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We discuss a novel approach, the point-to-set correlation functions, that allows to determine relevant static and dynamic length scales in glass-forming liquids. We find that static length scales increase monotonically when the temperature…

Disordered Systems and Neural Networks · Physics 2013-07-04 Walter Kob , Sandalo Roldan-Vargas , Ludovic Berthier

A few years ago it was showed that some systems that have very similar local structure, as quantified by the pair correlation function, exhibit vastly different slowing down upon supercooling [L. Berthier and G. Tarjus, Phys. Rev. Lett.…

Soft Condensed Matter · Physics 2015-06-17 Elijah Flenner , Hannah Staley , Grzegorz Szamel

We present results of theoretical description and numerical calculation of the dynamics of molecular liquids based on the Reference Interaction Site Model / Mode-Coupling Theory. They include the temperature-pressure(density) dependence of…

Chemical Physics · Physics 2007-05-23 A. E. Kobryn , T. Yamaguchi , F. Hirata

Dynamics near the surface of glasses is generally much faster than in the bulk. Neglecting static perturbations of structure at the surface, we use random first order transition theory to show the free energy barrier for activated motion…

Soft Condensed Matter · Physics 2009-11-13 Jacob D. Stevenson , Peter G. Wolynes

We study the distribution of colloidal particles confined in drying spherical droplets using both dynamic density functional theory (DDFT) and particle-based simulations. In particular, we focus on the advection-dominated regime typical of…

Soft Condensed Matter · Physics 2025-01-24 Mayukh Kundu , Kritika Kritika , Yashraj M. Wani , Arash Nikoubashman , Michael P. Howard

We numerically study a nondisordered lattice spin system with a first order liquid-crystal transition, as a model for supercooled liquids and glasses. Below the melting temperature the system can be kept in the metastable liquid phase, and…

Statistical Mechanics · Physics 2009-11-07 Andrea Cavagna , Irene Giardina , Tomas S. Grigera

Time-dependent density functional theory, proposed recently in the context of atomic diffusion and non-equilibrium processes in solids, is tested against Monte Carlo simulation. In order to assess the basic approximation of that theory, the…

Statistical Mechanics · Physics 2009-11-07 M. Kessler , W. Dieterich , H. L. Frisch , J. F. Gouyet , P. Maass

Slow dynamics of difluorotetrachloroethane in both supercooled plastic crystal and supercooled liquid states have been investigated from Molecular Dynamics simulations. The temperature and wave-vector dependence of collective dynamics in…

Soft Condensed Matter · Physics 2009-11-11 F. Affouard , M. Descamps

Numerical solutions of the mode-coupling theory (MCT) equations for a hard-sphere fluid confined between two parallel hard walls are elaborated. The governing equations feature multiple parallel relaxation channels which significantly…

Soft Condensed Matter · Physics 2020-08-05 Gerhard Jung , Michele Caraglio , Lukas Schrack , Thomas Franosch

We present Monte Carlo simulation results on the equilibrium relaxation dynamics in the two dimensional lattice Coulomb gas, where finite fraction $f$ of the lattice sites are occupied by positive charges. In the case of high order rational…

Statistical Mechanics · Physics 2009-11-07 Sung Jong Lee , Bongsoo Kim , Jong-Rim Lee

Understanding the nanoscale effects controlling the dynamics of a contact line -- defined as the line formed at the junction of two fluid phases and a solid -- has been a longstanding problem in fluid mechanics pushing experimental and…

Fluid Dynamics · Physics 2025-01-06 Andreas Nold , Benjamin D. Goddard , David N. Sibley , Serafim Kalliadasis

Random first order transition theory is used to determine the role of attractive and repulsive interactions in the dynamics of supercooled liquids. Self-consistent phonon theory, an approximate mean field treatment consistent with random…

Soft Condensed Matter · Physics 2007-09-13 Randall W. Hall , Peter G. Wolynes

The mode-coupling theory of the glass transition treats the dynamics of supercooled liquids in terms of two-point density correlation functions. Here we consider a generalized, hierarchical formulation of schematic mode-coupling equations…

Statistical Mechanics · Physics 2014-11-27 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

Odd diffusion breaks time-reversal symmetry in overdamped systems through transverse probability currents while preserving equilibrium steady states. In this work, we develop a dynamical density functional theory (DDFT) for dense…

Soft Condensed Matter · Physics 2026-02-02 Iman Abdoli , René Wittmann , Hartmut Löwen

The mode coupling theory (MCT) of glasses, while offering an incomplete description of glass transition physics, represents the only established route to first-principles prediction of rheological behavior in nonergodic materials such as…

Soft Condensed Matter · Physics 2009-09-29 J. M. Brader , Th. Voigtmann , M. Fuchs , R. G. Larson , M. E. Cates

In supercooled liquids, at a temperature between the glass transition temperature Tg and the melting point Tm, thermodynamic properties remain continuous, while dynamic behavior exhibits anomalies. The origin of such thermodynamics-dynamic…

Soft Condensed Matter · Physics 2025-06-17 X. R. Tian , D. M. Zhang , B. Zhang , D. Y. Sun , X. G. Gong

The complex behavior of confined fluids arising due to a competition between layering and local packing can be disentangled by considering quasi-confined liquids, where periodic boundary conditions along the confining direction restore…

Soft Condensed Matter · Physics 2020-09-03 Lukas Schrack , Charlotte F. Petersen , Gerhard Jung , Michele Caraglio , Thomas Franosch

Using conceptually and procedurally consistent density functional theory (DFT) calculations with an advanced meta-GGA exchange-correlation functional in ab initio molecular dynamics simulations, we determine the insulator-metal transition…

Ferrofluid heating by an external alternating field is studied based on the rigid dipole model, where the magnetization of each particle in a fluid is supposed to be firmly fixed in the crystal lattice. Equations of motion, employing the…

Mesoscale and Nanoscale Physics · Physics 2018-05-23 T. V. Lyutyy , V. V. Reva

We use Brownian dynamics simulations of a binary mixture of highly charged spherical colloidal particles to illustrate many of the implications of the Random First Order Transition (RFOT) theory (PRA 40 1045 (1989)), which is the only…

Statistical Mechanics · Physics 2015-06-12 Hongsuk Kang , T. R. Kirkpatrick , D. Thirumalai