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We report extensive simulations of the relaxation dynamics of a self-avoiding polymer confined inside a cylindrical pore. In particular, we concentrate on examining how confinement influences the scaling behavior of the global relaxation…

Soft Condensed Matter · Physics 2009-11-13 A. Arnold , B. Bozorgui , D. Frenkel , B. -Y. Ha , S. Jun

The tube-like cages of stiff polymers in entangled solutions have been shown to exhibit characteristic spatial heterogeneities. We explain these observations by a systematic theory generalizing previous work by D. Morse (Phys. Rev. E…

Soft Condensed Matter · Physics 2011-11-07 Jens Glaser , Klaus Kroy

Self-diffusion and radial distribution functions are studied in a strongly confined Lennard-Jones fluid. Surprisingly, in the solid-liquid phase transition region, where the system exhibits dynamic coexistence, the self-diffusion constants…

Statistical Mechanics · Physics 2016-02-11 N. de Sousa , J. J. Sáenz , Frank Scheffold , A. García Martín , L. S. Froufe-Pérez

The conformations of semiflexible (bio)polymers are studied in flow through geometrically structured microchannels. Using mesoscale hydrodynamics simulations, we show that the polymer undergoes a rod-to-helix transition as it moves from the…

Soft Condensed Matter · Physics 2012-10-24 Raghunath Chelakkot , Roland G. Winkler , Gerhard Gompper

We investigate the length distribution of self-assembled, long and stiff polymers at thermal equilibrium. Our analysis is based on calculating the partition functions of stiff polymers of variable lengths in the elastic regime. Our…

Soft Condensed Matter · Physics 2012-09-06 Chiu Fan Lee

Typical device architectures in polymer-based optoelectronic devices, such as field effect transistors organic light emitting diodes and photovoltaic cells include sub-100 nm semiconducting polymer thin-film active layers, whose…

We revisit the classical problem of a polymer confined in a slit in both of its static and dynamic aspects. We confirm a number of well known scaling predictions and analyse their range of validity by means of comprehensive Molecular…

We study the dynamics of a single chain polymer confined to a two dimensional cell. We introduce a kinetically constrained lattice gas model that preserves the connectivity of the chain, and we use this kinetically constrained model to…

Statistical Mechanics · Physics 2011-11-09 Armin Rahmani , Claudio Castelnovo , Jeremy Schmit , Claudio Chamon

A variational framework is developed to examine the equilibrium states of a semi-flexible polymer that is constrained to lie on a fixed surface. As an application the confinement of a closed polymer loop of fixed length $2\pi R$ within a…

Soft Condensed Matter · Physics 2012-02-17 Jemal Guven , Pablo Vázquez-Montejo

We explore the elastic behavior of a wormlike chain under compression in terms of exact solutions for the associated probability densities. Strikingly, the probability density for the end-to-end distance projected along the applied force…

Soft Condensed Matter · Physics 2019-11-11 Christina Kurzthaler , Thomas Franosch

The impact of confinement on self-assembly of particles interacting with short-range attraction and long-range repulsion (SALR) potential is studied for thermodynamic states corresponding to local ordering of clusters or layers in the bulk.…

Soft Condensed Matter · Physics 2014-11-17 Jakub Pękalski , Alina Ciach , Noé G. Almarza

Semiflexible polymers form central structures in biological material. Modeling approaches usually neglect influences of polymer-specific molecular features aiming to describe semiflexible polymers universally. Here, we investigate the…

We use computer simulations and scaling arguments to investigate statistical and structural properties of a semiflexible ribbon composed of isosceles triangles. We study two different models, one where the bending energy is calculated from…

Statistical Mechanics · Physics 2009-11-07 Boris Mergell , Mohammad R. Ejtehadi , Ralf Everaers

The requirement that packings of hard particles, arguably the simplest structural glass, cannot be compressed by rearranging their network of contacts is shown to yield a new constraint on their microscopic structure. This constraint takes…

Statistical Mechanics · Physics 2015-06-04 Matthieu Wyart

Twist stiffness and an asymmetric bending stiffness of a polymer or a polymer bundle is captured by the elastic ribbon model. We investigate the effects a ring geometry induces to a thermally fluctuating ribbon, finding bend-bend coupling…

Biomolecules · Quantitative Biology 2008-02-07 Karen Alim , Erwin Frey

We present a semi-analytical approach to the determination of the dynamic properties of randomly branched polymers under the Rouse approximation. The principle procedure is based on examining a spectrum of eigenvalues which represents the…

Statistical Mechanics · Physics 2009-10-31 Josh P. Kemp , Zheng Yu Chen

We investigate the dynamics of a single semiflexible filament, under the action of a compressing force, using numerical simulations and scaling arguments. The force is applied along the end to end vector at one extremity of the filament,…

Soft Condensed Matter · Physics 2009-11-07 P. Ranjith , P. B. Sunil Kumar

A number of strange results have been reported for the twist elasticity of a semiflexible filament, actin. In particular dynamic and static methods for determining the torsional twist modulus give very different results. I show here that…

Soft Condensed Matter · Physics 2007-05-23 A. C. Maggs

An important quantity in liquid state theory is the radial distribution function $g(r)$. It can be calculated within the framework of classical density functional theory in two very distinct ways. In the test-particle route, one fixes a…

Soft Condensed Matter · Physics 2026-04-08 Michael Wassermair , Gerhard Kahl , Andrew J Archer , Roland Roth

We present using simple scaling arguments and one step replica symmetry breaking a theory for the localization of semiflexible polymers in a quenched random environment. In contrast to completely flexible polymers, localization of…

Soft Condensed Matter · Physics 2009-11-10 Arti Dua , Thomas A. Vilgis
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