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We have observed large-amplitude coherent phonon oscillations of radial breathing modes (RBMs) in single-walled carbon nanotubes excited through the lowest-energy (E11) interband transitions. In contrast to the previously-studied coherent…

Mesoscale and Nanoscale Physics · Physics 2010-08-11 Y. -S. Lim , J. -G. Ahn , J. -H. Kim , K. -J. Yee , T. Joo , S. -H. Baik , E. H. Haroz , L. G. Booshehri , J. Kono

We present a theoretical model to describe the double-resonant scattering process in arbitrary carbon nanotubes. We use this approach to investigate the defect-induced $D$ mode in CNTs and unravel the dependence of the $D$-mode frequency on…

Materials Science · Physics 2016-01-20 Felix Herziger , Asmus Vierck , Jan Laudenbach , Janina Maultzsch

Raman excitation and emission spectra for the radial breathing mode (RBM) are reported, together with a preliminary analysis. From the position of the peaks on the two-dimensional plot of excitation resonance energy against Raman shift, the…

Mesoscale and Nanoscale Physics · Physics 2012-05-11 A. J. Ghandour , A. Sapelkin , I. Hernandez , D. J. Dunstan , I. F. Crowe , M. P. Halsall

We have performed first-principles calculations to study the lattice vibrational modes and their Raman activities in silicon nanowires (SiNWs). Two types of characteristic vibrational modes are examined: high-frequency optical modes and…

Mesoscale and Nanoscale Physics · Physics 2011-08-30 Li Yang , M. Y. Chou

We have generated and detected the radial-breathing mode of coherent lattice vibrations in single-walled carbon nanotubes using ultrashort laser pulses. Because the band gap is a function of diameter, these diameter oscillations cause…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Y. S. Lim , K. J. Yee , J. H. Kim , J. Shaver , E. H. Haroz , J. Kono , S. K. Doorn , R. H. Hauge , R. E. Smalley

In this paper, we provide a detailed expression of the vibrational potential for the lattice dynamics of the single-wall carbon nanotubes (SWCNT) satisfying the requirements of the exact rigid translational as well as rotational symmetries,…

Materials Science · Physics 2007-05-23 Jin-Wu Jiang , Hui Tang , Bing-Shen Wang , Zhao-Bin Su

Raman spectroscopy has been the most extensively employed method to study carbon nanotubes at high pressures. This review covers reversible pressure-induced changes of the lattice dynamics and structure of single- and multi-wall carbon…

Condensed Matter · Physics 2009-09-29 I. Loa

Intrinsic optical transition energies for isolated and individual single wall carbon nanotubes grown over trenches are measured using tunable resonant Raman scattering. Previously measured E22_S optical transitions from nanotubes in…

We study the phonon modes in single-walled MoS$_{2}$ nanotubes via the lattice dynamics calculation and molecular dynamics simulation. The phonon spectra for tubes of arbitrary chiralities are calculated from the dynamical matrix…

Materials Science · Physics 2014-03-19 Jin-Wu Jiang , Bing-Shen Wang , Timon Rabczuk

The analysis of the Raman scattering cross section of the radial breathing modes of double-wall carbon nanotubes allowed to determine the optical transitions of the inner tubes. The Raman lines are found to cluster into species with similar…

Soft Condensed Matter · Physics 2007-05-23 R. Pfeiffer , F. Simon , H. Kuzmany , V. N. Popov

Using electron diffraction on free-standing single-walled carbon nanotubes we have determined the structural indices (n,m) of tubes in the diameter range from 1.4 to 3nm. On the same free-standing tubes we have recorded Raman spectra of the…

We present a resonance Raman study of the disorder-induced D mode in a sample highly enriched with semiconducting (9,7) single-walled carbon nanotubes in the excitation energy range of 1.49 - 2.05 eV. The intensity of the D mode shows a…

Materials Science · Physics 2015-06-12 Jan Laudenbach , Frank Hennrich , Hagen Telg , Manfred Kappes , Janina Maultzsch

Using a macroscopic ensemble of highly-enriched (6,5) single-wall carbon nanotubes, combined with high signal-to-noise ratio, time-dependent differential transmission spectroscopy, we have generated vibrational modes in an ultrawide…

The quantum corrections to the frequencies of the $\Gamma$ point longitudinal optical (LO) and transverse optical (TO) phonon modes in carbon nanotubes are investigated theoretically. The frequency shift and broadening of the TO phonon mode…

Mesoscale and Nanoscale Physics · Physics 2008-07-07 K. Sasaki , R. Saito , G. Dresselhaus , M. S. Dresselhaus , H. Farhat , J. Kong

Using the density functional theory calculations, we show that the oxygen functional groups exhibit unexpected spontaneously dynamic behaviors on the interior surface of single-walled carbon nanotubes (SWCNT). Two types of dynamic oxygen…

Materials Science · Physics 2021-12-03 Guangdong Zhu , Zhijing Huang , Liang Zhao , Yusong Tu

The dipole-dipole interactions between excitons are of paramount importance in the nanoscale structures. When two excitons are placed together they can exchange the energy can manifest in the resonant Raman cross sections. We provide…

Mesoscale and Nanoscale Physics · Physics 2024-04-09 Anna Wroblewska , Niclas S. Mueller , Mariusz Zdrojek , Stephanie Reich , Georgy Gordeev

We show by ab initio calculations that the electron-phonon coupling matrix element M of the radial breathing mode in single-walled carbon nanotubes depends strongly on tube chirality. For nanotubes of the same diameter the coupling strength…

Materials Science · Physics 2009-11-10 M. Machon , S. Reich , H. Telg , J. Maultzsch , P. Ordejon , C. Thomsen

The dynamics of the one-dimensional array of the single-walled carbon nanotubes, which interact by van der Waals forces, is considered. The molecular dynamics simulation shows that both the mutual displacements of the nanotubes and the…

Mesoscale and Nanoscale Physics · Physics 2022-09-07 Valeri V. Smirnov

Bending-mode vibrations of carbon nanotube resonator devices were mechanically detected in air at atmospheric pressure by means of a novel scanning force microscopy method. The fundamental and higher order bending eigenmodes were imaged at…

Mesoscale and Nanoscale Physics · Physics 2012-07-12 D. Garcia-Sanchez , A. San Paulo , M. J. Esplandiu , F. Perez-Murano , L. Forro , A. Aguasca , A. Bachtold

The pressure response of double-wall carbon nanotubes has been investigated by means of Raman spectroscopy up to 10 GPa. The intensity of the radial breathing modes of the outer tubes decreases rapidly but remain observable up to 9 GPa,…