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We determine the distribution of free ends and the monomer insertion potential in the strongly-stretched limit for regularly and statistically branched polymer brushes. We find that the end density flattens in the limit of very strong…

Soft Condensed Matter · Physics 2015-07-14 Daniel O. LeSher , Grant L Metheny , Galen T. Pickett

The paper presents results from kinetic Monte Carlo simulations of kinetic surface roughening using an important and experimentally relevant model of epitaxial growth -- the solid-on-solid model with Arrhenius dynamics. A restriction on…

Materials Science · Physics 2014-08-15 Petar P. Petrov , Daniela Gogova

We present a novel computational method to simulate accurately a wide range of interfacial patterns whose growth is limited by a large scale diffusion field. To illustrate the computational power of this method, we demonstrate that it can…

Materials Science · Physics 2009-10-31 Mathis Plapp , Alain Karma

The convex hull peeling of a point set is obtained by taking the convex hull of the set and repeating iteratively the operation on the interior points until no point remains. The boundary of each hull is called a layer. We study the number…

Probability · Mathematics 2022-06-22 Pierre Calka , Gauthier Quilan

The permeability of certain polymer membranes with impenetrable nanoinclusions increases with the particle volume fraction (Merkel et al., Science, 296, 2002). This intriguing observation contradicts even qualitative expectations based on…

Materials Science · Physics 2007-05-23 Reghan J. Hill

The viscosity enhancement of a solvent produced by the addition of thickening branched polymers is predicted as a function of polymer concentration, branch length and persistence length, and strength of the covalent bonding interactions.…

Soft Condensed Matter · Physics 2021-08-02 E. Mayoral , A. Gama Goicochea

We study the growth of Richtmyer-Meshkov mixing layers from an initial surface with spatially localized perturbations. We use two symmetric forms of the initial patch, which allow simulation data to be averaged to generate a two-dimensional…

Fluid Dynamics · Physics 2019-08-09 Britton J. Olson , Robin Williams

Polymer brush layers are responsive materials that swell in contact with good solvents and their vapors. We deposit drops of an almost completely wetting volatile oil onto an oleophilic polymer brush layer and follow the response of the…

Soft Condensed Matter · Physics 2023-08-11 Özlem Kap , Simon Hartmann , Harmen Hoek , Sissi de Beer , Igor Siretanu , Uwe Thiele , Frieder Mugele

Randomly branching polymers with {\em annealed} connectivity are model systems for ring polymers and chromosomes. In this context, the branched structure represents transient folding induced by topological constraints. Here we present…

Statistical Mechanics · Physics 2016-11-03 Angelo Rosa , Ralf Everaers

Droplet patterns condensing on solid substrates (breath figures) tend to evolve into a self-similar regime, characterized by a bimodal droplet size distribution. The distributions comprise a bell-shaped peak of monodisperse large droplets,…

Fluid Dynamics · Physics 2015-10-28 L. Stricker , J. Vollmer

The random deposition model must be enriched to reflect the variety of surface roughness due to some material characteristics of the film growing by vacuum deposition or sputtering. The essence of the computer simulation in this case is to…

Condensed Matter · Physics 2007-05-23 K. Malarz , A. Z. Maksymowicz

The structural properties of polydisperse hard spheres in the presence of a hard wall are investigated via Monte Carlo simulation and density functional theory (DFT). Attention is focussed on the local density distribution $\rho(\sigma,z)$,…

Soft Condensed Matter · Physics 2009-11-10 Matteo Buzzacchi , Ignacio Pagonabarraga , Nigel B. Wilding

Large scale molecular dynamics and grand canonical Monte Carlo simulation techniques are used to study the behavior of the interdiffusion of a solvent into an entangled polymer matrix as the state of the polymer changes from a melt to a…

Soft Condensed Matter · Physics 2009-11-10 Mesfin Tsige , Gary S. Grest

We consider closed immersed hypersurfaces in $\R^{3}$ and $\R^4$ evolving by a class of constrained surface diffusion flows. Our result, similar to earlier results for the Willmore flow, gives both a positive lower bound on the time for…

Differential Geometry · Mathematics 2012-05-29 James McCoy , Glen Wheeler , Graham Williams

We examine the conjectured asymptotic shape of the three dimensional corner growth model [Olejarz et. al.,PRL, 108, 016102 (2012)] by mapping the model onto a restricted solid on solid model on a triangular lattice. By choosing appropriate…

Statistical Mechanics · Physics 2015-06-12 Rajeev Singh , R. Rajesh

This article proposes an active learning method for high dimensional data, based on intrinsic data geometries learned through diffusion processes on graphs. Diffusion distances are used to parametrize low-dimensional structures on the…

Machine Learning · Computer Science 2019-05-31 Mauro Maggioni , James M. Murphy

There are three fundamental physical processes that gives rise to the morphology of a surface: deposition, surface diffusion and desorption. The characteristics of the interfaces generated by the combination of deposition and surface…

Statistical Mechanics · Physics 2007-05-23 Juan R. Sanchez

As a first step to understand anomalous kinetic roughening with multifractality in recent experiments of the vapor deposition polymerization (VDP) growth, we study a simple toy model of the VDP growth in a (1+1)-dimensional lattice, along…

Statistical Mechanics · Physics 2009-02-12 Seung-Woo Son , Meesoon Ha , Hawoong Jeong

Understanding and optimizing thin-film synthesis requires measuring the diffusion length $d_\alpha$ of adsorbed growth precursors. Despite technological advances, in-situ measurements of $d_\alpha$ are often unachievable due to harsh…

A coarse grained model for flexible polymers end-grafted to repulsive spherical nanoparticles is studied for various chain lengths and grafting densities under good solvent conditions, by Molecular Dynamics methods and density functional…

Soft Condensed Matter · Physics 2015-05-18 Federica Lo Verso , Sergei A. Egorov , Andrey Milchev , Kurt Binder