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The transient behaviour of highly concentrated colloidal liquids and dynamically arrested states (glasses) under time-dependent shear is reviewed. This includes both theoretical and experimental studies and comprises the macroscopic…

Soft Condensed Matter · Physics 2013-09-03 K J Mutch , M Laurati , C P Amann , M Fuchs , S U Egelhaaf

Using a dynamical density functional theory we analyze the density profile of a colloidal liquid near a wall under shear flow. Due to the symmetries of the system considered, the naive application of dynamical density functional theory does…

Soft Condensed Matter · Physics 2015-05-20 J. M. Brader , M. Krüger

Flow behavior of a single-component yield stress fluid is addressed on the hydrodynamic level. A basic ingredient of the model is a coupling between fluctuations of density and velocity gradient via a Herschel-Bulkley-type constitutive…

Soft Condensed Matter · Physics 2018-06-07 Markus Gross , Fathollah Varnik

We present here a microscopic study of the effect of shear on a dense purely repulsive colloidal suspension. We use Multispeckle Diffusing Wave Spectroscopy to monitor the transient motions of colloidal particles after being submitted to an…

Soft Condensed Matter · Physics 2007-05-23 V. Viasnoff , S. Jurine , F. Lequeux

We compute the rheological properties of inelastic hard spheres in steady shear flow for general shear rates and densities. Starting from the microscopic dynamics we generalise the Integration Through Transients (\textsc{itt}) formalism to…

Soft Condensed Matter · Physics 2020-03-03 W. Till Kranz , Fabian Frahsa , Annette Zippelius , Matthias Fuchs , Matthias Sperl

The binary hard-sphere mixture is one of the simplest representations of a many-body system with competing time and length scales. This model is relevant to fundamentally understand both the structural and dynamical properties of materials,…

Vapour deposition can directly produce ultrastable glasses, which are similar to conventional glasses aged over thousands of years. The highly mobile surface layer is believed to accelerate the ageing process of vapour-deposited glasses,…

Soft Condensed Matter · Physics 2016-10-20 Xin Cao , Huijun Zhang , Yilong Han

We study concentrated colloidal suspensions, a model system which has a glass transition. Samples in the glassy state show aging, in that the motion of the colloidal particles slows as the sample ages from an initial state. We study the…

Soft Condensed Matter · Physics 2007-05-23 Gianguido C. Cianci , Rachel E. Courtland , Eric R. Weeks

We use confocal microscopy to study the aging of a bidisperse colloidal glass near rough and smooth boundaries. Near smooth boundaries, the particles form layers, and particle motion is dramatically slower near the boundary as compared to…

Soft Condensed Matter · Physics 2017-12-14 Cong Cao , Xinru Huang , Connie B. Roth , Eric R. Weeks

The smooth emergence of shear elasticity is an hallmark of the liquid to glass transition. In a liquid, viscous stresses arise from local structural rearrangements. In the solid, Eshelby has shown that stresses around an inclusion decay as…

Soft Condensed Matter · Physics 2024-11-08 Niklas Grimm , Martin von Bischopinck , Andreas Zumbusch , Matthias Fuchs

We study colloidal particle dynamics of a model glass system using confocal and fluorescence microscopy as the sample evolves from a hard-sphere glass to a liquid with attractive interparticle interactions. The transition from hard-sphere…

Soft Condensed Matter · Physics 2015-05-13 Andrzej Latka , Yilong Han , Ahmed M. Alsayed , Andrew B. Schofield , A. G. Yodh , Piotr Habdas

Dense suspensions of model hard-sphere-like colloids, with different particle sizes, are examined experimentally in the glass state, under shear and extensional rheology. Under steady shear flow we detect Discontinuous Shear Thickening…

Glass-like materials are nonequilibrium systems where the relaxation time may exceed reasonable time scales of observations. In the present paper a dynamic percolation model is introduced in order to explain the principal properties of…

Condensed Matter · Physics 2007-05-23 A. Vazquez , O. Sotolongo-Costa

The history dependence of the glasses formed from flow-melted steady states by a sudden cessation of the shear rate $\dot\gamma$ is studied in colloidal suspensions, by molecular dynamics simulations, and mode-coupling theory. In an ideal…

Employing a recently developed dynamical density functional theory we study the response of a colloidal sediment above a wall to shear, demonstrating the time dependent changes of the density distribution and its center-of-mass after…

Soft Condensed Matter · Physics 2015-05-30 Matthias Krüger , Joseph M. Brader

Glass-forming materials are characterized by an intermittent motion at the microscopic scale. Particles spend most of their time rattling within the cages formed by their neighbors, and seldom jump to a different cage. In molecular glass…

Soft Condensed Matter · Physics 2014-12-03 Raffaele Pastore , Massimo Pica Ciamarra , Giuseppe Pesce , Antonio Sasso

The flow curves, viz. the curves of stationary stress under steady shearing, are obtained close to the glass transition in dense colloidal dispersions using asymptotic expansions in a schematic model of mode coupling theory. The shear…

Soft Condensed Matter · Physics 2010-09-15 D. Hajnal , M. Fuchs

We study the responses of fluid-immersed soft hydrogel spheres that are sheared under controlled volume fractions. Slippery, deformable particles along with the density-matched interstitial fluid are sandwiched between two opposing rough…

Soft Condensed Matter · Physics 2020-07-22 J. -C. Tsai , M. -R. Chou , P. -C. Huang , H. -T. Fei

Quasi-two-dimensional (quasi-2D) colloidal hard-sphere suspensions confined in a slit geometry are widely used as two dimensional (2D) model systems in experiments that probe the glassy relaxation dynamics of 2D systems. However, the…

Soft Condensed Matter · Physics 2023-02-15 Jiting Tian , Walter Kob , Jean-Louis Barrat

We use confocal microscopy and time-resolved light scattering to investigate plasticity in a col- loidal polycrystal, following the evolution of the network of grain boundaries as the sample is submitted to thousands of shear deformation…

Soft Condensed Matter · Physics 2014-08-28 Elisa Tamborini , Luca Cipelletti , Laurence Ramos