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The electronic shell structure in small metallic nanoclusters leads to high level degeneracy, which is strongly beneficial for the appearance of pair correlation. This results in a high value of Tc as well as in the appearance of a…

Superconductivity · Physics 2009-11-11 Y. N. Ovchinnikov , V. Z. Kresin

The presence of shell structure and the accompanying high level degeneracy leads to a strengthening of the pairing interaction in some metallic nanoclusters and ions. It is predicted that for some specific systems one can expect a large…

Superconductivity · Physics 2009-11-11 Y. N. Ovchinnikov , V. Z. Kresin

A unique property of metal nanoclusters is the "superatom" shell structure of their delocalized electrons. The electronic shell levels are highly degenerate and therefore represent sharp peaks in the density of states. This can enable…

Superconductivity · Physics 2015-12-17 Avik Halder , Vitaly V. Kresin

Electronic states in metallic nanoclusters form energy shells and degree of their filling depends on the number of delocalized electrons. In the region close to half-filling the cluster geometry oscillates between the prolate and oblate…

Superconductivity · Physics 2015-06-23 Vladimir Kresin , Yurii Ovchinnikov , Jacques Friedel

A unique property of size-resolved metal nanocluster particles is their "superatom"-like electronic shell structure. The shell levels are highly degenerate, and it has been predicted that this can enable exceptionally strong…

Superconductivity · Physics 2015-02-06 Avik Halder , Anthony Liang , Vitaly V. Kresin

Metallic nanoclusters displaying electronic shell structure exhibit the special feature of a correlation between their geometry and the number of delocalized electrons . Their shape evolution can be described as a quantum oscillation…

Atomic and Molecular Clusters · Physics 2008-04-04 Vladimir Kresin

Motivated by the recent observation of the shell effect in a nanoscale pure superconductor by Bose {\em et al} [Nat. Mat. {\bf 9}, 550 (2010)], we explore the possible shell-like effect in a strongly disordered superconductor as it is known…

Superconductivity · Physics 2013-11-19 Sanjib Ghosh , Sudhansu S. Mandal

The pair correlations in mesoscopic systems such as $nm$-size superconducting clusters and nuclei are studied at finite temperature for the canonical ensemble of fermions in model spaces with a fixed particle number: i) a degenerate…

Atomic and Molecular Clusters · Physics 2009-11-10 S. Frauendorf , N. K. Kuzmenko , V. M. Mikhajlov , J. Sheikh

The magnetic susceptibility of electrons confined to a spherical cavity or a circular billiard shows slow oscillations as a function of the number of electrons, which are a new manifestation of the Super Shell Structure found in the free…

Atomic and Molecular Clusters · Physics 2009-10-31 S. Frauendorf , V. M. Kolomietz , A. G. Magner , A. I. Sanzhur

Collective optical excitations, such as localized surface plasmons in metallic nanoparticles and Mie resonances in high-index dielectrics, play a central role in nanoscale light--matter interactions. When such optical modes interact with…

The existence of macroscopic shell structure of submicron metal clusters is known for several decades. Since the most studies provide theoretical analysis for clusters of spherical shape, the electron density inhomogeneities caused by shell…

Atomic and Molecular Clusters · Physics 2025-01-16 S. E. Kuratov , I. S. Galtsov , S. A. Dyachkov , S. Yu. Igashov

Electron-phonon relaxation in size-quantized systems may become inhibited when the spacing of discrete electron energy levels exceeds the magnitude of the phonon frequency. We show, however, that nanoclusters can support a fast nonradiative…

Atomic and Molecular Clusters · Physics 2007-05-23 Vitaly V. Kresin , Yu. N. Ovchinnikov

Exact calculations of collective excitations and charge/spin (pseudo)gaps in an ensemble of bipartite and nonbipartite clusters yield level crossing degeneracies, spin-charge separation, condensation and recombination of electron charge and…

Strongly Correlated Electrons · Physics 2009-11-13 A. N. Kocharian , G. W. Fernando , K. Palandage , J. W. Davenport

Motivated by recent experiments on Al nanoparticles, we have studied the effects of fixed electron number and small size in nanoscale superconductors, by applying the canonical BCS theory for the attractive Hubbard model in two and three…

Superconductivity · Physics 2009-10-31 K. Tanaka , F. Marsiglio

To understand the electronic shell- and supershell-structure in large metal clusters we have performed self-consistent calculations in the homogeneous, spherical jellium model for a variety of different materials. A scaling analysis of the…

Condensed Matter · Physics 2009-10-28 Erik Koch

Electron pairing and ferromagnetism in various cluster geometries are studied with emphasis on tetrahedron and square pyramid under variation of interaction strength, electron doping and temperature. These exact calculations of charge and…

Strongly Correlated Electrons · Physics 2008-04-08 A. N. Kocharian , G. W. Fernando , K. Palandage , J. W. Davenport

We report experiments on aluminum nanowires in ultra-high vacuum at room temperature that reveal a periodic spectrum of exceptionally stable structures. Two "magic" series of stable structures are observed: At low conductance, the formation…

Mesoscale and Nanoscale Physics · Physics 2007-06-11 A. I. Mares , D. F. Urban , J. Bürki , H. Grabert , C. A. Stafford , J. M. van Ruitenbeek

We present the results of self-consistent calculations of the electronic shell and supershell structure for clusters having up to 6000 valence electrons. The ionic background is described in terms of a homogeneous jellium. The calculations…

Condensed Matter · Physics 2009-10-28 Erik Koch , Olle Gunnarsson

The quantum states of a system of particles in a finite spatial domain in general consist of a set of discrete energy eigenvalues; these are usually grouped into bunches of degenerate or close-lying levels, called shells. In fermionic…

Mesoscale and Nanoscale Physics · Physics 2022-09-21 A. I. Yanson , I. K. Yanson , J. M. van Ruitenbeek

We present results of density-functional calculations on the magnetic properties of Cr, Mn, Fe and Co nano-clusters (1 to 9 atoms large) supported on Cu(001) and Cu(111). The inter-atomic exchange coupling is found to depend on competing…

Materials Science · Physics 2015-05-14 Phivos Mavropoulos , Samir Lounis , Stefan Blügel
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