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We study the convergence to equilibrium of a class of nonlinear recombination models. In analogy with Boltzmann's H theorem from kinetic theory, and in contrast with previous analysis of these models, convergence is measured in terms of…

Probability · Mathematics 2018-04-24 Pietro Caputo , Alistair Sinclair

Entropy production for a system not in the thermodynamic limit is formulated using Hill's nanothermodynamics, in which a macroscopic ensemble of such systems is considered. External influence of the environment on the average nanosystem is…

Statistical Mechanics · Physics 2011-03-21 J. Carrete , L. M. Varela , L. J. Gallego

It is observed that the entropy reduction (the information gain in the initial terminology) of an efficient (ideal or pure) quantum measurement coincides with the generalized quantum mutual information of a q-c channel mapping an a priori…

Quantum Physics · Physics 2015-05-20 M. E. Shirokov

Recently a number of approaches has been developed to connect the microscopic dynamics of particle systems to the macroscopic properties of systems in nonequilibrium stationary states, via the theory of dynamical systems. This way a direct…

Statistical Mechanics · Physics 2009-10-31 L. Rondoni , E. G. D. Cohen

The rate of entropy production by a stochastic process quantifies how far it is from thermodynamic equilibrium. Equivalently, entropy production captures the degree to which detailed balance and time-reversal symmetry are broken. Despite…

Statistical Mechanics · Physics 2020-12-02 Luca Cocconi , Rosalba Garcia-Millan , Zigan Zhen , Bianca Buturca , Gunnar Pruessner

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

Entropy might be a not well defined concept if the system can undergo transformations involving stationary nonequilibria. It might be analogous to the heat content (once called ``caloric'') in transformations that are not isochoric (i.e.…

Statistical Mechanics · Physics 2007-05-23 Giovanni Gallavotti

The entropy production rate is a key quantity in non-equilibrium thermodynamics of both classical and quantum processes. No universal theory of entropy production is available to date, which hinders progress towards its full grasping. By…

Quantum Physics · Physics 2020-12-18 Alessio Belenchia , Luca Mancino , Gabriel T. Landi , Mauro Paternostro

In our derivation of the second law of thermodynamics from the relation of adiabatic accessibility of equilibrium states we stressed the importance of being able to scale a system's size without changing its intrinsic properties. This…

Mathematical Physics · Physics 2015-06-19 Elliott H. Lieb , Jakob Yngvason

All of the basic microsopic physical laws are time reversible. In contrast, the second law of thermodynamics, which is a macroscopic physical representation of the world, is able to describe irreversible processes in an isolated system…

Chemical Physics · Physics 2015-06-19 Roland Riek

We show that macroscopic irreversible thermodynamics for viscous fluids can be derived from exact information-theoretic thermodynamic identities valid at the microscale. Entropy production, in particular, is a measure of the loss of…

Statistical Mechanics · Physics 2025-02-17 Danilo Forastiere , Francesco Avanzini , Massimiliano Esposito

Boltzmann defined the entropy of a macroscopic system in a macrostate $M$ as the $\log$ of the volume of phase space (number of microstates) corresponding to $M$. This agrees with the thermodynamic entropy of Clausius when $M$ specifies the…

Statistical Mechanics · Physics 2009-11-10 S. Goldstein , Joel L. Lebowitz

This chapter deals with our recent attempt to extend the notion of equilibrium (EQ) entropy to nonequilibrium (NEQ) systems so that it can also capture memory effects. This is done by enlarging the equilibrium state space by introducing…

Statistical Mechanics · Physics 2022-01-03 P. D. Gujrati

We study the entropy production in a macroscopic nonequilibrium system that undergoes an order-disorder phase transition. Entropy production is a characteristic feature of nonequilibrium dynamics with broken detailed balance. It is found…

Statistical Mechanics · Physics 2016-01-20 Pyoung-Seop Shim , Hyun-Myung Chun , Jae Dong Noh

The work done when a system at thermal equilibrium is externally driven by a unitary control parameter leads to irreversible entropy production. The entropy produced can be thought of as a combination of coherence generation and a…

Quantum Physics · Physics 2024-12-30 Krishna Shende , Kavita Dorai , Arvind

A general method for proving continuity of the von Neumann entropy on subsets of positive trace-class operators is considered. This makes it possible to re-derive the known conditions for continuity of the entropy in more general forms and…

Mathematical Physics · Physics 2015-05-13 M. E. Shirokov

The characterization of irreversibility in general quantum processes is an open problem of increasing techno- logical relevance. Yet, the tools currently available to this aim are mostly limited to the assessment of dynamics induced by…

Quantum Physics · Physics 2017-06-06 Jader P. Santos , Gabriel T. Landi , Mauro Paternostro

We ask the question whether entropy accumulates, in the sense that the operationally relevant total uncertainty about an $n$-partite system $A = (A_1, \ldots A_n)$ corresponds to the sum of the entropies of its parts $A_i$. The Asymptotic…

Quantum Physics · Physics 2022-10-05 Frederic Dupuis , Omar Fawzi , Renato Renner

In earlier work we presented a foundation for the Second Law of Classical Thermodynamics in terms of the Entropy Principle. More precisely, we provided an empirically accessible axiomatic derivation of an entropy function defined on all…

Mathematical Physics · Physics 2015-06-16 Elliott H. Lieb , Jakob Yngvason

Entropy is a very useful concept from physics that tries to explain how a system behaves from a point of view of the thermodynamics. However, there are two ways to explain entropy, and it depends on if we are studying a microsystem or a…

General Finance · Quantitative Finance 2024-07-02 Martin Pomares Calero