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We introduce the electron attachment equation-of-motion pair coupled cluster doubles (EA-EOM-pCCD) ansatz, which allows us to inexpensively compute electron affinities, energies of unoccupied orbitals, and electron attachment spectra. We…

Chemical Physics · Physics 2024-06-24 Marta Gałyńska , Paweł Tecmer , Katharina Bogusławski

We study hydrodynamic limits of the cluster coagulation model; a coagulation model introduced by Norris [$\textit{Comm. Math. Phys.}$, 209(2):407-435 (2000)]. In this process, pairs of particles $x,y$ in a measure space $E$, merge to form a…

Probability · Mathematics 2024-06-19 Luisa Andreis , Tejas Iyer , Elena Magnanini

The capability of density-functional theory to deal with the ground-state of strongly correlated low-dimensional systems, such as semiconductor quantum dots, depends on the accuracy of functionals developed for the exchange and correlation…

Strongly Correlated Electrons · Physics 2009-02-25 S. Pittalis , E. Rasanen , C. Proetto , E. K. U. Gross

The method for calculation of the correlation functions of the Ising-type systems with short-range interaction and with arbitrary value of spin is developed within cluster approximation. For the Ising model (spin $S^z=\pm1$) the expressions…

Condensed Matter · Physics 2007-05-23 R. R. Levitskii , S. I. Sorokov

We present an alternative derivation of the pair correlation function for simple classical fluids by using a variational approach. That approach involves the conditional probability p(3,..., N /1, 2) of an undefined system of N particles…

Statistical Mechanics · Physics 2021-05-10 Richard Bonneville

Cluster Perturbation Theory (CPT) is a computationally economic method commonly used to estimate the momentum and energy resolved single-particle Green's function. It has been used extensively in direct comparisons with experiments that…

Strongly Correlated Electrons · Physics 2020-02-20 P. T. Raum , G. Alvarez , Thomas Maier , V. W. Scarola

Using a molecular dynamics computer simulation we determine the temperature dependence of the partial structure factors for a binary Lennard-Jones system. These structure factors are used as input data to solve numerically the wave-vector…

Condensed Matter · Physics 2016-08-31 Markus Nauroth , Walter Kob

Quantum entanglement is a concept commonly used with reference to the existence of certain correlations in quantum systems that have no classical interpretation. It is a useful resource to enhance the mutual information of memory channels…

Quantum Physics · Physics 2009-11-13 Tina A. C. Maiolo , Fabio Della Sala , Luigi Martina , Giulio Soliani

We show how to detect entanglement with criteria built from simple two-body correlation terms. Since many natural Hamiltonians are sums of such correlation terms, our ideas can be used to detect entanglement by energy measurement. Our…

Quantum Physics · Physics 2007-05-23 Geza Toth , Otfried Gühne

Quantum embedding methods have recently developed significantly to model large molecular structures. This work proposes a novel wave function theory in density functional theory (WTF-in-DFT) embedding scheme based on pair-coupled cluster…

Chemical Physics · Physics 2024-01-10 Rahul Chakraborty , Katharina Boguslawski , Paweł Tecmer

In this work, we assess the accuracy of dielectric-dependent hybrid density functionals and many-body perturbation theory methods for the calculation of electron affinities of small water clusters, including hydrogen-bonded water dimer and…

Chemical Physics · Physics 2017-11-30 Alex P. Gaiduk , Francesco Paesani , Giulia Galli

Some methods for the convergence acceleration of the M{\o}ller-Plesset perturbation series for the correlation energy are discussed. The order-by-order summation is less effective than the Feenberg series. The latter is obtained by…

chem-ph · Physics 2011-08-22 Herbert H. H. Homeier

Theoretical calculations based on the Dirac--Coulomb--Breit relativistic coupled cluster method have been carried out for the electron affinities and ionization potentials of the superheavy element nihonium (Nh) and its lighter homologues…

Atomic Physics · Physics 2022-07-13 Yangyang Guo , Anastasia Borschevsky , Ephraim Eliav , Lukáš F. Pašteka

An effective description for spherical nanoparticles in a fluid of point particles is presented. The points inside the nanoparticles and the point particles are assumed to interact via spherically symmetric additive pair potentials, while…

Statistical Mechanics · Physics 2009-11-13 Ramses van Zon

We study dynamics of clustering in systems containing active particles that are immersed in an explicit solvent. For this purpose we have adopted a hybrid simulation method, consisting of molecular dynamics and multi-particle collision…

Soft Condensed Matter · Physics 2021-01-01 Arabinda Bera , Soudamini Sahoo , Snigdha Thakur , Subir K. Das

We derive an exact, simple relation between the average number of clusters and the wrapping probabilities for two-dimensional percolation. The relation holds for periodic lattices of any size. It generalizes a classical result of Sykes and…

Statistical Mechanics · Physics 2017-01-04 Stephan Mertens , Robert M. Ziff

The dependencies of charged particle pseudorapidity density and transverse energy pseudorapidity density at midrapidity on the collision energy and on the number of nucleon participants, or centrality, measured in nucleus-nucleus collisions…

High Energy Physics - Phenomenology · Physics 2015-04-01 Aditya Nath Mishra , Raghunath Sahoo , Edward K. G. Sarkisyan , Alexander S. Sakharov

We search for approximate, but analytic solutions of the pairing problem for one pair of nucleons in many levels of a potential well. For the collective energy a general formula, independent of the details of the single particle spectrum,…

Nuclear Theory · Physics 2009-11-07 M. Barbaro , R. Cenni , A. Molinari , M. R. Quaglia

Electron pairs have an illustrious history in chemistry, from powerful concepts to understanding structural stability and reactive changes, to the promise of serving as building blocks of quantitative descriptions of the electronic…

We present a Jastrow-factor-inspired variant of coupled cluster theory that accurately describes both weak and strong electron correlation. Compatibility with quantum Monte Carlo allows for variational energy evaluations and an…

Strongly Correlated Electrons · Physics 2013-12-24 Eric Neuscamman