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In a recent letter [Phys. Rev. Lett. {\bf 75}, 2360 (1996)] we briefly discussed the existence and nature of ferroelectric order in positionally disordered dipolar materials. Here we report further results and give a complete description of…

Disordered Systems and Neural Networks · Physics 2009-10-30 G. Ayton , M. J. P. Gingras , G. N. Patey

This paper provides a brief introduction to the phenomenological aspects of the polarization in ferrroelectric materials, and then an analysis of a few selected topics related to the modelling of ferroelectrics. The description of…

Emerging Technologies · Computer Science 2023-11-08 David Esseni , Francesco Driussi , Daniel Lizzit , Marco Massarotto , Mattia Segatto

Relaxor ferroelectrics exhibit exceptional dielectric and electromechanical properties, yet their microscopic origins remain elusive due to the interplay of hierarchical polar structures and chemical complexity. While models based on polar…

Materials Science · Physics 2025-09-03 Yuan-Jinsheng Liu , Tyler C. Sterling , Shi Liu

Interfacial ferroelectricity, prevalent in various parallel-stacked layered materials, allows switching of out-of-plane ferroelectric order by in-plane sliding of adjacent layers. Its resilience against doping potentially enables…

Metal-organic frameworks comprehend a wide class of hybrid organic-inorganic materials with general structure A$_m$BX$_n$, with $A$ and $X$ being organic molecules and B a metal cation. This often results in enhanced structural flexibility…

Materials Science · Physics 2022-04-21 Francesco Foggetti , Alessandro Stroppa , Sergey Artyukhin

Although multiferroics have undergone extensive examination for several decades, the occurrence of ferroelectricity induced by orbital order is only scarcely documented. In this study, we propose the existence of spontaneous ferroelectric…

Materials Science · Physics 2025-01-07 Xiao-Feng Luo , Xu He , Rui Wang , Hongjun Xiang , Jin-Zhu Zhao

Comprehensive review of investigations of substances with a small difference in the energies of the ferroelectric and antiferroelectric types of dipole ordering is presented. Detailed analysis of the stability of homogeneous phases and…

Materials Science · Physics 2018-01-11 V. M. Ishchuk , V. L. Sobolev

The equations for phase transitions temperatures, order parameters and critical concentrations of components have been derived for mixed ferroelectrics. The electric dipoles randomly distributed over the system were considered as a random…

Materials Science · Physics 2007-05-23 M. D. Glinchuk , E. A. Eliseev , V. A. Stephanovich , L. Jastrabik

Relaxor ferroelectrics are complex oxide materials which are rather unique to study the effects of compositional disorder on phase transitions. Here, we study the effects of quenched cubic random electric fields on the lattice instabilities…

Materials Science · Physics 2017-06-14 J. R. Arce-Gamboa , G. G. Guzmán-Verri

Ferroelectric order in polar liquids has been observed in numerical simulations and liquid-crystal experiments. In mean-field frameworks, this behavior is associated to sample-shape dependent, surface contribution to the free energy. This…

Chemical Physics · Physics 2026-02-24 M. G. Izzo

The direction of ferroelectric polarization is prescribed by the symmetry of the crystal structure. Therefore, rotation of the polarization direction is largely limited, despite the opportunity it offers in understanding important…

In this short article, we overview a concept of electronic toroidal multipoles, and their ordering with associated physical properties in non-magnetic and magnetic materials. The toroidal multipoles are introduced as microscopic electronic…

Materials Science · Physics 2024-09-12 Hiroaki Kusunose , Satoru Hayami

The state of art in the theoretical and experimental studies of transition metal doped oxides (dilute magnetic dielectrics) is reviewed. The available data show that the generic non-equilibrium state of oxide films doped with magnetic…

Materials Science · Physics 2009-11-13 K. Kikoin

Ferroelectricity in BaTiO3 was observed nearly eighty years ago, but the mechanism underlying its ferroelectric-paraelectric phase transition remains elusive. The order-disorder transition has been recognized as playing a critical role,…

Materials Science · Physics 2025-10-02 Yang Zhang , Xiaoming Shi , Suk Hyun Sung , Cong Li , Houbing Huang , Pu Yu , Ismail El Baggari

General microscopic mechanism of ferroelectric ordering in chiral smectic C* liquid crystals is considered. It is shown that if the mesogenic molecules have a sufficiently low symmetry, the spontaneous polarization is proportional to one of…

Soft Condensed Matter · Physics 2009-11-13 M. A. Osipov , M. V. Gorkunov

We review the phenomenology of coupled magnetic and electric order parameters for systems in which ferroelectric and incommensurate magnetic order occur simultaneously. We discuss the role that such materials might play in fabricating novel…

Materials Science · Physics 2007-05-23 A. B. Harris , G. Lawes

We present a simple theory for structural transitions in displacive ferroelectrics of the perovskite type. In our theory, the competition between the elastic energy cost for the displacement of the homopolar ion from the centrosymmetric…

Materials Science · Physics 2007-05-23 K. Sheshadri , Rangan Lahiri Pushan Ayyub , Shobo Bhattacharya

A ferroaxial ordering, which appears without mirror symmetry parallel to an electric axial moment, is described by a ferroic alignment of the electric toroidal (ET) dipole rather than the conventional electric and magnetic dipoles. Although…

Strongly Correlated Electrons · Physics 2023-11-23 Akimitsu Kirikoshi , Satoru Hayami

Fluid molecular ferroelectrics are a new class of organic materials where ferroelectricity is found in conjunction with 3D fluidity whilst still retaining spontaneous polarization values comparable to their traditional solid state…

Soft Condensed Matter · Physics 2026-02-19 Calum J Gibb , Jordan Hobbs , William C Ogle , Richard J Mandle

A four-state model is proposed for description of the sequence of phase transitions in ferroelectric crystals of DMAGaS and DMAAlS type. The ordering processes in the subsystems of DMA groups are considered as a main reason of such…

Condensed Matter · Physics 2007-05-23 I. V. Stasyuk , O. V. Velychko
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