Related papers: Filling transition for a wedge
The present manuscript gives a theoretical description of the first-order phase transition in a cell fluid model with a modified Morse potential and additional repulsive interaction. In the framework of the grand canonical ensemble, the…
Although medium chain length insoluble amphiphiles are well known to form gaseous and liquid expanded phases on an air/water interface, the situation for the soluble case is less clear. We perform molecular dynamics simulations of model…
Glass-to-glass and liquid-to-liquid phase transitions were observed many years ago in bulk and confined water with or without applied pressure. It is shown that they result from the competition of two-liquid phases separated by an enthalpy…
We propose a model describing the liquid-vapour phase transition according to a phase-field approach. The model takes up a setting proposed by the second author, where a phase field is introduced whose equilibrium values 0 and 1 are…
Mean field analysis of the effective interfacial Hamiltonian shows that with increasing temperature the adsorption on a periodically corrugated substrate can proceed in two steps: first, there is the filling transition in which the…
When a capillary channel with corners is wetted by a fluid, there are regions where the fluid fills the whole cross-section and regions where only the corners are filled by the fluid. The fluid fraction of the partially-filled region,…
We study pressurised self-avoiding ring polymers in two dimensions using Monte Carlo simulations, scaling arguments and Flory-type theories, through models which generalise the model of Leibler, Singh and Fisher [Phys. Rev. Lett. Vol. 59,…
A simple two dimensional model of a phase growing on a substrate is introduced. The model is characterized by an adsorption rate q, and a desorption rate p. It exhibits a wetting transition which may be viewed as an unbinding transition of…
The surface freezing and surface melting transitions exhibited by a model two-dimensional soft matter system is studied. The behaviour when confined within a wedge is also considered. The system consists of particles interacting via a soft…
We report a detailed simulation and classical density functional theory study of the drying transition in a realistic model fluid at a smooth substrate. This transition (in which the contact angle $\theta\to 180^\circ$) is shown to be…
We investigate a spinless Fermi gas trapped in a honeycomb optical lattice with attractive nearest-neighbor interactions. At zero temperature, mean-field theory predicts three quantum phase transitions, two being topological. At low…
We consider the liquid-vapor type phase transition for fluids confined within spatially periodic external fields. For a fluid in d=3 dimensions, the periodic field induces an additional phase, characterized by large density modulations…
This experimental study focuses on the characteristics of air-water two-phase interfacial structure. Interfacial parameters including void fraction, interfacial area concentration, and bubble interfacial velocity are measured using…
We consider a restricted Solid-on-Solid interface in $\Bbb{Z}_{+}$, subject to a potential $V\left( n\right) $ behaving at infinity like $-\mathrm{w}/n^{2}$. Whenever there is a wetting transition as $b_{0}\equiv \exp V\left( 0\right) $ is…
Wetting and drying phenomena are studied for flexible and semiflexible polymer solutions via coarse-grained molecular dynamics simulations and density functional theory calculations. The study is based on the use of Young's equation for the…
A ubiquitous arrangement in nature is a free-flowing fluid coupled to a porous medium, for example a river or lake lying above a porous bed. Depending on the environmental conditions, thermal convection can occur and may be confined to the…
We investigate the phase diagram of a two-component associating fluid mixture in the presence of selectively adsorbing substrates. The mixture is characterized by a bulk phase diagram which displays peculiar features such as closed loops of…
In steady-state non-isentropic flows of perfect fluids there is always thermodynamic generation of vorticity when the difference between the product of the temperature with the gradient of the entropy and the gradient of total enthalpy is…
We study boundary induced phase transitions in a driven lattice gas exhibiting metastability. The phase diagram for open systems, parameterized by the input and output rates, consists of two regions corresponding to the free flow and jammed…
We show that the 3D wedge filling transition in the presence of short-ranged interactions can be first-order or second order depending on the strength of the line tension associated with to the wedge bottom. This fact implies the existence…