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An explicitly orbital-dependent correlation energy functional is proposed, which is to be used in combination with the orbital-dependent exchange energy functional in energy-band calculations. It bears a close resemblance to the…

Strongly Correlated Electrons · Physics 2009-11-10 Masahiko Higuchi , Hiroshi Yasuhara

A new approach to modelling the behaviour of simple fluids is presented. Starting from the usual expression of the partition function of N molecules, a Fourier transformation is performed. It is argued that the N(N-1)/2 dynamical variables…

Fluid Dynamics · Physics 2020-03-03 Richard Bonneville

We propose a streamlined combination scheme of the transcorrelation (TC) and coupled cluster (CC) theory, which not only increases the convergence rate with respect to the basis set, but also extends the applicability of the lowest order CC…

Strongly Correlated Electrons · Physics 2021-07-28 Ke Liao , Thomas Schraivogel , Hongjun Luo , Daniel Kats , Ali Alavi

We consider a hypothetical substance, where interaction between (within) structural elements of condensed matter (molecules, nanoparticles, clusters, layers, wires etc.) depends on state of Cooper pairs: an additional work must be made…

Superconductivity · Physics 2018-05-02 Konstantin V. Grigorishin

Level density $\rho(E,N,Z)$ is calculated for the two-component close- and open-shell nuclei with a given energy $E$, and neutron $N$ and proton $Z$ numbers, taking into account pairing effects within the microscopic-macroscopic approach…

Nuclear Theory · Physics 2023-08-16 A. G. Magner , A. I. Sanzhur , S. N. Fedotkin , A. I. Levon , U. V. Grygoriev , S. Shlomo

The binding energies of two-dimensional clusters (puddles) of $^4$He are calculated in the framework of the diffusion Monte Carlo method. The results are very well fitted by a mass formula in powers of $x=N^{-1/2}$, where $N$ is the number…

Soft Condensed Matter · Physics 2009-11-10 A. Sarsa , J. Mur-Petit , A. Polls , J. Navarro

The new mathematical framework based on the free energy of pure classical fluids presented in [R. D. Rohrmann, Physica A 347, 221 (2005)] is extended to multi-component systems to determine thermodynamic and structural properties of…

Statistical Mechanics · Physics 2008-11-26 R. D. Rohrmann , J. Zorec

The extent of ion pairing in solution is an important phenomenon to rationalise transport and thermodynamic properties of electrolytes. A fundamental measure of this pairing is the potential of mean force (PMF) between solvated ions. The…

Chemical Physics · Physics 2024-04-11 Niamh O'Neill , Benjamin X. Shi , Kara Fong , Angelos Michaelides , Christoph Schran

The structural property of liquid cesium is investigated in the temperature range 900 K to 1900 K by application of semiempirical effective Lennard-Jones (8.5-4) pair potential function and employing Gillan s algorithm to solve…

Statistical Mechanics · Physics 2007-05-23 Mohammad Hadi Ghatee , Mahmod Sanchooli

It is shown how traditional development of theories of fluids based upon the concept of physical clustering can be adapted to an alternative local clustering definition. The alternative definition can preserve a detailed valence description…

Chemical Physics · Physics 2015-06-26 Lawrence R. Pratt , Randall A. LaViolette

We argue that recently proposed [Melnyk et al., Fluid Phase Equilibr., 2009, Vol. 279, 1] a criterion to split the pair interaction energy into two parts, one of which is forced to be responsible the most accurate as possible for excluded…

Soft Condensed Matter · Physics 2015-04-06 A. Trokhymchuk , R. Melnyk , I. Nezbeda

We extend Wertheim's thermodynamic perturbation theory to derive the association free energy of a multicomponent mixture for which double bonds can form between any two pairs of the molecules' arbitrary number of bonding sites. This…

Soft Condensed Matter · Physics 2021-02-26 Michael P. Howard , Zachary M. Sherman , Delia J. Milliron , Thomas M. Truskett

We develop a coupled-cluster theory for bosonic mixtures of binary species in external traps, providing a promising theoretical approach to demonstrate highly accurately the many-body physics of mixtures of Bose-Einstein condensates. The…

Quantum Gases · Physics 2024-02-01 Anal Bhowmik , Ofir E. Alon

We present and discuss some ideas concerning an ``average-pair-density functional theory'', in which the ground-state energy of a many-electron system is rewritten as a functional of the spherically and system-averaged pair density. These…

Materials Science · Physics 2009-11-11 Paola Gori-Giorgi , Andreas Savin

We present an analytical proof and numerical demonstrations of the equivalence of the correlation energy from particle-particle random phase approximation (pp-RPA) and ladder-couple-cluster-doubles (ladder-CCD). These two theories reduce to…

Chemical Physics · Physics 2013-11-01 Degao Peng , Stephan N. Steinmann , Helen van Aggelen , Weitao Yang

Energy Correlators measure the energy deposited in multiple detectors as a function of the angles between the detectors. In this paper, we analytically compute the three particle correlator in the collinear limit in QCD for quark and gluon…

High Energy Physics - Phenomenology · Physics 2020-11-10 Hao Chen , Ming-Xing Luo , Ian Moult , Tong-Zhi Yang , Xiaoyuan Zhang , Hua Xing Zhu

Previously, it has been shown that the direct correlation function for a Lennard-Jones fluid could be modeled by a sum of that for hard-spheres, a mean-field tail and a simple linear correction in the core region constructed so as to…

Statistical Mechanics · Physics 2008-08-20 James F. Lutsko

Analysis of various mass relations connected with neutron-proton correlations in atomic nuclei is carried out. On the example of $N = Z$ chain it is shown that for self-adjoint nuclei various formulas proposed in literature for $ np $…

Nuclear Theory · Physics 2023-12-11 B. S. Ishkhanov , S. Sidorov , T. Tretyakova , E. Vladimirova

The calculations of the first and the second ionization potentials of lawrencium and lutetium and the electron affinity of lawrencium are performed within the relativistic coupled cluster framework. These results are corrected by including…

We introduce a range-separation approximation to coupled cluster doubles (CCD) theory that successfully overcomes limitations of regular CCD when applied to the uniform electron gas. We combine the short-range ladder channel with the…

Chemical Physics · Physics 2014-05-07 James J. Shepherd , Thomas M. Henderson , Gustavo E. Scuseria
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