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Three one-body profiles that correspond to local fluctuations in energy, in entropy, and in particle number are used to describe the equilibrium properties of inhomogeneous classical many-body systems. Local fluctuations are obtained from…

Soft Condensed Matter · Physics 2026-04-08 Tobias Eckert , Nex C. X. Stuhlmüller , Florian Sammüller , Matthias Schmidt

The phase behavior of colloidal particles embedded in a binary fluid is influenced by wetting layers surrounding each particle. The free energy of the fluid film depends on its morphology, i.e., on size, shape and connectivity. Under rather…

Soft Condensed Matter · Physics 2007-05-23 Uwe Brodatzki , Klaus Mecke

In numerical simulations of multiphase flow and transport in fractured porous media, the estimation of the hydrocarbon recovery requires accurately predicting the capillary-driven imbibition rate of the wetting phase initially present in…

Computational Engineering, Finance, and Science · Computer Science 2020-07-21 Ammar Alali , Francois Hamon , Bradley Mallison , Hamdi Tchelepi

In this article we calculate the surface phase diagram of a two-dimensional hard-rod fluid confined between two hard lines. In a first stage we study the semi-infinite system consisting of an isotropic fluid in contact with a single hard…

Statistical Mechanics · Physics 2009-11-13 Yuri Martinez-Raton

The instability of the interface between a dielectric and a conducting liquid, excited by a spatially homogeneous interface-normal time-periodic electric field, is studied based on experiments and theory. Special attention is paid to the…

Fluid Dynamics · Physics 2022-04-06 S. Dehe , M. Hartmann , A. Bandopadhyay , S. Hardt

Controlling interfaces of phase separating fluid mixtures is key to creating diverse functional soft materials. Traditionally, this is accomplished with surface-modifying chemical agents. Using experiment and theory, we study how mechanical…

Soft Condensed Matter · Physics 2022-08-15 Raymond Adkins , Itamar Kolvin , Zhihong You , Sven Witthaus , M. Cristina Marchetti , Zvonimir Dogic

We use molecular simulations to demonstrate the connection between transverse water-water correlations and wetting phenomena for a range of hydrophobic to hydrophilic solid surfaces.Near superhydrophobic surfaces, the correlations are long…

Soft Condensed Matter · Physics 2014-09-10 Rahul Godawat , Sumanth N. Jamadagni , Vasudevan Venkateshwaran , Shekhar Garde

We present the hydrodynamic theory of coherent collective motion ("flocking") at a solid-liquid interface, and many of its predictions for experiment. We find that such systems are stable, and have long-range orientational order, over a…

Soft Condensed Matter · Physics 2022-01-05 Niladri Sarkar , Abhik Basu , John Toner

We report on the onset of fluid entrainment when a contact line is forced to advance over a dry solid of arbitrary wettability. We show that entrainment occurs at a critical advancing speed beyond which the balance between capillary,…

Soft Condensed Matter · Physics 2015-06-16 Rodrigo Ledesma-Aguilar , Aurora Hernández-Machado , Ignacio Pagonabarraga

The influence of ions on the bulk phase behavior of binary liquid mixtures acting as their solvents and on the corresponding interfacial structures close to a planar wall is investigated by means of density functional theory based on local…

Soft Condensed Matter · Physics 2012-07-18 Markus Bier , Andrea Gambassi , S. Dietrich

We experimentally study gravity-capillary wave turbulence on the interface between two immiscible fluids of close density with free upper surface. We locally measure the wave height at the interface between both fluids by means of a highly…

Fluid Dynamics · Physics 2017-03-08 Bruno Issenmann , Claude Laroche , Eric Falcon

A continuum-space bead-spring model is used to study the phase behavior of binary blends of homopolymers and the structure of the interface between the two immiscible phases. The structure of the interface is investigated as a function of…

Soft Condensed Matter · Physics 2009-10-30 Martin-D. Lacasse , Gary S. Grest , Alex J. Levine

We determine the capillary attraction and equilibrium configurations of particles trapped at a liquid-fluid interface due to the pinning of their contact-line. We calculate analytically the asymptotic interaction energy between two…

Soft Condensed Matter · Physics 2009-11-07 J. -B. Fournier , P. Galatola

We study flows and interface deformations produced by the scattering of a laser beam propagating through non-absorbing turbid fluids. Light scattering produces a force density resulting from the transfer of linear momentum from the laser to…

Soft Condensed Matter · Physics 2011-11-30 Hamza Chraibi , Régis Wunenburger , Didier Lasseux , Julien Petit , Jean-Pierre Delville

The crystal-melt interfaces of a binary hard-sphere fluid mixture in coexistence with a single-component hard-sphere crystal is investigated using molecular-dynamics simulation. In the system under study, the fluid phase consists of a…

Chemical Physics · Physics 2009-11-07 Rachel Sibug-Aga , Brian B. Laird

In this paper a generalization of the Cahn-Hilliard theory of binary liquids is presented for multi-component incompressible liquid mixtures. First, a thermodynamically consistent convection-diffusion type dynamics is derived on the basis…

Materials Science · Physics 2016-02-03 Gyula I. Toth , Mojdeh Zarifi , Bjorn Kvamme

The propagation and roughening of a liquid-gas interface moving through a disordered medium under the influence of capillary forces is considered. The system is described by a phase-field model with conserved dynamics and spatial disorder…

Statistical Mechanics · Physics 2009-10-31 M. Dube , M. Rost , K. Elder , M. Alava , S. Majaniemi , T. Ala-Nissila

The dynamic conformal transformation method has been generalized for the first time to numerically simulate the capillary wave turbulence of a liquid surface in the plane symmetric anisotropic geometry. The model is strongly nonlinear and…

Fluid Dynamics · Physics 2024-03-20 Evgeny Kochurin

We use hard-sphere generalized hydrodynamic equations to discuss the extended hydrodynamic modes of a binary mixture. The theory presented here is analytic and it provides us with a simple description of the collective excitations of a…

Soft Condensed Matter · Physics 2009-11-11 M. Cristina Marchetti , Supurna Sinha

The structure of polar liquids and electrolytic solutions, such as water and aqueous electrolytes, at interfaces underlies numerous phenomena in physics, chemistry, biology, and engineering. In this work, we develop a continuum theory that…

Soft Condensed Matter · Physics 2022-07-13 J. Pedro de Souza , Alexei A. Kornyshev , Martin Z. Bazant