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This paper builds on two previous works, Lindgren et al. J. Comp. Phys. 371, 712-731 (2018) and Quan et al. arXiv:1807.05384 (2018), to devise a new method to solve the problem of calculating electrostatic interactions in a system composed…

Soft Condensed Matter · Physics 2019-02-20 Eric B. Lindgren , Chaoyu Quan , Benjamin Stamm

We study the effective interaction between a planar array of uniformly negatively charged, stiff rods parallel to a negatively charged planar substrate in the absence of salt in a continuous, isotropic dielectric medium. Using Brownian…

Soft Condensed Matter · Physics 2009-10-31 R. Jay Mashl , Niels Grønbech-Jensen

Charge-stabilized colloidal suspensions can be conveniently described by formally reducing the macroion-microion mixture to an equivalent one-component system of pseudo-particles. Within this scheme, the utility of a linear response…

Soft Condensed Matter · Physics 2009-10-31 A. R. Denton

Nonmagnetic spheres confined in a ferrofluid layer (magnetic holes) present dipolar interactions when an external magnetic field is exerted. The interaction potential of a microsphere pair is derived analytically, with a precise care for…

Soft Condensed Matter · Physics 2009-11-10 Renaud Toussaint , Jørgen Akselvoll , Eirik G. Flekkøy , Geir Helgesen , Arne T. Skjeltorp

We study the interactions between two negatively charged macroscopic surfaces confining positive counterions. A density-functional approach is introduced which, besides the usual mean-field interactions, takes into account the correlations…

Soft Condensed Matter · Physics 2015-06-25 A. Diehl , M. N. Tamashiro , Marcia C. Barbosa , Yan Levin

The equilibrium phase behavior of a binary mixture of charged colloids and neutral, non-adsorbing polymers is studied within free-volume theory. A model mixture of charged hard-sphere macroions and ideal, coarse-grained, effective-sphere…

Soft Condensed Matter · Physics 2009-11-11 Alan R. Denton , Matthias Schmidt

We report an approach to obtain effective pair potentials which describe the structure of two-dimensional systems of active Brownian particles. The pair potential is found by an inverse method, which matches the radial distribution function…

We study the depletion interaction between spherical particles of radius R immersed in a dilute solution of rigid rods of length L. The computed interaction potential is, within numerical accuracy, exact for any value of L/R. In particular…

Soft Condensed Matter · Physics 2009-10-30 K. Yaman , C. Jeppesen , C. M. Marques

The depletion interactions between two colloidal plates or between two colloidal spheres, induced by interacting polymers in a good solvent, are calculated theoretically and by computer simulations. A simple analytical theory is shown to be…

Soft Condensed Matter · Physics 2009-11-07 A. A. Louis , P. G. Bolhuis , E. J. Meijer , J. P. Hansen

We investigate effective interactions between a colloidal particle, immersed in a binary mixture of smaller spheres, and a semipermeable membrane. The colloid is modeled as a big hard sphere and the membrane is represented as an infinitely…

Soft Condensed Matter · Physics 2007-05-23 Pawel Bryk

We discuss phase coexistence of polydisperse colloidal suspensions in the presence of adhesion forces. The combined effect of polydispersity and Baxter's sticky-hard-sphere (SHS) potential, describing hard spheres interacting via strong and…

Statistical Mechanics · Physics 2009-11-11 Domenico Gazzillo , Achille Giacometti , Riccardo Fantoni

We report the coupled effects of macroion charge discretization and counterion valence in the primitive model for spherical colloids. Instead of considering a uniformly charged surface, as it is traditionally done, we consider a more…

Soft Condensed Matter · Physics 2009-11-07 Rene Messina

The depletion interaction between two parallel repulsive walls confining a dilute solution of long and flexible polymer chains is studied by field-theoretic methods. Special attention is paid to self-avoidance between chain monomers…

Soft Condensed Matter · Physics 2009-11-07 F. Schlesener , A. Hanke , R. Klimpel , S. Dietrich

Interaction of particles of many systems can be effectively approximated by multiscale interaction potentials. Such potentials are widely used for investigation of colloidal systems and colloid-polymer mixtures, complex liquids (for…

Soft Condensed Matter · Physics 2019-02-13 Yu. D. Fomin , V. N. Ryzhov , E. N. Tsiok

The surface tension of interacting polymers in a good solvent is calculated theoretically and by computer simulations for a planar wall geometry and for the insertion of a single colloidal hard-sphere. This is achieved for the planar wall…

Soft Condensed Matter · Physics 2016-08-31 A. A. Louis , P. G. Bolhuis , E. J. Meijer , J. P. Hansen

We study the low-frequency dielectric response of highly charged spheres arranged in a cubic lattice and immersed in an electrolyte solution. We focus on the influence of the out-of-phase current in the regime where the ionic charge is…

Soft Condensed Matter · Physics 2019-03-27 Chang-Yu Hou , Jiang Qian , Denise E. Freed

We consider a random diffusion dynamics for an infinite system of hard spheres of two different sizes evolving in $\mathbb{R}^d$, its reversible probability measure, and its projection on the subset of the large spheres. The main feature is…

Probability · Mathematics 2024-03-05 Myriam Fradon , Julian Kern , Sylvie Roelly , Alexander Zass

Simulations for the density and potential profiles of the ions in the planar electrical double layer of a model electrolyte or an ionic liquid are reported. The ions of a real electrolyte or an ionic liquid are usually not spheres; in ionic…

Soft Condensed Matter · Physics 2016-03-08 W. Silvestre-Alcantara , L. B. Bhuiyan , S. Lamperski , M. Kaja , D. Henderson

In biomimetic and biological systems, interactions between surfaces are often mediated by adhesive molecules, nanoparticles, or colloids dispersed in the surrounding solution. We present here a general, statistical-mechanical model for two…

Soft Condensed Matter · Physics 2009-11-13 Bartosz Rozycki , Reinhard Lipowsky , Thomas R. Weikl

We consider two charged semipermeable membranes, which bound bulk electrolyte solutions and are separated by a thin film of salt-free liquid. Small counter-ions permeate into the gap, which leads to a steric charge separation in the system.…

Soft Condensed Matter · Physics 2016-11-23 Salim R. Maduar , Olga I. Vinogradova