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The influence of an external flow on the relaxation dynamics of a single polymer is investigated theoretically and numerically. We show that a pronounced dynamical slowdown occurs in the vicinity of the coil-stretch transition, especially…

Chaotic Dynamics · Physics 2007-05-23 Antonio Celani , Alberto Puliafito , Dario Vincenzi

We perform a linear stability analysis of extended domains in phase-separating fluids of equal viscosity, in two dimensions. Using the coupled Cahn-Hilliard and Stokes equations, we derive analytically the stability eigenvalues for long…

Statistical Mechanics · Physics 2009-10-30 Amalie Frischknecht

Entangled polymers are deformed by a strong shear flow. The shape of the polymer, called the form factor, is measured by small angle neutron scattering. However, the real-space molecular structure is not directly available from the…

We investigate through numerical simulations how a two-dimensional crystal yields and flows under an applied shear. We focus over a range that allows us to both address the response in the limit of an infinitesimal shear rate and describe…

Soft Condensed Matter · Physics 2023-10-10 Federico Ghimenti , Misaki Ozawa , Giulio Biroli , Gilles Tarjus

We report on experimental measurements of the flow behavior of a wet, two-dimensional foam under conditions of slow, steady shear. The initial response of the foam is elastic. Above the yield strain, the foam begins to flow. The flow…

Soft Condensed Matter · Physics 2009-11-07 John Lauridsen , Michael Twardos , Michael Dennin

We theoretically study the conformational and dynamical properties of semiflexible active polar ring polymers under linear shear flow. A ring is described as a continuous Gaussian polymer with a tangential active force of a constant density…

Soft Condensed Matter · Physics 2024-07-04 Roland G. Winkler , Sunil P. Singh

This study focuses on comparing the individual polymer chain dynamics in an entangled polymeric liquid under different shear and extension rates. Polymer chains under various shear rates and extension rates were simulated using a…

Chemical Physics · Physics 2021-01-15 Behrouz Behdani , Tong Mou , Cody Spratt , Slava Butcovich , Ryan Gettler , Joontaek Park

Shear induced particle pressure has been measured and modelled for concentrated suspensions of particles. Importantly, the significance of the shear induced particle pressure has not been recognized in polymer rheology. The shear induced…

Soft Condensed Matter · Physics 2019-11-22 Dave E. Dunstan , Dalton J. E. Harvie

The phase-separation process of a binary mixture with order-parameter-dependent mobility under shear flow is numerically studied. The ordering is characterized by an alternate stretching and bursting of domains which produce oscillations in…

Soft Condensed Matter · Physics 2021-12-14 G. Gonnella , A. Lamura

Molecular dynamics simulations were performed for a polymer melt. In quiescent states, the inter-chain interaction energy supported by each particle takes relatively large values persistently for long times if the particle is close to an…

Soft Condensed Matter · Physics 2007-05-23 Ryoichi Yamamoto , Akira Onuki

The occurence of shear bands in a complex fluid is generally understood as resulting from a structural evolution of the material under shear, which leads (from a theoretical perspective) to a non-monotonic stationnary flow curve related to…

Soft Condensed Matter · Physics 2012-06-22 Sylvain Bénito , François Molino , Charles-Henri Bruneau , Thierry Colin , Cyprien Gay

We explore the effect of Couette flow on knotted linear polymer chains with extensive Molecular Dynamics (MD) simulations. Hydrodynamic interactions are accounted for by means of Multi-Particle Collision Dynamics (MPCD). The polymer chain,…

Soft Condensed Matter · Physics 2024-12-10 Andrey Milchev , Maurice P. Schmitt , Peter Virnau

We present some results of recent calculations of rigid rod-like particles in shear flow, based on the Doi model. This is an ideal model system for exhibiting the generic behavior of shear-thinning fluids (polymer solutions, wormlike…

Soft Condensed Matter · Physics 2015-06-25 Peter D. Olmsted , C-Y David Lu

In this work, the nonlinear dynamics of a fully three-dimensional multicomponent vesicle in shear flow are explored. Using a volume- and area-conserving projection method coupled to a gradient-augmented level set and surface phase method,…

Soft Condensed Matter · Physics 2018-05-22 Prerna Gera , David Salac

The stretching of a polymer chain by a large scale chaotic flow is considered. The steady state which emerges as a balance of the turbulent stretching and anharmonic resistance of the chain is quantitatively described, i.e. the dependency…

chao-dyn · Physics 2009-10-31 Michael Chertkov

We present a novel method to investigate the dynamics of a single semiflexible polymer, subject to anisotropic friction in a viscous fluid. In contrast to previous approaches, we do not rely on a discrete bead-rod model, but introduce a…

Biomolecules · Quantitative Biology 2009-11-13 Tobias Munk , Oskar Hallatschek , Chris H. Wiggins , Erwin Frey

Results from numerical simulations of polymers under shear flow are compared with predictions for shear banding based on a model coupling Rolie-Poly-like tube dynamics to the entanglement dynamics mediated by Convected Constraint Release…

Soft Condensed Matter · Physics 2026-04-07 Lucas L. Nelson , Gary S. Grest , Peter D. Olmsted

Associative polymer networks have shown a major promise in fabrication of self-healing and responsive materials. The can also serve as simple models to study more complex biological systems where transient interactions play an important…

Soft Condensed Matter · Physics 2023-12-15 Zuzanna M. Jedlinska , Robert A. Riggleman

We apply monomer-resolved computer simulations of supercoiled ring polymers under shear, taking full account of the hydrodynamic interactions, accompanied, in parallel, by simulations in which these are switched off. The combination of…

Soft Condensed Matter · Physics 2024-04-17 Christoph Schneck , Jan Smrek , Christos N. Likos , Andreas Zöttl

We investigate the effect of flow kinematics on the extensional viscosity of dilute polymer solutions by conducting dissipative particle dynamics simulations under uniaxial, planar, and biaxial extensional flows. At high extension rates,…

Soft Condensed Matter · Physics 2026-03-13 Yusuke Koide , Takato Ishida , Takashi Uneyama , Yuichi Masubuchi