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We present molecular dynamics simulations of a model glass-forming liquid (the binary Kob-Anderson Lennard-Jones model) and consider the distributions of inherent energies and metabasins during aging. In addition to the typical protocol of…

Disordered Systems and Neural Networks · Physics 2016-08-14 Christian Rehwald , Nicoletta Gnan , Andreas Heuer , Thomas Schrøder , Jeppe C. Dyre , Gregor Diezemann

Recent efforts to deal with the complexities of the liquid state, particularly those of glassforming systems, have focused on the "energy landscape" as a means of dealing with the collective variables problem [1]. The "basins of attraction"…

Disordered Systems and Neural Networks · Physics 2007-05-23 L. -M. Martinez , C. A. Angell

Framing the glass formation within standard statistical mechanics is an outstanding problem of condensed matter theory. To provide new insight, we investigate the structural properties of the Lennard-Jones fluid in the very-low temperature…

Statistical Mechanics · Physics 2026-02-02 Bomont Jean-Marc , Bretonnet Jean-Louis , Costa Dino , Pastore Giorgio

We connect the configurational entropy of a liquid to the geometrical properties of its local energy landscape, using a high-temperature expansion. It is proposed that correlations between local structures arises from their overlap and,…

Soft Condensed Matter · Physics 2016-08-24 Pierre Ronceray , Peter Harrowell

Hard-sphere models exhibit many of the same kinds of supercooled-liquid behavior as more realistic models of liquids, but the highly non-analytic character of their potentials makes it a challenge to think of that behavior in…

Soft Condensed Matter · Physics 2015-06-22 Qingqing Ma , Richard M. Stratt

Generic glass formers exhibit at least two characteristic changes in their relaxation behavior, first to an Arrhenius-type relaxation at some characteristic temperature, and then at a lower characteristic temperature to a super-Arrhenius…

Disordered Systems and Neural Networks · Physics 2012-03-08 H. George E. Hentschel , Smarajit Karmakar , Itamar Procaccia , Jacques Zylberg

The scaling properties of the soft-sphere potential allow the derivation of an exact expression for the pressure of a frozen liquid, i.e., the pressure corresponding to configurations which are local minima in its multidimensional potential…

Soft Condensed Matter · Physics 2009-11-10 E. La Nave , F. Sciortino , P. Tartaglia , M. S. Shell , P. G. Debenedetti

The evaluation of the long term stability of a material requires the estimation of its long-time dynamics. For amorphous materials such as structural glasses, it has proven difficult to predict the long-time dynamics starting from static…

Soft Condensed Matter · Physics 2014-05-27 Raffaele Pastore , Antonio Coniglio , Massimo Pica Ciamarra

We calculate the density of states of a binary Lennard-Jones glass using a recently proposed Monte Carlo algorithm. Unlike traditional molecular simulation approaches, the algorithm samples distinct configurations according to…

Soft Condensed Matter · Physics 2009-11-10 Roland Faller , Juan J. de Pablo

We consider a simple model of a structural glass, represented by a lattice gas with kinetic constraints in contact with a particle reservoir. Quench below the glass transition is represented by the jump of the chemical potential above a…

Statistical Mechanics · Physics 2007-05-23 Luca Peliti , Mauro Sellitto

We introduce a lattice spin model where frustration is due to multibody interactions rather than quenched disorder in the Hamiltonian. The system has a crystalline ground state and below the melting temperature displays a dynamic behaviour…

Statistical Mechanics · Physics 2009-11-07 Andrea Cavagna , Irene Giardina , Tomas Grigera

Using molecular dynamics simulations we study the temperature-density phase diagram of a simple model system of particles in two dimensions. In addition to translational degrees of freedom, each particle has two internal states and…

Soft Condensed Matter · Physics 2013-05-29 Chandana Mondal , Surajit Sengupta

Liquids near the glass transition exhibit dynamical heterogeneity, i.e. local relaxation rates fluctuate strongly over space and time. Here we introduce a simple continuum model that allows for quantitative predictions for the correlators…

Soft Condensed Matter · Physics 2024-03-20 Rajib K. Pandit , Horacio E. Castillo

Molecular dynamics simulations of a Lennard-Jones binary mixture confined in a disordered array of soft spheres are presented. The single particle dynamical behavior of the glass former is examined upon supercooling. Predictions of mode…

Statistical Mechanics · Physics 2009-11-07 P. Gallo , R. Pellarin , M. Rovere

The complex physics of glass forming systems is controlled by the structure of the low energy portions of their potential energy landscapes. Here, we report that a modified metadynamics algorithm efficiently explores and samples low energy…

Soft Condensed Matter · Physics 2023-01-11 Amruthesh Thirumalaiswamy , Robert A. Riggleman , John C. Crocker

Simulations of a stochastic fixed-energy sandpile in one and two dimensions reveal slow relaxation of the order parameter, even far from the critical point. The decay of the activity is best described by a stretched-exponential form. The…

Statistical Mechanics · Physics 2009-11-07 Ronald Dickman

We review recent results on the potential energy landscape (PES) of model liquids. The role of saddle-points in the PES in connecting dynamics to statics is investigated, confirming that a change between minima-dominated and…

Soft Condensed Matter · Physics 2012-11-26 Antonio Scala , Luca Angelani , Roberto Di Leonardo , Giancarlo Ruocco , Francesco Sciortino

The spherical p-spin model is not only a fundamental model in statistical mechanics of disordered system, but has recently gained popularity since many hard problems in machine learning can be mapped on it. Thus the study of the out of…

Disordered Systems and Neural Networks · Physics 2020-09-02 Giampaolo Folena , Silvio Franz , Federico Ricci-Tersenghi

By defining a spatially varying replica overlap parameter for a supercooled liquid referenced to an ensemble of fiducial liquid state configurations we explicitly construct a constrained replica free energy functional that maps directly…

Soft Condensed Matter · Physics 2009-11-13 Jacob D. Stevenson , Aleksandra M. Walczak , Randall W. Hall , Peter G. Wolynes

In this paper we study the process of fragmentation of highly excited Lennard-Jones drops by introducing the concept of emitted fragments (clusters recognizable in configuration space which live more than a minimum lifetime). We focus on…

Nuclear Theory · Physics 2009-11-10 M. J. Ison , C. O. Dorso