A new layered Ti-based pnictide oxide superconductor, Ba1-xNaxTi2Sb2O (0.0 <= x <= 0.33), is reported. X-ray studies reveal it crystallizes in the tetragonal CeCr2Si2C structure. The undoped parent compound, BaTi2Sb2O (P4/mmm; a=4.1196(1){\AA}; c=8.0951(2){\AA}), exhibits a CDW/SDW transition at 54K. Upon chemical doping with Na, the CDW/SDW transition is systematically suppressed and super-conductivity arises with the critical temperatures, Tc, increasing to 5.5 K. Bulk superconductivity is confirmed by resistivity, magnetic and heat capacity measurements. Like the high-Tc cuprates and the iron pnictides, superconductivity in BaTi2Sb2O arises from an ordered state. Similarities and differences to the cuprate and iron pnictide supercon-ductors are discussed.
@article{arxiv.1209.5447,
title = {Ba1-xNaxTi2Sb2O (0.0 <= x <= 0.33): A Layered Titanium-based Pnictide Oxide Superconductor},
author = {Phuong Doan and Melissa Gooch and Zhongjia Tang and Bernd Lorenz and Angela Möller and Joshua Tapp and Paul C. W. Chu and Arnold M. Guloy},
journal= {arXiv preprint arXiv:1209.5447},
year = {2013}
}