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The presence of knots has been observed in a small fraction of single-domain proteins and related to their thermodynamic and kinetic properties. The exchanging of identical structural elements, typical of domain-swapped proteins, make such…

Soft Condensed Matter · Physics 2017-06-13 Marco Baiesi , Enzo Orlandini , Antonio Trovato , Flavio Seno

It is nontrivial whether the average size of a ring polymer should become smaller or larger under a topological constraint. Making use of some knot invariants, we evaluate numerically the mean square radius of gyration for ring polymers…

Statistical Mechanics · Physics 2016-08-31 Miyuki K. Shimamura , Tetsuo Deguchi

We report grand canonical Monte Carlo simulations of the critical point properties of homopolymers within the Bond Fluctuation model. By employing Configurational Bias Monte Carlo methods, chain lengths of up to N=60 monomers could be…

Condensed Matter · Physics 2009-10-28 N. B. Wilding , M. Mueller , K. Binder

The scaling of the bond-bond correlation function $C(s)$ along linear polymer chains is investigated with respect to the curvilinear distance, $s$, along the flexible chain and the monomer density, $\rho$, via Monte Carlo and molecular…

Soft Condensed Matter · Physics 2009-11-10 J. P. Wittmer , H. Meyer , J. Baschnagel , A. Johner , S. Obukhov , L. Mattioni , M. Mueller , A. N. Semenov

The behavior of mobile linkers connecting two semi-flexible charged polymers, such as polyvalent counterions connecting DNA or F-actin chains, is studied theoretically. The chain bending rigidity induces an effective repulsion between…

Soft Condensed Matter · Physics 2009-11-07 I. Borukhov , R. F. Bruinsma , W. M. Gelbart , A. J. Liu

We study jamming in model freely rotating polymers as a function of chain length $N$ and bond angle $\theta_0$. The volume fraction at jamming, $\phi_J(\theta_0)$, is minimal for rigid-rod-like chains ($\theta_0 = 0$), and increases…

Soft Condensed Matter · Physics 2017-02-15 Robert S. Hoy

Molecular dynamics simulations confirm recent extensional flow experiments showing ring polymer melts exhibit strong extension-rate thickening of the viscosity at Weissenberg numbers $Wi<<1$. Thickening coincides with the extreme elongation…

Soft Condensed Matter · Physics 2020-01-22 Thomas C. O'Connor , Ting Ge , Michael Rubinstein , Gary S. Grest

The work in this article is inspired by a classical problem: the statistical physical properties of a closed polymer loop that is wound around a rod. Historically the preserved topology of this system has been addressed through…

Statistical Mechanics · Physics 2015-09-14 Christian M. Rohwer , Kristian K. Müller-Nedebock , F. -E. Mpiana Mulamba

We investigate diffusion-limited reactions between a diffusing particle and a target site on a semiflexible polymer, a key factor determining the kinetics of DNA-protein binding and polymerization of cytoskeletal filaments. Our theory…

Soft Condensed Matter · Physics 2010-12-08 Yann von Hansen , Roland R. Netz , Michael Hinczewski

By Monte Carlo simulations of a variant of the bond-fluctuation model without topological constraints we examine the center-of-mass (COM) dynamics of polymer melts in $d=3$ dimensions. Our analysis focuses on the COM displacement…

The conformations of interacting linear polymers on a dynamical planar random lattice are studied using a random two-matrix model. An exact expression for the partition function of self-avoiding chains subject to attractive contact…

Condensed Matter · Physics 2008-02-03 Simon Dalley

We investigate the chain conformation of ring polymers confined to a cylindrical nanochannel using both theoretical analysis and three dimensional Langevin dynamics simulations. We predict that the longitudinal size of a ring polymer scales…

Soft Condensed Matter · Physics 2012-12-06 Junfang Sheng , Kaifu Luo

The equilibrium properties of isolated ring molecules were investigated using an off-lattice model with no excluded volume but with dynamics that preserve the topological class. Using an efficient set of long range moves, chains of more…

Soft Condensed Matter · Physics 2009-10-31 J. M. Deutsch

Our first main result is that correlations between monomers in the dimer model in $\mathbb{Z}^d$ do not decay to zero when $d > 2$. This is the first rigorous result about correlations in the dimer model in dimensions greater than two and…

Probability · Mathematics 2019-11-25 Lorenzo Taggi

We use the bond fluctuation model to study the contraction process of two polymer loops with $N$ segments that are connected each to the bottom and top part of a Feringa engine. The change in the size of the molecules as well as the folding…

Chemical Physics · Physics 2022-07-04 Michael Lang , Cornelia Schuster , Ron Dockhorn , Martin Wengenmayr , Jens-Uuwe Sommer

A novel statistical model for the cooperative binding of monomeric ligands to a linear lattice is developed to study the interaction of ionic surfactant molecules with flexible polyion chain in dilute solution. Electrostatic binding of a…

Soft Condensed Matter · Physics 2015-01-13 T. Nishio , T. Shimizu , Sh. Yoshida , A. Minakata

Polymers are an effective test-bed for studying topological constraints in condensed matter due to a wide array of synthetically-available chain topologies. When linear and ring polymers are blended together, emergent rheological properties…

Soft Condensed Matter · Physics 2024-04-25 Daniel L. Vigil , Ting Ge , Michael Rubinstein , Thomas C. O'Connor , Gary S. Grest

Brownian motion and viscoelasticity of semiflexible polymers is a subject that has been studied for many years. Still, rigorous analysis has been hindered due to the difficulty in handling the constraint that polymer chains cannot be…

Soft Condensed Matter · Physics 2024-05-22 Zhongqiang Xiong , Ryohei Seto , Masao Doi

We discuss the entropy of a circular polymer under a topological constraint. We call it the {\it topological entropy} of the polymer, in short. A ring polymer does not change its topology (knot type) under any thermal fluctuations. Through…

Statistical Mechanics · Physics 2009-11-07 Miyuki K. Shimamura , Tetso Deguchi

Simulations in which a globular ring polymer with delocalized knots is separated in two interacting loops by a slipping link, or in two non-interacting globuli by a wall with a hole, show how the minimal crossing number of the knots…

Soft Condensed Matter · Physics 2011-10-17 M. Baiesi , E. Orlandini , A. L. Stella , F. Zonta