Dominant apical-oxygen electron-phonon coupling in HgBa$_2$Ca$_2$Cu$_3$O$_{8+\delta}$
Abstract
How electron-phonon interactions influence high-temperature superconductivity in cuprates remains contested, and their role outside the CuO planes has been largely overlooked. The most conspicuous evidence for such coupling is the ubiquitous 70-meV dispersion kink seen by photoemission, yet its microscopic origin is still debated. Here we use oxygen--edge resonant inelastic X-ray scattering (RIXS) to probe the trilayer cuprate HgBaCaCuO (Hg1223). When both incident photon energy and polarization are tuned to the apical-oxygen transition, the RIXS spectra exhibit a ladder of at least ten phonon overtones, evenly spaced by 70 meV, whose intensities follow a Franck-Condon envelope, signalling exceptionally strong electron-phonon coupling. Quantitative modelling that incorporates core-hole lifetime evaluation yields an apical-phonon coupling energy of 0.25(1) eV, significantly larger than that of the planar stretching mode. Such a coupling strength offers a strong contender for explaining the universal 70-meV kink and suggests that the dominant electron-phonon channel resides outside the CuO planes. By elevating inter-layer lattice dynamics from a peripheral factor to a central actor, our results provide a fresh starting point for theories seeking to reconcile strong correlations, lattice dynamics and high-temperature superconductivity.
Keywords
Cite
@article{arxiv.2505.00223,
title = {Dominant apical-oxygen electron-phonon coupling in HgBa$_2$Ca$_2$Cu$_3$O$_{8+\delta}$},
author = {Wenshan Hong and Qizhi Li and Shilong Zhang and Qian Xiao and Sahil Tippireddy and Jie Li and Yuchen Gu and Shichi Dong and Taimin Miao and Xiangyu Luo and Xianghong Jin and Lin Zhao and Xingjiang Zhou and Ke-Jin Zhou and Yi Lu and Yingying Peng and Yuan Li},
journal= {arXiv preprint arXiv:2505.00223},
year = {2025}
}
Comments
33 pages, 15 figures; comments are welcome