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We study the model of a molecular switch comprised of a molecule with a soft vibrational degree of freedom coupled to metallic leads. In the presence of strong electron-ion interaction, different charge states of the molecule correspond to…

Mesoscale and Nanoscale Physics · Physics 2008-12-18 Fabio Pistolesi , Yaroslav M. Blanter , Ivar Martin

Quasi-forbidden electronic transitions in atoms and quasi-degenerate vibronic transitions in molecules serve as powerful probes of hypothetical temporal variations of fundamental constants. Computation of the sensitivity of a transition to…

Chemical Physics · Physics 2025-11-17 Carsten Zülch , Konstantin Gaul , Robert Berger

A qubit-oscillator junction connecting as a series two bosonic heat baths at different temperatures can display heat valve and diode effects. In particular, the rectification can change in magnitude and even in sign, implying an inversion…

Quantum Physics · Physics 2025-07-15 Luca Magazzù , Elisabetta Paladino , Jukka P. Pekola , Milena Grifoni

The stability of molecular junctions under transport is of the utmost importance for the field of molecular electronics. This question is often addressed within the paradigm of current-induced heating of nuclear degrees of freedom or…

Mesoscale and Nanoscale Physics · Physics 2022-12-26 André Erpenbeck , Yaling Ke , Uri Peskin , Michael Thoss

We investigate the possibility of optical current control through single molecules which are weakly coupled to leads. A master equation approach for the transport through a molecule is combined with a Floquet theory for the time-dependent…

Chemical Physics · Physics 2016-09-08 Jörg Lehmann , Sébastien Camalet , Sigmund Kohler , Peter Hänggi

We report on the room-temperature switching of 1T-TaS2 thin-film charge-density-wave devices, using nanosecond-duration electrical pulsing to construct their time-resolved current-voltage characteristics. The switching action is based upon…

The effect of electrical resistivity switching in nanographite films is described. In difference with cases published elsewhere the switching in nanographite films occurs from stable high conductive to metastable low conductive state.…

Mesoscale and Nanoscale Physics · Physics 2016-06-29 Sergey G. Lebedev

This work explores different mechanisms that induce thermal rectification in the nanoscale. The presence of interacting energy channels combined with simple asymmetries is sufficient for promoting the desired behavior. We use simple quantum…

Mesoscale and Nanoscale Physics · Physics 2018-07-12 Alejandro Marcos-Vicioso , Carmen López-Jurado , Miguel Ruiz-Garcia , Rafael Sánchez

Molecular transistors have the potential for switching with lower gate voltages than conventional field-effect transistors. We have calculated the performance of a single-molecule device in which there is interference between electron…

Mesoscale and Nanoscale Physics · Physics 2016-07-28 Ying Li , Jan Mol , Simon Benjamin , Andrew Briggs

We demonstrate a molecular rectifying junction made from a sequential self-assembly on silicon. The device structure consists of only one conjugated (p) group and an alkyl spacer chain. We obtain rectification ratios up to 37 and threshold…

Conductance switching has been reported in many molecular junction devices, but in most cases has not been convincingly explained. We investigate conductance switching in Pt/stearic acid monolayer/Ti devices using pressure-modulated…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Feng Miao , Douglas Ohlberg , Duncan Stewart , R. Stanley Williams , Chun Ning Lau*

Carbon nanotube Schottky diodes have been fabricated in an all-photolithographic process using dissimilar contact metals on high-frequency compatible substrates (quartz and sapphire). Diodes show near-ideal behavior, and rectify currents of…

Materials Science · Physics 2009-11-13 Enrique Cobas , Michael S. Fuhrer

An exact solution is presented for tunneling through a negative-U d-fold degenerate molecular quantum dot weakly coupled to electrical leads. The tunnel current exhibits hysteresis if the level degeneracy of the negative-U dot is larger…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 A. S. Alexandrov , A. M. Bratkovsky , R. S. Williams

Molecular spintronics is made possible by the coupling between electronic configuration and magnetic po- larization of the molecules. For control and application of the individual molecular states it is necessary to both read and write…

Mesoscale and Nanoscale Physics · Physics 2016-04-27 T. Saygun , J. Bylin , H. Hammar , J. Fransson

Strongly correlated insulators, such as Mott or charge-transfer insulators, exhibit a strong temperature dependence in their resistivity. Consequently, self-heating effects can lead to electrothermal instabilities in planar thin film…

Controlling the direction and magnitude of both heat and electronic currents using rectifiers has significant implications for the advancement of molecular circuit design. In order to facilitate the implementation of new transport phenomena…

Mesoscale and Nanoscale Physics · Physics 2019-08-02 Galen T. Craven , Dahai He , Abraham Nitzan

Within the emerging field of quantum thermodynamics the issues of heat transfer and heat rectification are basic ingredients for the understanding and design of heat engines or refrigerators at nanoscales. Here, a consistent and versatile…

Statistical Mechanics · Physics 2018-11-21 Thomas Motz , Michael Wiedmann , Jürgen T. Stockburger , Joachim Ankerhold

Molecular electronics is a fascinating area of research with the ability to tune device properties by a chemical tailoring of organic molecules. However, molecular electronics devices often suffer from dispersion and lack of reproducibility…

Mesoscale and Nanoscale Physics · Physics 2013-02-11 Nicolas Clement , David Guerin , Stephane Pleutin , Sylvie Godey , Dominique Vuillaume

Transport properties of asymmetric molecular structure are studied within the kinetic equation approach, taking into consideration the electron interaction in the self-consistent manner (SCF procedure). The device is made of a molecule…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Kamil Walczak

The polarization of light is critical in various applications, including quantum communication, where the photon polarization encoding a qubit can undergo uncontrolled changes when transmitted through optical fibers. Bends in the fiber,…

Quantum Physics · Physics 2025-06-03 Niklas Braband , Arman Mansouri , Riza Fazili , Stefanie Czischek , Jeff S. Lundeen