Related papers: Superconductor made by electrolyzed and oxidized w…
We report results of specific heat measurements on polycrystalline samples of the layered superconductor, Na(0.3)CoO(2).1.3H(2)O. The electronic contribution to the specific heat, gamma, is found to be 12.2 mJ/mol-K2. The feature at the…
Various samples of sodium cobalt oxyhydrate with relatively large amounts of Na$^{+}$ ions were synthesized by a modified soft-chemical process in which a NaOH aqueous solution was added in the final step of the procedure. From these…
Water splitting allows the storage of solar energy into chemical bonds (H2+O2) and will help to implement the urgently needed replacement of limited available fossil fuels. Particularly in neutral environment electrochemically initiated…
Another phase transition that is probably of first order is found in the beta-pyrochlore oxide superconductor KOs2O6 with a superconducting transition temperature Tc of 9.6 K. It takes place at Tp=7.5 K in the superconducting state in a…
We have successfully grown single crystalline NaFeAs with cobalt or phosphor doping. Bulk superconductivity occurs in NaFe$_{0.95}$Co$_{0.05}$As at 19 K while much higher transition temperature is observed in NaFeAs$_{0.8}$P$_{0.2}$, in…
Pressure can tune material's electronic properties and control its quantum state, making some systems present disconnected superconducting region as observed in iron chalcogenides and heavy fermion CeCu2Si2. For CaC6 superconductor (Tc of…
Although the microscopic origin of the superconductivity in high Tc copper oxides remains the subject of active inquiry, several of their electronic characteristics are well established as universal to all the known materials, forming the…
We report 59Co nuclear quadrupole resonance (NQR) studies of bilayer water intercalated sodium cobalt oxides NaxCoO2.yH2O (BLH) with the superconducting transition temperatures, 2 K < T_c <= 4.6 K, as well as a magnetic BLH sample without…
A new layered Ti-based pnictide oxide superconductor, Ba1-xNaxTi2Sb2O (0.0 <= x <= 0.33), is reported. X-ray studies reveal it crystallizes in the tetragonal CeCr2Si2C structure. The undoped parent compound, BaTi2Sb2O (P4/mmm;…
The observation of superconductivity in the layered transition metal oxide NaxCoO2 y H2O (K. Takada et al., Nature 422, 53 (2003)) has caused a tremendous upsurge of scientific interest due to its similarities and its differences to the…
Superconductivity can be understood in terms of a phase transition from an uncorrelated electron gas to a condensate of Cooper pairs in which the relative phases of the constituent electrons are coherent over macroscopic length scales. The…
We report a ^{59}Co Knight shift measurement in a single crystal of the cobalt oxide superconductor Na_{x}CoO_2\cdot1.3H_2O (T_c=4.25 K). We find that the shift due to the spin susceptibility, K^s, is substantially large and anisotropic,…
In 2023, superconductivity in La$_3$Ni$_2$O$_7$ was discovered under high pressures above approximately 14 GPa. In addition to its high transition temperature ($T_{\mathrm{c}} \simeq 80$ K), the structural resemblance to…
Superconducting nanowires can be fabricated by decomposition of an organometallic gas using a focused beam of Ga ions. However, physical damage and unintentional doping often results from the exposure to the ion beam, motivating the search…
The nonstoichiometric NaxCoO2 system exhibits extraordinary physical properties that correlate with temperature and Na concentration in its layered lattice without evident long-range structure modification when conventional crystallographic…
Electrochemical CO2 reduction offers a method to use renewable electricity to convert CO2 into CO and other carbon-based chemical building blocks. While nearly all studies rely on a CO2 feed, we show herein that aqueous bicarbonate…
The roles of aliovalent Ca(II)-for-Y(III) substitution and high-pressure-oxygen annealing in the process of "superconducterizing" the Co-based layered copper oxide, CoSr2(Y1-xCax)Cu2O7+d (Co-1212), were investigated. The as-air-synthesized…
The transition to a green hydrogen economy demands robust, scalable, and sustainable anodes for alkaline water electrolysis operating at industrial current densities (>1 A/cm2). However, achieving high activity and long-term stability under…
Although hydrogen generation by water electrolysis is the cheapest of all other available sources, water splitting still occurs with sluggish kinetics. It is a challenging barrier for H2 production on a large scale. Moreover, research is…
Protonic ceramic fuel cells can be operated at low temperatures, but their performances relying on bulk ion transfer in solid electrolytes are usually limited by much lower proton conductivity than 0.1 S/cm below 600 {\deg}C. Herein,…