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We address the problem of the dynamical foundation of non-canonical equilibrium. We consider, as a source of divergence from ordinary statistical mechanics, the breakdown of the condition of time scale separation between microscopic and…

Statistical Mechanics · Physics 2009-10-31 M. Annunziato , P. Grigolini , B. J. West

Granular matter is comprised of a large number of particles whose collective behavior determines macroscopic properties such as flow and mechanical strength. A comprehensive theory of the properties of granular matter, therefore, requires a…

Statistical Mechanics · Physics 2009-11-13 Silke Henkes , Corey S. O'Hern , Bulbul Chakraborty

We derive the microcanonical ensemble from the Maximum Entropy Principle (MEP) using the phase space volume entropy of P. Hertz. Maximizing this entropy with respect to the probability distribution with the constraints of normalization and…

Statistical Mechanics · Physics 2008-02-15 Michele Campisi , Donald H. Kobe

We present an alternative formalism of quantum mechanics tailored to statistical ensemble in phase space. The purpose of our work is to show that it is possible to establish an alternative autonomous formalism of quantum mechanics in phase…

Quantum Physics · Physics 2018-11-20 Chol Jong , Byong-Il Ri , Song-Guk Kim , Son-Il Jo , Shin-Hyok Jon , Namchol Choe

This paper reviews a number of fundamental connections that exist between nonequivalent microcanonical and canonical ensembles, the appearance of first-order phase transitions in the canonical ensemble, and thermodynamic metastable…

Statistical Mechanics · Physics 2017-08-23 Hugo Touchette , Richard S. Ellis

It is generally believed that, in the thermodynamic limit, the microcanonical description as a function of energy coincides with the canonical description as a function of temperature. However, various examples of systems for which the…

Statistical Mechanics · Physics 2016-01-13 Tiziano Squartini , Joey de Mol , Frank den Hollander , Diego Garlaschelli

The theory of small-system thermodynamics was originally developed to extend the laws of thermodynamics to length scales of nanometers. Here we review this "nanothermodynamics," and stress how it also applies to large systems that subdivide…

Statistical Mechanics · Physics 2020-07-28 Ralph V. Chamberlin , Michael R. Clark , Vladimiro Mujica , George H. Wolf

We provide an overview of a canonical formalism that describes mixed quantum-classical systems in terms of statistical ensembles on configuration space, and discuss applications to measurement theory. It is shown that the formalism allows a…

Quantum Physics · Physics 2009-07-06 M Reginatto , M J W Hall

A simple model of particle creation and annihilation in an isolated assembly of particles with conserved energy and fixed volume, the Cell Model, is formulated. With increasing time, particle number distribution, obtained by averaging over…

Nuclear Theory · Physics 2018-04-25 M. Gazdzicki , M. I. Gorenstein , A. Fronczak , P. Fronczak , M. Mackowiak-Pawlowska

Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. However, some 150 years ago the original motivation of thermodynamics was the description of steam engines, i.e. boiling water. Its essential…

Statistical Mechanics · Physics 2009-11-10 D. H. E. Gross

The paper discusses the physical groundlessness of the models used for the derivation of canonical distribution and provides the experimental data demonstrating the incompleteness of quantum mechanics. The possibility of using statistical…

General Physics · Physics 2014-05-06 V. A. Skrebnev

In complex systems with many degrees of freedom such as spin glass and biomolecular systems, conventional simulations in canonical ensemble suffer from the quasi-ergodicity problem. A simulation in generalized ensemble performs a random…

Statistical Mechanics · Physics 2008-06-24 Y. Okamoto

Many experimentally-accessible, finite-sized interacting quantum systems are most appropriately described by the canonical ensemble of statistical mechanics. Conventional numerical simulation methods either approximate them as being coupled…

Strongly Correlated Electrons · Physics 2023-05-23 Tong Shen , Hatem Barghathi , Jiangyong Yu , Adrian Del Maestro , Brenda Rubenstein

We consider an arbitrary quantum system coupled non perturbatively to a large arbitrary and fully quantum environment. In [G. Ithier and F. Benaych-Georges, Phys. Rev. A 96, 012108 (2017)] the typicality of the dynamics of such an embedded…

Quantum Physics · Physics 2017-12-20 Grégoire Ithier , Saeed Ascroft , Florent Benaych-Georges

The relation between thermodynamic phase transitions in classical systems and topology changes in their state space is discussed for systems in which equivalence of statistical ensembles does not hold. As an example, the spherical model…

Statistical Mechanics · Physics 2007-05-23 Michael Kastner

I present a theoretical model of a quantum statistical ensemble for which, unlike in conventional physics, the total number of particles is extremely small. The thermodynamical quantities are calculated by taking a small $N$ by virtue of…

Quantum Physics · Physics 2010-01-15 Enrico Prati

We consider a paradigmatic model describing the one-dimensional motion of $N$ rotators coupled through a mean-field interaction, and subject to the perturbation of an external magnetic field. The latter is shown to significantly alter the…

Statistical Mechanics · Physics 2010-11-29 Giovanni De Ninno , Duccio Fanelli

Random Quantum States are presently of interest in the fields of quantum information theory and quantum chaos. Moreover, a detailed study of their properties can shed light on some foundational issues of the quantum statistical mechanics…

Quantum Physics · Physics 2010-01-07 Barbara Fresch , Giorgio J. Moro

The microcanonical properties of a two dimensional system of N classical particles interacting via a smoothed Newtonian potential as a function of the total energy E and the total angular momentum L are discussed. In order to estimate…

Statistical Mechanics · Physics 2009-11-07 Olivier Fliegans , D. H. E. Gross

In order to increase the efficiency of the computer simulation of biological molecules, it is very common to impose holonomic constraints on the fastest degrees of freedom; normally bond lengths, but also possibly bond angles. However, as…

Chemical Physics · Physics 2011-12-19 Pablo Echenique , Claudio N. Cavasotto , Pablo García-Risueño