 2019-06-26 Jochen Schmid

The development of advanced quantum technologies and the quest for a deeper understanding of many-particle quantum mechanics requires control over the quantum state of interacting particles to a high degree of fidelity. However, the quickly…

Quantum Physics · Physics 2016-03-17 Albert Benseny , Jérémie Gillet , Thomas Busch

We establish adiabatic theorems with and without spectral gap condition for general -- typically dissipative -- linear operators $A(t): D(A(t)) \subset X \to X$ with time-dependent domains $D(A(t))$ in some Banach space $X$. In these…

Mathematical Physics · Physics 2018-09-18 Jochen Schmid

Topological phases emerge as the parameters of a quantum system vary with time. Under the adiabatic approximation, the time dependence can be eliminated, allowing the Berry topological phase to be obtained from a closed trajectory in…

Mesoscale and Nanoscale Physics · Physics 2025-04-30 Abdiel de Jesús Espinosa-Champo , Alejandro Kunold , Gerardo G. Naumis

The level crossing problem is neatly formulated by the second quantized formulation, which exhibits a hidden local gauge symmetry. The analysis of geometric phases is reduced to a simple diagonalization of the Hamiltonian. If one…

Quantum Physics · Physics 2017-08-23 Kazuo Fujikawa

The quantum adiabatic theorem incorporating the Berry phase phenomenon can be characterized as a factorization of the time evolution operator into a path-dependent geometric factor, a usual dynamical factor and a non-adiabatic factor that…

Quantum Physics · Physics 2007-09-08 J. Chee

We consider a time-dependent two-level quantum system interacting with a free Boson reservoir. The coupling is energy conserving and depends slowly on time, as does the system Hamiltonian, with a common adiabatic parameter $\varepsilon$.…

Mathematical Physics · Physics 2020-10-28 Alain Joye , Marco Merkli , Dominique Spehner

Avoided crossings of level pairs with opposite slopes can form potential energy curves for the external degree of freedom of quantum particles. We investigate nonadiabatic decay of metastable states on such avoided crossings (MSACs) using…

Quantum Physics · Physics 2022-10-21 Alisher Duspayev , Ansh Shah , Georg Raithel

We consider the electrons of a molecule in the adiabatic time-dependent density functional theory approximation. We establish the well-posedness of the time evolution and its linear response close to a non-degenerate ground state, and prove…

Analysis of PDEs · Mathematics 2024-09-19 Mi-Song Dupuy , Eloïse Letournel , Antoine Levitt

The exact nuclear time-dependent potential energy surface arises from the exact decomposition of electronic and nuclear motion, recently presented in [A. Abedi, N. T. Maitra, and E. K. U. Gross, Phys. Rev. Lett. 105, 123002 (2010)]. Such…

Chemical Physics · Physics 2015-06-16 Federica Agostini , Ali Abedi , Yasumitsu Suzuki , E. K. U. Gross

The adiabatic theorem and "shortcuts to adiabaticity" for the adiabatic dynamics of time-dependent decoherence-free subspaces are explored in this paper. Starting from the definition of the dynamical stable decoherence-free subspaces, we…

Quantum Physics · Physics 2017-10-25 S. L. Wu , X. L. Huang , H. Li , X. X. Yi

We develop a time-dependent real-space renormalization-group approach which can be applied to Hamiltonians with time-dependent random terms. To illustrate the renormalization-group analysis, we focus on the quantum Ising Hamiltonian with…

Disordered Systems and Neural Networks · Physics 2019-01-30 Peter Mason , Alexandre Zagoskin , Joseph Betouras

We demonstrate that the general model of a linearly time-dependent crossing of two energy bands is integrable. Namely, the Hamiltonian of this model has a quadratically time-dependent commuting operator. We apply this property to four-state…

Mesoscale and Nanoscale Physics · Physics 2021-04-14 Rajesh K. Malla , Vladimir Y. Chernyak , Nikolai A. Sinitsyn

We have investigated pumping in quantum dots from the perspective of non-Abelian (matrix) Berry phases by solving the time dependent Schr{\"o}dinger equation exactly for adiabatic changes. Our results demonstrate that a pumped charge is…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 N. Y. Hwang , S. C. Kim , P. S. Park , S. -R. Eric Yang