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Work is one of the most basic notion in statistical mechanics, with work fluctuation theorems being one central topic in nanoscale thermodynamics. With Hamiltonian chaos commonly thought to provide a foundation for classical statistical…

Statistical Mechanics · Physics 2017-02-01 Jiawen Deng , Alvis Mazon Tan , Peter Hanggi , Jiangbin Gong

Research on the out-of-equilibrium dynamics of quantum systems has so far produced important statements on the thermodynamics of small systems undergoing quantum mechanical evolutions. Key examples are provided by the Crooks and Jarzynski…

We theoretically explore the Bochkov-Kuzovlev-Jarzynski-Crooks work theorems in a finite system subject to external control, which is coupled to a heat reservoir. We first elaborate the mechanical energy-balance between the system and the…

Statistical Mechanics · Physics 2015-09-02 Chang Sub Kim

We study temperature fluctuations in mesoscopic $N$-body systems undergoing non-equilibrium processes from the perspective of stochastic thermodynamics. By introducing a stochastic differential equation, we describe the evolution of the…

Statistical Mechanics · Physics 2026-05-19 Zhaoyu Fei , Yu-Han Ma

The imaginary-time path integral representation of the canonical partition function of a quantum system and non-equilibrium work fluctuation relations are combined to yield methods for computing free energy differences in quantum systems…

Statistical Mechanics · Physics 2009-11-13 Ramses van Zon , Lisandro Hernandez de la Pena , Gilles H. Peslherbe , Jeremy Schofield

Fluctuation theorems (FTs) quantify the thermodynamic reversibility of a system, and for deterministic systems they are defined in terms of the dissipation function. However, in a nonequilibrium steady state of deterministic dynamics, the…

Statistical Mechanics · Physics 2026-03-24 Stephen Sanderson , Charlotte F. Petersen , Debra J. Searles

The Fluctuation Theorem (FT) gives an analytic expression for the probability, in a nonequilibrium system of finite size observed for a finite time, that the dissipative flux will flow in the reverse direction to that required by the Second…

Statistical Mechanics · Physics 2007-09-10 Gary Ayton , Denis J. Evans , Debra J. Searles

This is a brief review of recently derived relations describing the behaviour of systems far from equilibrium. They include the Fluctuation Theorem, Jarzynski's and Crooks' equalities, and an extended form of the Second Principle for…

Statistical Mechanics · Physics 2009-11-11 Jorge Kurchan

There is evidence that taking the time average of the work performed by a thermally isolated system effectively "transforms" the adiabatic process into an isothermal one. This approach allows inherent quantities of adiabatic processes to be…

Statistical Mechanics · Physics 2025-10-03 Pierre Nazé

Recent results on the stationary state Fluctuation Theorems for work and heat fluctuations of Langevin systems are presented. The relevance of finite time corrections in understanding experimental and simulation results is explained in the…

Statistical Mechanics · Physics 2007-07-31 E. G. D. Cohen , Ramses van Zon

We derive analogues of the Jarzynski equality and Crooks relation to characterise the nonequilibrium work associated with changes in the spring constant of an overdamped oscillator in a quadratically varying spatial temperature profile. The…

Statistical Mechanics · Physics 2015-09-30 Ian J. Ford , Robert W. Eyre

Fluctuation Theorem(FT) has been studied as far from equilibrium theorem, which relates the symmetry of entropy production. To investigate the application of this theorem, especially to biological physics, we consider the FT for tilted…

Statistical Mechanics · Physics 2009-11-10 T. Monnai

The concept of work is basic for statistical thermodynamics. To gain a fuller understanding of work and its (quantum) features, it needs to be represented as an average of a fluctuating quantity. Here I focus on the work done between two…

Statistical Mechanics · Physics 2015-06-19 A. E. Allahverdyan

The formalism of Kundu et al. [J. Stat. Mech. (2011) P03007], for computing the large deviations of heat flow in harmonic systems, is applied to the case of single Brownian particle in a harmonic trap and coupled to two heat baths at…

Statistical Mechanics · Physics 2012-02-21 Sanjib Sabhapandit

Stochastic thermodynamics is an important development in the direction of finding general thermodynamic principles for non-equilibrium systems. We believe stochastic thermodynamics has the potential to benefit from the measure-theoretic…

Statistical Mechanics · Physics 2023-07-06 Annwesha Dutta , Saikat Sarkar

We derive an integral fluctuation theorem (FT) in a general setup of cavity quantum electrodynamics systems. In the derivation, a key difficulty lies in a diverging behavior of entropy change arising from the zero-temperature limit of an…

Statistical Mechanics · Physics 2020-02-19 Tatsuro Yuge , Makoto Yamaguchi

For driven open systems in contact with multiple heat reservoirs, we find the marginal distributions of work or heat do not satisfy any fluctuation theorem, but only the joint distribution of work and heat satisfies a family of fluctuation…

Statistical Mechanics · Physics 2023-03-08 Jin-Fu Chen , H. T. Quan

Two-state models provide phenomenological descriptions of many different systems, ranging from physics to chemistry and biology. We investigate work fluctuations in an ensemble of two-state systems driven out of equilibrium under the action…

Statistical Mechanics · Physics 2009-11-10 F. Ritort

We study the Fluctuation Theorem (FT) for entropy production in chaotic discrete-time dynamical systems on compact metric spaces, and extend it to empirical measures, all continuous potentials, and all weak Gibbs states. In particular, we…

Mathematical Physics · Physics 2026-02-13 Noé Cuneo , Vojkan Jakšić , Claude-Alain Pillet , Armen Shirikyan

Nonequilibrium systems exchange the energy with an environment in the form of work and heat. The work done on a system obeys the fluctuation theorem, while the dissipated heat which differs from the work by the internal energy change does…

Statistical Mechanics · Physics 2014-02-04 Jae Dong Noh