English

Correlation between the energy shell structure and geometry in metallic nanoclusters: quasi-resonance states, isotope effect

Atomic and Molecular Clusters 2008-04-04 v1

Abstract

Metallic nanoclusters displaying electronic shell structure exhibit the special feature of a correlation between their geometry and the number of delocalized electrons . Their shape evolution can be described as a quantum oscillation between quasi-resonant states (prolate and oblate configurations) whose amplitudes depend upon the degree of shell filling. The picture explains the evolution of absorption spectra and predicts a peculiar isotope effect .

Keywords

Cite

@article{arxiv.0804.0466,
  title  = {Correlation between the energy shell structure and geometry in metallic nanoclusters: quasi-resonance states, isotope effect},
  author = {Vladimir Kresin},
  journal= {arXiv preprint arXiv:0804.0466},
  year   = {2008}
}