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With the empirical bond polarizability model, the nonresonant Raman spectra of the chiral and achiral single-wall carbon nanotubes (SWCNTs) under uniaxial and torsional strains have been systematically studied by \textit{ab initio} method.…

Mesoscale and Nanoscale Physics · Physics 2007-07-31 Gang Wu , Jian Zhou , Jinming Dong

Phonon softening phenomena of the $\Gamma$ point optical modes including the longitudinal optical mode, transverse optical mode and radial breathing mode in "metallic" single wall carbon nanotubes are reviewed from a theoretical point of…

Mesoscale and Nanoscale Physics · Physics 2010-05-13 K. Sasaki , H. Farhat , R. Saito , M. S. Dresselhaus

A phonon frequency shift of the radial breathing mode for metallic single wall carbon nanotubes is predicted as a function of Fermi energy. Armchair nanotubes do not show any frequency shift while zigzag nanotubes exhibit phonon softening,…

Mesoscale and Nanoscale Physics · Physics 2008-12-05 K. Sasaki , R. Saito , G. Dresselhaus , M. S. Dresselhaus , H. Farhat , J. Kong

We have used a femtosecond pump-probe impulsive Raman technique to explore the ultrafast dynamics of micelle suspended single walled carbon nanotubes (SWNTs) in various pH environments. The structures of coherent phonon spectra of the…

Mesoscale and Nanoscale Physics · Physics 2010-11-17 Kotaro Makino , Atsushi Hirano , Kentaro Shiraki , Yutaka Maeda , Muneaki Hase

In this study, we performed comprehensive investigations on the Raman active phonon modes in cubic bixbyite In$_2$O$_3$, an important oxide based, wide-bandgap semiconductor. Fundamental insights into the lattice dynamics are revealed, by…

We review recent studies of coherent phonons (CPs) corresponding to the radial breathing mode (RBM) and G-mode in single-wall carbon nanotubes (SWCNTs) and graphene. Because of the bandgap-diameter relationship, RBM-CPs cause bandgap…

Mesoscale and Nanoscale Physics · Physics 2013-03-28 J. -H. Kim , A. R. T. Nugraha , L. G. Booshehri , E. H. Hároz , K. Sato , G. D. Sanders , K. -J. Yee , Y. -S. Lim , C. J. Stanton , R. Saito , J. Kono

Coherent phonons in single wall carbon nanotubes (SWNTs) are observed as oscillations of the differential absorption coefficient as a function of time by means of pump-probe spectroscopy. For the radial breathing mode (RBM) of a SWNT, the…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 A. R. T. Nugraha , E. H. Hasdeo , G. D. Sanders , C. J. Stanton , R. Saito

Raman spectroscopy is used to probe the structure and electronic properties of nanotubes dispersed in a liquid phase. We show that the radial breathing modes are upshifted in suspensions due to the molecular pressure of the solvent. On the…

Other Condensed Matter · Physics 2016-08-16 Nicolas Izard , Alain Pénicaud , Eric Anglaret

We have studied the coherent dynamics of G-band phonons in single-walled carbon nanotubes through impulsive stimulated Stokes and anti-Stokes Raman scattering. The probe energy dependence of phonon amplitude as well as preferential…

Mesoscale and Nanoscale Physics · Physics 2012-11-13 J. -H. Kim , K. -J. Yee , Y. -S. Lim , L. G. Booshehri , E. H. Haroz , J. Kono

We investigate vibration modes and their Raman activity of single-walled carbon nanotubes that are bent within their intrinsic elastic limits. By implementing novel boundary conditions for density-functional based tight-binding, and using…

Materials Science · Physics 2009-11-13 Sami Malola , Hannu Häkkinen , Pekka Koskinen

Using the molecular dynamics simulations and the force constant model we have studied the Raman-active tangential modes (TMs) of a (10, 0) single-wall carbon nanotube (SWNT) under hydrostatic pressure. With increasing pressure, the atomic…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Wei Yang , Ru-Zhi Wang , Yu-Fang Wang , Xue-Mei Song , Bo Wang , Hui Yan

Raman spectra and electrical conductance of individual, pristine, suspended, metallic single-walled carbon nanotubes are measured under applied gate potentials. The G- band is observed to downshift with small applied gate voltages, with the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Adam W. Bushmaker , Vikram V. Deshpande , Scott Hsieh , Marc W. Bockrath , Stephen B. Cronin

We present a first-principles study on lattice vibrational modes of Si/Ge core-shell nanowires (NWs). In addition to quantum confinement, the internal strain induced by the lattice mismatch between core and shell contributes to significant…

Mesoscale and Nanoscale Physics · Physics 2012-07-04 Shouting Huang , Li Yang

The tangential G-band in the Raman spectra of a metallic single-wall carbon nanotube shows two peaks: a higher frequency component having the Lorentzian shape and a lower-frequency component of lower intensity with a Breit-Wigner-Fano…

Other Condensed Matter · Physics 2009-11-11 S. M. Bose , S. Gayen , S. N. Behera

In this paper, we investigate the low frequency Raman spectra of multi-wall carbon nanotubes (MWNT) prepared by the electric arc method. Low frequency Raman modes are unambiguously identified on purified samples thanks to the small internal…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 J. M. Benoit , J. P. Buisson , O. Chauvet , C. Godon , S. Lefrant

Large variations of up to two orders of magnitude are observed in the Raman intensity of pristine, suspended quasi-metallic single-walled carbon nanotubes in response to applied gate potentials. No change in the resonance condition is…

Mesoscale and Nanoscale Physics · Physics 2009-05-07 Adam W. Bushmaker , Vikram V. Deshpande , Scott Hsieh , Marc W. Bockrath , Stephen B. Cronin

The radial-breathing-like phonon modes (RBLMs) of the double-walled carbon nanotubes are studied in a simple analytical model, in which the interaction force constants (FCs) can be obtained analytically from the continuous model. The RBLMs…

Mesoscale and Nanoscale Physics · Physics 2007-07-31 Gang Wu , Jian Zhou , Jinming Dong

We report the existence of broad and weakly asymmetric features in the high-energy (G) Raman modes of freely suspended metallic carbon nanotubes of defined chiral index. A significant variation in peak width (from 12 cm-1 to 110 cm-1) is…

We develop a continuous theory of low-frequency dynamics for nanotubes with truly two-dimensional (2D) walls constituted by single-atom monolayer. In this frame topological bending elasticity of the monolayer is not related to its vanishing…

Materials Science · Physics 2015-06-16 S. B. Rochal , V. L. Lorman , Yu. I. Yuzyuk

The Raman spectra of two G-bands and a radial breathing mode (RBM) of unfilled and filled single-wall semiconducting and metallic carbon nanotubes have been investigated theoretically, in the presence of electron-phonon and phonon-phonon…

Other Condensed Matter · Physics 2009-11-13 S. Gayen , S. N. Behera , S. M. Bose
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