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A detailed computational analysis has been performed, considering copper atomic contacts that are exposed directly to water molecules, hydroxyl groups, and monatomic as well as molecular hydrogen and oxygen species. The optimized physical…

Chemical Physics · Physics 2020-02-28 Firuz Demir , Kevin Dean , George Kirczenow

Multiterminal measurements have typically been employed to examine electronic properties of strongly correlated electronic materials such as transition metal oxides without the influence of contact effects. In contrast, in this work we…

Strongly Correlated Electrons · Physics 2010-12-01 A. A. Fursina , R. G. S. Sofin , I. V. Shvets , D. Natelson

Motivated by recent experiments, we present here a systematic ab-initio study of the length dependence of the thermal conductance of single-molecule junctions. We make use of a combination of density functional theory with non-equilibrium…

Mesoscale and Nanoscale Physics · Physics 2016-11-30 J. C. Klöckner , M. Bürkle , J. C. Cuevas , F. Pauly

We present quantum electron transport theory that incorporates dynamical effects of motion of atoms on electrode-molecule interfaces in the calculations of the electric current. The theory is based on non-equilibrium Green's functions. We…

Mesoscale and Nanoscale Physics · Physics 2018-08-14 Vincent F. Kershaw , Daniel S. Kosov

Computationally inexpensive approximations describing electron-phonon scattering in molecular-scale conductors are derived from the non-equilibrium Green's function method. The accuracy is demonstrated with a first principles calculation on…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Magnus Paulsson , Thomas Frederiksen , Mads Brandbyge

A surface-adsorbed molecule is contacted with the tip of a scanning tunneling microscope (STM) at a pre-defined atom. On tip retraction, the molecule is peeled off the surface. During this experiment, a two-dimensional differential…

Mesoscale and Nanoscale Physics · Physics 2024-01-30 C. Toher , R. Temirov , A. Greuling , F. Pump , M. Kaczmarski , M. Rohlfing , G. Cuniberti , F. S. Tautz

Many experiments have shown that the conductance histograms of metallic atomic-sized contacts exhibit a peak structure, which is characteristic of the corresponding material. The origin of these peaks still remains as an open problem. In…

Mesoscale and Nanoscale Physics · Physics 2007-10-02 M. Dreher , F. Pauly , J. Heurich , J. C. Cuevas , E. Scheer , P. Nielaba

Metal/two-dimensional carbon junctions are characterized by using a nanoprobe in an ultrahigh vacuum environment. Significant differences were found in bias voltage (V) dependence of differential conductance (dI/dV) between edge- and…

Mesoscale and Nanoscale Physics · Physics 2012-02-06 Yihong Wu , Ying Wang , Jiayi Wang , Miao Zhou , Aihua Zhang , Chun Zhang , Yanjing Yang , Younan Hua , Baoxi Xu

The magnetic and transport properties of the metal phthalocyanine (MPc) and F$_{16}$MPc (M = Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn and Ag) families of molecules in contact with S-Au wires are investigated by density functional theory within…

Mesoscale and Nanoscale Physics · Physics 2016-01-14 M. M. Fadlallah , U. Eckern , A. H. Romero , U. Schwingenschlögl

We present a theoretical study of the electronic transport through Pt nanocontacts. We show that the analysis of the tunnelling regime requires a very careful treatment of the technical details. For instance, an insufficient size of the…

Mesoscale and Nanoscale Physics · Physics 2017-03-30 Linda A. Zotti , Rubén Pérez

Electronic properties of heterostructures in which a finite number of Mott-insulator layers are sandwiched by semi-infinite metallic leads are investigated by using the dynamical-mean-field method combined with the Keldysh Green's function…

Strongly Correlated Electrons · Physics 2009-11-13 Satoshi Okamoto

The dynamics of a molecular junction consisting of a PTCDA molecule between the tip of a scanning tunneling microscope and a Ag(111) surface have been investigated experimentally and theoretically. Repeated switching of a PTCDA molecule…

We present a computational framework that integrates machine learning with high-throughput \textit{ab initio} calculations to screen over 2.8 million compounds for metallic transport. We identify several intermetallic candidates with…

We present results of electronic structure calculations for well-relaxed Au/benzene-1,4-dithiol/Au molecular contacts, based on density functional theory and the generalized gradient approximation. Electronic states in the vicinity of the…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Udo Schwingenschloegl , Cosima Schuster

Path integral techniques and Green functions formalism are applied to study the (time) temperature dependent scattering of a polaronic quasiparticle by a local anharmonic potential in a bath of diatomic molecules. The electrical resistivity…

Statistical Mechanics · Physics 2009-10-31 Marco Zoli

We investigate charge transport in C$_{60}$-based single-molecule junctions with graphene electrodes employing a combination of density functional theory (DFT) electronic structure calculations and Landauer transport theory. In particular,…

Mesoscale and Nanoscale Physics · Physics 2017-01-12 Susanne Leitherer , Pedro B. Coto , Konrad Ullmann , Heiko B. Weber , Michael Thoss

The energetics and structures of physisorbed and chemisorbed alkanethiols on Au(111) have been systematically investigated up to 10 carbon atoms using van der Waals (vdW) corrected density functional theory (DFT) calculations. The role of…

Chemical Physics · Physics 2018-03-07 Ersen Mete , Merve Yortanlı , Mehmet Fatih Danışman

Quantum transport through single molecules is very sensitive to the strength of the molecule-electrode contact. When a molecular junction weakly coupled to external electrodes, charging effects do play an important role (Coulomb blockade…

Mesoscale and Nanoscale Physics · Physics 2007-10-03 Bo Song

The transport properties of unsubstituted and amino-substituted butanethiol molecules sandwiched between Au electrodes are investigated by using first-principles approaches. New states are observed around the Fermi levels when -NH2 is…

Mesoscale and Nanoscale Physics · Physics 2009-04-06 Chun-Lan Ma , Diu Nghiem , Yu-Chang Chen

Altermagnets (AMs) - magnetic materials that have spin-split bandstructure with zero net spin polarization can be classified as weak or strong depending upon the strength of altermagnetic term in the Hamiltonian. We theoretically…

Mesoscale and Nanoscale Physics · Physics 2026-02-18 Shubham Ghadigaonkar , Sachchidanand Das , Abhiram Soori