Related papers: Corrugation-Induced First-Order Wetting: An Effect…
We use microscopic density functional theory to study filling transitions in systems with long-ranged wall-fluid and short-ranged fluid-fluid forces occurring in a right-angle wedge. By changing the strength of the wall-fluid interaction we…
We consider fluid wetting on a corrugated substrate using effective interfacial Hamiltonian theory and show that breaking the translational invariance along the wall can induce an 'unbending' phase transition in addition to unbinding. Both…
We present numerical studies of complete, first-order and critical wedge filling transitions, at a right angle corner, using a microscopic fundamental measure density functional theory. We consider systems with short-ranged, cut-off…
Recent analyses of wetting in the semi-infinite two dimensional Ising model, extended to include both a surface coupling enhancement and a surface field, have shown that the wetting transition may be effectively first-order and that…
We study how the formalism of the Hierarchical Reference Theory (HRT) can be extended to inhomogeneous systems. HRT is a liquid state theory which implements the basic ideas of Wilson momentum shell renormalization group (RG) to microscopic…
We present numerical studies of first-order and continuous filling transitions, in wedges of arbitrary opening angle $\psi$, using a microscopic fundamental measure density functional model with short-ranged fluid-fluid forces and…
Recent work on the complete wetting transition for three dimensional systems with short-ranged forces has emphasized the role played by the coupling of order-parameter fluctuations near the wall and depinning interface. It has been proposed…
We study the effect of thermal fluctuations on the wetting phase transitions of infinite order and of continuously varying order, recently discovered within a mean-field density-functional model for three-phase equilibria in systems with…
We address three problems faced by effective interfacial Hamiltonian models of wetting based on a single collective coordinate \ell representing the position of the unbinding fluid interface. Problems (P1) and (P2) refer to the predictions…
Mean field analysis of the effective interfacial Hamiltonian shows that with increasing temperature the adsorption on a periodically corrugated substrate can proceed in two steps: first, there is the filling transition in which the…
Using fundamental-measure density functional theory we investigate entropic wetting in an asymmetric binary mixture of hard spheres with positive non-additivity. We consider a general planar hard wall, where preferential adsorption is…
We show that continuous filling or wedge-wetting transitions are possible in 3D wedge-geometries made from (angled) substrates exhibiting first-order wetting transitions and develop a comprehensive fluctuation theory yielding a complete…
We present results of a microscopic density functional theory study of wedge filling transitions, at a right-angle wedge, in the presence of dispersion-like wall-fluid forces. Far from the corner the walls of the wedge show a first-order…
Replica and functional renormalization group methods show that, with short range substrate forces or in strong fluctuation regimes, wetting of a self-affine rough wall in 2D turns first-order as soon as the wall roughness exponent exceeds…
Critical effects at complete and critical wetting in three dimensions are studied using a coupled effective Hamiltonian H[s(y),\ell]. The model is constructed via a novel variational principle which ensures that the choice of collective…
We report a theoretical and simulation study of the drying and wetting phase transitions of a truncated Lennard-Jones fluid at a flat structureless wall. Binding potential calculations predict that the nature of these transitions depends on…
The excess adsorption $\Gamma $ in two-dimensional Ising strips $(\infty \times L)$ subject to identical boundary fields, at both one-dimensional surfaces decaying in the orthogonal direction $j$ as $-h_1j^{-p}$, is studied for various…
The global phase diagram of wetting in the two-dimensional (2d) Ising model is obtained through exact calculation of the surface excess free energy. Besides a surface field for inducing wetting, a surface-coupling enhancement is included.…
Interfacial fluctuation effects occuring at wedge and cone filling transitions are investigated and shown to exhibit very different characteristics. For both geometries we show how the conditions for observing critical (continuous) filling…
We have studied a simple effective model of charge ordered insulators. The tight binding Hamiltonian consists of the effective on-site interaction U and the intersite density-density interaction Wij (both: nearest-neighbor and…