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The disjoining pressure isotherm in foam films is theoretically studied and an important contribution of adsorption is discovered. On the basis of the interfacial thermodynamics an adsorption disjoining pressure component is derived, which…

Mesoscale and Nanoscale Physics · Physics 2012-01-19 R. Tsekov

We perform three-dimensional direct numerical simulations of surface-driven convection near the temperature of maximum density $\tilde T_{md}$. A dynamic surface boundary condition couples heat flux through the surface to the induced…

Atmospheric and Oceanic Physics · Physics 2024-05-08 Jason Olsthoorn

The smearing of the graphene/graphane interface due to the thermally activated migration of hydrogen atoms is studied by the molecular dynamics method. Contrary to expectations, it is found that the fast spontaneous regeneration of this…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 L. A. Openov , A. I. Podlivaev

We investigate the growth kinetics on vicinal GaAs(001) surfaces by making detailed comparisons between reflection high--energy electron--diffraction specular intensity measured near in--phase diffraction conditions and the surface step…

Condensed Matter · Physics 2009-10-22 Pavel Šmilauer , Dimitri D. Vvedensky

The thermodynamic properties for three different types of off-lattice four-strand beta-sheet protein models interacting via a hybrid Go-type potential have been investigated. Discontinuous molecular dynamic simulations have been performed…

Biological Physics · Physics 2009-11-07 Hyunbum Jang , Carol K. Hall , Yaoqi Zhou

We study the non-equilibrium coarsening dynamics of a binary liquid solvent around a colloidal particle in a presence of a time-dependent temperature gradient that emerges after temperature quench of a suitably coated colloid surface. The…

Soft Condensed Matter · Physics 2018-11-30 Sutapa Roy , Anna Maciolek

The surface tension $\sigma$ of free-standing graphene is studied by path-integral simulations as a function of the temperature and the in-plane stress. Even if the applied stress vanishes, the membrane displays a finite surface tension…

Materials Science · Physics 2018-06-27 R. Ramirez , C. P. Herrero

A glass surface may still flow below the bulk glass transition temperature, where the underlying bulk is frozen. Assuming the existence at T=T* of a bulk thermodynamical glass transition, we show that the glass-vapor interface is generally…

Materials Science · Physics 2009-10-31 E. A. Jagla , E. Tosatti

We perform the analysis of predictions of a classical density functional theory for associating fluids with different association strength concerned with wetting of solid surfaces. The four associating sites water-like models with…

Soft Condensed Matter · Physics 2024-04-01 A. Kozina , M. Aguilar , O. Pizio , S. Sokołowski

A theory for the thermodynamic properties of steps on faceted crystalline surfaces is presented. The formalism leads to the definition of step excess quantities, including an excess step stress that is the step analogy of surface stress.…

Materials Science · Physics 2017-05-03 Rodrigo Freitas , Timofey Frolov , Mark Asta

We study adsorption of liquid at a one-dimensional substrate composed of a single chemical inhomogeneity of width $2L$ placed on an otherwise homogeneous, planar, solid surface. The excess point free energy $\eta (L,T)$ associated with the…

Statistical Mechanics · Physics 2009-11-11 P. Jakubczyk , M. Napiorkowski , A. O. Parry

A thermodynamically consistent phase-field model is developed to study the non-isothermal grain coalescence during the sintering process, with a potential application to the simulation in unconventional sintering techniques, e.g. spark…

Materials Science · Physics 2018-06-08 Yangyiwei Yang , Min Yi , Bai-Xiang Xu , Long-Qing Chen

We derive a continuum sharp-interface model for moving contact lines with soluble surfactants in a thermodynamically consistent framework. The model consists of the isothermal two-phase incompressible Navier-Stokes equations for the fluid…

Fluid Dynamics · Physics 2021-08-11 Quan Zhao , Weiqing Ren , Zhen Zhang

The phase diagram of a 2D Josephson junction array with large substrate resistance, described by a quantum XY model, is studied by means of Fourier path-integral Monte Carlo. A genuine Berezinskii-Kosterlitz-Thouless transition is found up…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Luca Capriotti , Alessandro Cuccoli , Andrea Fubini , Valerio Tognetti , Ruggero Vaia

Conformational phases of a semiflexible off-lattice homopolymer model near an attractive substrate are investigated by means of multicanonical computer simulations. In our polymer-substrate model, nonbonded pairs of monomers as well as…

Computational Physics · Physics 2009-07-20 Monika Möddel , Michael Bachmann , Wolfhard Janke

Multilayer sorption isotherms of 1-propanol on graphite have been measured by means of high-resolution ellipsometry within the liquid regime of the adsorbed film for temperatures ranging from 180 to 260 K. In the first three monolayers the…

Chemical Physics · Physics 2015-03-19 Matthias Wolff , Frank Kruchten , Patrick Huber , Klaus Knorr , Ulrich G. Volkmann

In this paper the development of a physically consistent phase-field theory of solidification shrinkage is presented. The coarse-grained hydrodynamic equations are derived directly from the N-body Hamiltonian equations in the framework of…

Materials Science · Physics 2020-02-28 Gyula I. Toth , Wenyue Ma

A sublimating vicinal crystal surface can undergo a step bunching instability when the attachment-detachment kinetics is asymmetric, in the sense of a normal Ehrlich-Schwoebel effect. Here we investigate this instability in a model that…

Statistical Mechanics · Physics 2015-05-18 Marian Ivanov , Vladislav Popkov , Joachim Krug

The temperature dependence of hydrogen (H) desorption from Si(100) H-terminated surfaces by a scanning tunneling microscope (STM) is reported for negative sample bias. It is found that the STM induced H desorption rate ($R$) decreases…

Materials Science · Physics 2009-10-31 C. Thirstrup , M. Sakurai , T. Nakayama , K. Stokbro

The glass transition temperature and its connection to statistical properties of confined and free-standing polymer films of varying thickness containing unentangled to highly entangled bead-spring chains are studied by molecular dynamics…

Soft Condensed Matter · Physics 2023-09-21 Hsiao-Ping Hsu , Kurt Kremer