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Modeling layered intercalation compounds from first principles poses a problem, as many of their properties are determined by a subtle balance between van der Waals interactions and chemical or Madelung terms, and a good description of van…

Materials Science · Physics 2014-10-30 E. Hazrati , G. A. de Wijs , G. Brocks

Graphene on silicon carbide (SiC) bears great potential for future graphene electronic applications because it is available on the wafer-scale and its properties can be custom-tailored by inserting various atoms into the graphene/SiC…

Materials Science · Physics 2018-11-07 T. A. de Jong , E. E. Krasovskii , C. Ott , R. M. Tromp , S. J. van der Molen , J. Jobst

In this paper, we predict the existence of low-frequency nonlocal plasmon excitations at the vacuum-surface interface of a superlattice of $N$ graphene layers interacting with a thick conducting substrate. This is different from graphite…

Mesoscale and Nanoscale Physics · Physics 2015-08-11 Godfrey Gumbs , Andrii Iurov , Jhao-Ying Wu , M. F. Lin , Paula Fekete

Close to charge neutrality, the low-energy properties of high-quality suspended devices based on atomically thin graphene layers are determined by electron-electron interactions. Bernal-stacked layers, in particular, have shown a remarkable…

Strongly Correlated Electrons · Physics 2016-10-20 Youngwoo Nam , Dong-Keun Ki , Mikito Koshino , Edward McCann , Alberto F. Morpurgo

We study the graphite intercalated compound CaC$_6$ by means of Eliashberg theory, focusing on the anisotropy properties. An analysis of the electron-phonon coupling is performed, and we define a minimal 6-band anisotropy structure.…

Superconductivity · Physics 2012-05-15 A. Sanna , S. Pittalis , J. K. Dewhurst , M. Monni , S. Sharma , G. Ummarino , S. Massidda , E. K. U. Gross

The lubricating ability of graphite largely depends on the environmental humidity, essentially the amount of water in between its layers. In general, intercalated molecules in layered materials modify their extraordinary properties by…

Materials Science · Physics 2019-01-09 A. Qadir , Y. W. Sun , W. Liu , P. Goldberg Oppenheimer , Y. Xu , C. J. Humphreys , D. J. Dunstan

By means of Density Functional Theory calculations we evaluate several lithium carbonate - graphite interface models as a prototype of the Solid Electrolyte Interphase capping layer on graphite anodes in lithium-ion batteries. It is found…

Materials Science · Physics 2016-12-06 Elena Zvereva , Damien Caliste , Pascal Pochet

Functional manipulation of graphene is an important topic in view of both fundamental researches and practical applications. In this study, we show that intercalation of 5$d$ transition metals in epitaxial graphene on SiC is a promising…

Mesoscale and Nanoscale Physics · Physics 2019-03-06 Minsung Kim , Cai-Zhuang Wang , Michael C. Tringides , Myron Hupalo , Kai-Ming Ho

How electron-phonon interactions influence high-temperature superconductivity in cuprates remains contested, and their role outside the CuO$_2$ planes has been largely overlooked. The most conspicuous evidence for such coupling is the…

Graphene exhibits promise as a plasmonic material with high mode confinement that could enable efficient hot carrier extraction. We investigate the lifetimes and mean free paths of energetic carriers in free-standing graphene, graphite and…

Materials Science · Physics 2016-12-28 Prineha Narang , Litao Zhao , Steven Claybrook , Ravishankar Sundararaman

The possibility of superconducting pairing of electrons in doped graphene due to in-plane and out-of-plane phonons is studied. Quadratic coupling of electrons with out-of-plane phonons is considered in details, taking into account both…

Mesoscale and Nanoscale Physics · Physics 2010-05-27 Yu. E. Lozovik , A. A. Sokolik

We present an orbital-resolved density functional theory study on the electronic properties of hydrogen and lithium intercalated graphene grown on the Si face of SiC. Starting from the $(6\sqrt3\times6\sqrt3)R30^{\circ}$ surface…

Mesoscale and Nanoscale Physics · Physics 2012-01-17 I. Deretzis , A. La Magna

Using density functional theory calculations, we have investigated the structural, energetic, and electronic properties of ternary graphite intercalation compounds (GICs) containing alkali atoms (AM) and normal alkylamine molecules (nC$x$),…

Materials Science · Physics 2017-09-20 Gum-Chol Ri , Chol-Jun Yu , Jin-Song Kim , Song-Nam Hong , Un-Gi Jong , Mun-Hyok Ri

Spectral distribution functions of electron-phonon interaction $\alpha^2F(\omega )$ obtained by ab initio linear--response calculations are used to describe various superconducting and transport properties in a number of elemental metals…

Condensed Matter · Physics 2009-10-28 S. Y. Savrasov , D. Y. Savrasov

Strong electron-electron interactions are known to significantly modify the electron-phonon coupling relative to the predictions of density functional theory, but this effect is challenging to calculate with realistic theories of strongly…

Strongly Correlated Electrons · Physics 2025-07-21 David J. Abramovitch , Jennifer Coulter , Sophie Beck , Andrew Millis

Ab initio downfolding describes the electronic structure of materials within a low-energy subspace, often around the Fermi level. Typically starting from mean-field calculations, this framework allows for the calculation of one- and…

On flat bands of the magic-angle twisted bilayer graphene, exotic correlation physics unfolds. Phonons, through mediating an effective electron-electron interaction, can play a crucial role in selecting various electronic phases. In this…

Strongly Correlated Electrons · Physics 2025-07-03 Yi-Jie Wang , Geng-Dong Zhou , Biao Lian , Zhi-Da Song

The interplay between substrate interactions and electron-phonon coupling in two-dimensional (2D) materials presents a significant challenge in understanding and controlling their electronic properties. Here, we present a comparative study…

Materials Science · Physics 2025-01-15 Amjad Al Taleb , Wen Wan , Giorgio Benedek , Miguel M. Ugeda , Daniel Farías

We use ab initio density functional calculations to determine the interaction of a graphene monolayer with the Si(111) surface. We found that graphene forms strong bonds to the bare substrate and accommodates the 12% lattice mismatch by…

Materials Science · Physics 2015-06-15 Ceren Tayran , Zhen Zhu , Matteo Baldoni , Daniele Selli , Gotthard Seifert , David Tománek

We compute electron-phonon coupling (EPC) of selected phonon modes in graphene and graphite using various ab-initio methods. The inclusion of non-local exchange-correlation effects within the GW approach strongly renormalizes the square EPC…

Materials Science · Physics 2008-08-28 Michele Lazzeri , Claudio Attaccalite , Ludger Wirtz , Francesco Mauri
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