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We describe the synthesis and single molecule electrical transport properties of a molecular wire containing a ${\pi}$-extended tetrathiafulvalene (exTTF) group and its charge-transfer complex with F4TCNQ. We form single molecule junctions…

The reversible control of a single spin of an atom or a molecule is of great interest in Kondo physics and a potential application in spin based electronics.Here we demonstrate that the Kondo resonance of manganese phthalocyanine molecules…

We theoretically study the spin-polarized transport through a single-molecule magnet, which is weakly coupled to ferromagnetic leads, by means of the rate-equation approach. We consider both the ferromagnetic and antiferromagnetic…

Mesoscale and Nanoscale Physics · Physics 2012-03-22 Haiqing Xie , Qiang Wang , Bo Chang , Hujun Jiao , J. -Q. Liang

We investigate the possibility of optical current control through single molecules which are weakly coupled to leads. A master equation approach for the transport through a molecule is combined with a Floquet theory for the time-dependent…

Chemical Physics · Physics 2016-09-08 Jörg Lehmann , Sébastien Camalet , Sigmund Kohler , Peter Hänggi

We investigate the electronic transport through a molecule in the Kondo regime. The tunneling between the electrode and the molecule is asymmetrically modulated by the oscillations of the molecule, i.e., if the molecule gets closer to one…

Mesoscale and Nanoscale Physics · Physics 2008-12-09 J. Mravlje , A. Ramsak

Electronic transport in a model molecular device coupled to local phonon modes is theoretically analyzed. The method allows for obtaining an accurate approximation of the system's quantum state irrespective of the electron and phonon energy…

Mesoscale and Nanoscale Physics · Physics 2007-10-10 Antonino La Magna , Ioannis Deretzis

In this contribution we demonstrate structural control over a transport resonance in HS(CH$_{2}$)$_{n}$[1,4 - C$_{6}$H$_{4}$](CH$_{2}$)$_{n}$SH (n = 1, 3, 4, 6) metal - molecule - metal junctions, fabricated and tested using the scanning…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Carly Brooke , Andrea Vezzoli , Simon J. Higgins , Linda A. Zotti , J. J. Palacios , Richard J. Nichols

We present a theory of single-electron tunneling transport through a ferromagnetic nanoparticle in which particle-hole excitations are coupled to spin collective modes. The model employed to describe the interaction between quasiparticles…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 L. Michalak , C. M. Canali , V. G. Benza

In all theoretical treatments of electron transport through single molecules between two metal electrodes, a clear distinction has to be made between a coherent transport regime with a strong coupling throughout the junction and a Coulomb…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Robert Stadler , Jerome Cornil , Victor Geskin

Here, we present theoretical analysis of electron transport in polyaniline based (PANi) nanofibers assuming the metalic state of the material. To build up this theory we treat conducting polymers as a special kind of granular metals, and we…

Soft Condensed Matter · Physics 2012-08-27 Natalya A. Zimbovskaya , Alan T. Johnson, , Nicholas J. Pinto

It is often intriguing experimentally to take stock of how conformational changes in the device configuration may impact the overall charge transport behavior of single-molecule junctions. Based on the allied approach of density functional…

Mesoscale and Nanoscale Physics · Physics 2020-02-06 Talem Rebeda Roy , Arijit Sen

The influence of vibrational motion on electron conduction through single molecules bound to metal electrodes is investigated employing first-principles electronic-structure calculations and projection-operator Green's function methods.…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 C. Benesch , M. Thoss , W. Domcke , M. Cizek

A nanodevice consisting of a conductive cylinder in an axial magnetic field with one-dimensional wires attached to its lateral surface is considered. An explicit form for transmission and reflection coefficients of the system as a function…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 V. A. Margulis , M. A. Pyataev

In the field of molecular electronics, particularly in quantum transport studies, the orientation of molecules plays a crucial role. This orientation, with respect to the electrodes, can be defined through the cavity of ring-shaped…

Materials Science · Physics 2023-02-17 A. Martinez-Garcia , T. de Ara , L. Pastor-Amat , C. Untiedt , E. B. Lombardi , W. Dednam , C. Sabater

We present a theoretical study of the electronic transport through single-molecule junctions incorporating a Pt6 metal cluster bound within an organic framework. We show that the insertion of this molecule between a pair of electrodes leads…

Mesoscale and Nanoscale Physics · Physics 2013-02-27 Linda A. Zotti , Edmund Leary , Maria Soriano , Juan Carlos Cuevas , Juan Jose Palacios

We report first-principles studies of electronic transport in monolayers of Tour wires functionalized with different side groups. An analysis of the scattering states and transmission eigenchannels suggests that the functionalization does…

Materials Science · Physics 2009-11-07 Jeremy Taylor , Mads Brandbyge , Kurt Stokbro

Inspired by cotunneling spectroscopy of spin-states in a single OPE5-based molecule, we investigate the prospects for electric control of magnetism in purely organic molecules contacted in a three-terminal geometry. Using the gate…

Mesoscale and Nanoscale Physics · Physics 2012-12-21 J. Fock , M. Leijnse , K. Jennum , A. S. Zyazin , J. Paaske , P. Hedegård , M. Brøndsted Nielsen , H. S. J. van der Zant

The single-molecule conductance of a 3-ring, conjugated azomethine was studied using the mechanically controlled breakjunction technique. Charge transport properties are found to be comparable to vinyl-based analogues; findings are…

Mesoscale and Nanoscale Physics · Physics 2016-08-18 Max Koole , Riccardo Frisenda , Michiel L. Petrus , Mickael L. Perrin , Herre S. J. van der Zant , Theo J. Dingemans

As the dimensions of a conductor approach the nano-scale, quantum effects will begin to dominate its behavior. This entails the exciting possibility of controlling the conductance of a device by direct manipulation of the electron wave…

Recently, rectifying direction inversion has been observed in dipyrimidinyl-diphenyl (PMPH) diblock molecular wire [J. Am. Chem. Soc. (2005) 127, 10456], and a protonation mechanism was suggested to explain this interesting phenomena. In…

Materials Science · Physics 2008-12-14 Zhenyu Li
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