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Related papers: Self-interaction correction in the LDA+U method

200 papers

We discuss different methods of calculation of the screened Coulomb interaction $U$ in transition metals and compare the constraint local-density approximation (LDA) with the GW approach. We clarify that they offer complementary methods of…

Strongly Correlated Electrons · Physics 2009-11-10 I. V. Solovyev , M. Imada

The so-called local density approximation plus the multi-orbital mean-field Hubbard model (LDA+U) has been implemented within the all-electron projector augmented-wave method (PAW), and then used to compute the insulating antiferromagnetic…

Strongly Correlated Electrons · Physics 2009-10-31 O. Bengone , M. Alouani , P. Bloechl , J. Hugel

The Hubbard model is investigated in the framework of lattice density functional theory (LDFT). The single-particle density matrix $\gamma_{ij}$ with respect the lattice sites is considered as the basic variable of the many-body problem. A…

Strongly Correlated Electrons · Physics 2009-11-10 R. Lopez-Sandoval , G. M. Pastor

Despite its widespread use, the predictive accuracy of density functional theory (DFT) is hampered by delocalization errors, especially for correlated systems such as transition-metal complexes. Two complementary tuning strategies have been…

Materials Science · Physics 2022-04-11 Yael Cytter , Aditya Nandy , Akash Bajaj , Heather J. Kulik

It is demonstrated that the commonly applied self interaction correction (SIC) used in density functional theory does not remove all self interaction. We present as an alternative a novel method which, by construction, is totally free from…

Materials Science · Physics 2007-05-23 Urban Lundin , Olle Eriksson

We discuss the final state interaction effects at high energies via a multi-channel N/D method. We find that the 2 by 2 charge--exchange final state interactions typically contribute an enhancement factor of a few times $10^{-2}$ in the $B$…

High Energy Physics - Phenomenology · Physics 2015-06-25 Feng Yuan , Hanqing Zheng

In this article, we propose an energy functional at the level of DFT+U+V that allows us to compute self-consistently the values of the on-site interaction, Hubbard U and Hund J, as well as the intersite interaction V. This functional…

Strongly Correlated Electrons · Physics 2020-10-21 Nicolas Tancogne-Dejean , Angel Rubio

We propose a computational scheme for materials where standard Local Density Approximation (LDA) fails to produce a satisfactory description of excitation energies. The method uses Slater's "transition state" approximation and Wannier…

Strongly Correlated Electrons · Physics 2009-11-11 V. I. Anisimov , A. V. Kozhevnikov

The LDA+DMFT method is a very powerful tool for gaining insight into the physics of strongly correlated materials. It combines traditional ab-initio density-functional techniques with the dynamical mean-field theory. The core aspects of the…

Strongly Correlated Electrons · Physics 2017-11-22 Eva Pavarini

The performance of functionals based on the idea of interpolating between the weak and the strong-interaction limits the global adiabatic-connection integrand is carefully studied for the challenging case of noble-metal clusters. Different…

Chemical Physics · Physics 2018-04-18 S. Giarrusso , P. Gori-Giorgi , F. Della Sala , E. Fabiano

For fast and accurate calculations of band gaps of solids, we present an {\it ab initio} method that extends the density functional theory plus on-site Hubbard interaction (DFT+$U$) to include inter-site Hubbard interaction ($V$). This…

Materials Science · Physics 2021-01-14 Sang-Hoon Lee , Young-Woo Son

We present an approach to the DFT+U method (Density Functional Theory + Hubbard model) within which the computational effort for calculation of ground state energies and forces scales linearly with system size. We employ a formulation of…

Strongly Correlated Electrons · Physics 2012-02-14 David D. O'Regan , Nicholas D. M. Hine , Mike C. Payne , Arash A. Mostofi

A framework for developing new approximate electronic structure methods is presented, in which the correlation energy of a many-electron system in the ground state is computed as in the single-reference second-order many-body perturbation…

Chemical Physics · Physics 2011-06-15 Dimitri Laikov

A practical electronic structure method in which a two-body functional is the fundamental variable is constructed. The basic formalism of our method is equivalent to Hartree-Fock density matrix functional theory [M. Levy in {\it Density…

Other Condensed Matter · Physics 2008-04-23 Balazs Hetenyi , Andreas W. Hauser

The Hubbard model is implemented in real-space Green's function calculations of x-ray spectra using an effective self-energy adapted from the LSDA+U method of Anisimov et al. This self-energy consists of an energy-dependent many-pole…

Strongly Correlated Electrons · Physics 2011-07-12 Towfiq Ahmed , J. J. Kas , J. J. Rehr

The density functional theory (DFT)+$U$ method is a pragmatic and effective approach for calculating the ground-state properties of strongly-correlated systems, and linear response calculations are widely used to determine the requisite…

Strongly Correlated Electrons · Physics 2018-12-31 Edward B. Linscott , Daniel J. Cole , Michael C. Payne , David D. O'Regan

In previous papers we showed that a division of the f-shell into two subsystems gives a better understanding of cohesive properties as well the general behavior of lanthanide systems. In this paper we present numerical computations using…

Strongly Correlated Electrons · Physics 2007-05-23 U. Lundin , I. Sandalov , O. Eriksson

Typical density-functional theory calculations that wrongly predict undoped cuprates to be metallic also predict Cu-O half- and full-breathing phonon energies that are significantly softer than observed, presumably because of weak on-site…

Strongly Correlated Electrons · Physics 2021-11-03 Tyler C. Sterling , Dmitry Reznik

The magnetic, noncollinear parametrization of Dudarev's DFT+$U$ method is generalized to fully-relativistic ultrasoft pseudopotentials. We present the definition of the DFT+$U$ total energy functional, and the calculation of forces and…

Materials Science · Physics 2023-10-13 Luca Binci , Nicola Marzari

The GW self-energy method has long been recognized as the gold standard for quasiparticle (QP) calculations of solids in spite of the fact that the neglect of vertex corrections and the use of a DFT starting point lacks rigorous…

Materials Science · Physics 2017-12-06 Per S. Schmidt , Christopher E. Patrick , Kristian S. Thygesen