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Ab initio modeling of molecular electronics is nowadays routinely performed by combining the Density Functional Theory (DFT) and Nonequilibrium Green function (NEGF) techniques. This method has its roots in the current formula given by Meir…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 A. P. Jauho

In this work, we use a combination of first-principles calculations under the density functional theory framework and heat transport simulations using the atomistic Green's function (AGF) method to quantitatively predict the contribution of…

Mesoscale and Nanoscale Physics · Physics 2017-03-01 Sridhar Sadasivam , Ning Ye , James Charles , Kai Miao , Joseph P. Feser , Tillmann Kubis , Timothy S. Fisher

In this work, a new theoretical approach to study the non-equilibrium transport properties of nanoscale systems coupled to metallic electrodes with strong electron-phonon interactions is presented. The proposed approach consists in a…

Mesoscale and Nanoscale Physics · Physics 2013-07-31 R. Seoane Souto , A. Levy Yeyati , A. Martín-Rodero , R. C. Monreal

We present a method for including inelastic scattering in a first-principles density-functional computational scheme for molecular electronics. As an application, we study two geometries of four-atom gold wires corresponding to two…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Thomas Frederiksen , Mads Brandbyge , Nicolas Lorente , Antti-Pekka Jauho

We overview nonequilibrium Green function combined with density functional theory (NEGF-DFT) modeling of independent electron and phonon transport in nanojunctions with applications focused on a new class of thermoelectric devices where a…

Mesoscale and Nanoscale Physics · Physics 2012-04-19 Branislav K. Nikolic , Kamal K. Saha , Troels Markussen , Kristian S. Thygesen

We calculate the effect of electron-vibration coupling on conduction through atomic gold wires, which was measured in the experiments of Agra\"it et al. [Phys. Rev. Lett. 88, 216803 (2002)]. The vibrational modes, the coupling constants,…

Mesoscale and Nanoscale Physics · Physics 2009-05-24 J. K. Viljas , J. C. Cuevas , F. Pauly , M. Häfner

We do parametric calculations to elucidate multi-terminal electron transport properties through a molecular system where a single phenalenyl molecule is attached to semi-infinite one-dimensional metallic leads. A formalism based on the…

Mesoscale and Nanoscale Physics · Physics 2010-05-25 Paramita Dutta , Santanu K. Maiti , S. N. Karmakar

We have modeled transport properties of nanostructures using the Green's function method within the framework of the density-functional theory. The scheme is computationally demanding so that numerical methods have to be chosen carefully. A…

Computational Physics · Physics 2007-05-23 Paula Havu , Ville Havu , Martti J. Puska , Mikko H. Hakala , Adam S. Foster , Risto M. Nieminen

A method for the calculation of the conductance of nanoscale electrical junctions is extended to ab-initio electronic structure methods and applied to realistic models of metallic wires and break-junctions of sodium and gold. The method is…

Materials Science · Physics 2014-05-13 Matthieu J. Verstraete , P. Bokes , R. W. Godby

Phonon transport across a vacuum gap separating intrinsic silicon crystals is predicted via the atomistic Green's function method combined with first-principles calculations of all interatomic force constants. The overlap of electron wave…

Mesoscale and Nanoscale Physics · Physics 2022-01-14 Takuro Tokunaga , Masao Arai , Kazuaki Kobayashi , Wataru Hayami , Shigeru Suehara , Takuma Shiga , Keunhan Park , Mathieu Francoeur

We propose a simple scheme that describes accurately essential non-equilibrium effects in nanoscale electronics devices using equilibrium transport theory. The scheme, which is based on the alignment and dealignment of the junction…

Mesoscale and Nanoscale Physics · Physics 2012-10-01 V. M. García-Suárez , J. Ferrer

Thermoelectrics are a promising class of materials for renewable energy owing to their capability to generate electricity from waste heat, with their performance being governed by a competition between charge and thermal transport. A…

We analyze how functionality could be obtained within single-molecule devices by using a combination of non-equilibrium Green's functions and ab-initio calculations to study the inelastic transport properties of single-molecule junctions.…

Mesoscale and Nanoscale Physics · Physics 2015-06-03 L. K. Dash , H. Ness , M. J. Verstraete , R. W. Godby

First-principle approaches for phonon-limited electronic transport are typically based on many-body perturbation theory and transport equations. With that, they rely on the validity of the quasi-particle picture for electrons and phonons,…

Materials Science · Physics 2024-08-26 Jingkai Quan , Christian Carbogno , Matthias Scheffler

We examine the electronic heat transport phenomena in nanoscale junctions composed of organic molecules coupled to two metallic reservoirs of different temperatures. The electronic heat flux and its dynamical noise properties are calculated…

Mesoscale and Nanoscale Physics · Physics 2016-08-02 Arthur Luniewski , Rita Aghjayan , Kamil Walczak

Vibrationally inelastic electron transport through a flexible molecular junction is investigated. The study is based on a mechanistic model for a biphenyl molecule between two metal electrodes. Employing methods from electron-molecule…

Mesoscale and Nanoscale Physics · Physics 2023-07-26 Martin Cizek , Michael Thoss , Wolfgang Domcke

We use the effective-mass approximation and the density-functional theory with the local-density approximation for modeling two-dimensional nano-structures connected phase-coherently to two infinite leads. Using the non-equilibrium Green's…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Paula Havu , Ville Havu , Martti Puska , Risto Nieminen

One of the fundamental properties of semiconductors is their ability to support highly tunable electric currents in the presence of electric fields or carrier concentration gradients. These properties are described by transport coefficients…

Materials Science · Physics 2020-02-19 Samuel Poncé , Wenbin Li , Sven Reichardt , Feliciano Giustino

The electron transport properties of ZnO nano-wires coupled by two aluminium electrodes were studied by {\it ab initio} method based on non-equilibrium Green's function approach and density functional theory. A clearly rectifying…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Zijiang Yang , Langhui Wan , Yunjin Yu , Yadong Wei , Jian Wang

We study dynamic nonequilibrium electron charging phenomena in ballistic molecular devices at room temperature that compromise their response to bias and whose nature is evidently distinguishable from static Schottky-type potential…

Mesoscale and Nanoscale Physics · Physics 2008-05-13 Ioannis Deretzis , Antonino La Magna