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The effect of the collision term of the Boltzmann equation is discussed for the diagonal conductivity in the absence of magnetic field and the off-diagonal conductivity within the linear order of magnetic field. The consistency between the…

Superconductivity · Physics 2021-04-02 Osamu Narikiyo

We develop a rigorous theory of hard-sphere dynamics in the kinetic regime, away from thermal equilibrium. In the low density limit, the empirical density obeys a law of large numbers and the dynamics is governed by the Boltzmann equation.…

Analysis of PDEs · Mathematics 2020-05-20 Thierry Bodineau , Isabelle Gallagher , Laure Saint-Raymond , Sergio Simonella

Coupled systems in mesoscopic regime are of interest as charge fluctuation between the sub-systems will depend on electron-electron interactions and will play a dominant role in determining their thermodynamic properties. We study some…

Mesoscale and Nanoscale Physics · Physics 2009-09-29 P. Singha Deo , P. Koskinen , M. Manninen

Within a dipolar Poisson-Boltzmann theory including electrostatic correlations, we consider the effect of explicit solvent structure on solvent and ion partition confined to charged nanopores. We develop a relaxation scheme for the solution…

Soft Condensed Matter · Physics 2015-10-28 Sahin Buyukdagli

We derive an exact equation for density changes induced by a general external field that corrects the hydrostatic approximation where the local value of the field is adsorbed into a modified chemical potential. Using linear response theory…

Statistical Mechanics · Physics 2009-10-31 Kirill Katsov , John D. Weeks

The persistence length of a single, intrinsically rigid polyelectrolyte chain, above the Manning condensation threshold is investigated theoretically in presence of added salt. Using a loop expansion method, the partition function is…

Statistical Mechanics · Physics 2009-11-07 Gil Ariel , David Andelman

We propose a field-theoretic framework for ideal hydrodynamics of charged relativistic fluids formulated in terms of a complex scalar field defined on a spacelike hypersurface comoving with the fluid. In the normal phase, the dynamics of…

High Energy Physics - Theory · Physics 2026-03-18 Aleksander Głódkowski

We consider vacuum fluctuations of the quantum electromagnetic field in the presence of an infinite and perfectly conducting plate. We evaluate how the change of vacuum fluctuations due to the plate modifies the Casimir-Polder potential…

Quantum Physics · Physics 2009-11-13 S. Spagnolo , R. Passante , L. Rizzuto

We present a soft-potential-enhanced Poisson-Boltzmann (SPB) theory to efficiently capture ion distributions and electrostatic potential around rodlike charged macromolecules. The SPB model is calibrated with a coarse-grained particle-based…

Soft Condensed Matter · Physics 2022-06-07 Hossein Vahid , Alberto Scacchi , Xiang Yang , Tapio Ala-Nissila , Maria Sammalkorpi

We study the fluctuation of the Atlas model, where a unit drift is assigned to the lowest ranked particle among a semi-infinite ($ \mathbb{Z}_+ $-indexed) system of otherwise independent Brownian particles, initiated according to a Poisson…

Probability · Mathematics 2015-03-13 Amir Dembo , Li-Cheng Tsai

In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using mean-field approach accounting for solvent polarization and non-uniform size effect. Applying a…

Soft Condensed Matter · Physics 2022-02-11 Jun-Sik Sin

We study the electric double layer near a charged soft surface by using a mean-field approach including non-uniform size effect and solvent polarization. Based on a free energy model, electrostatic potential and number densities of water…

Soft Condensed Matter · Physics 2022-02-10 Jun-Sik Sin , Nam-Hyok Kim , Chung-Sik Sin

Surface electric (charge) noise influences spin defects due to fluctuation of the surface charge density and also the electrostatic potential at the crystal surface. Surprisingly, the two-point correlation function of both the charged…

Mesoscale and Nanoscale Physics · Physics 2025-04-22 Denis R. Candido , Michael E. Flatté

We investigate an extension of excited state mean-field theory in which the energy expression is augmented with density functional components in an effort to include the effects of weak electron correlations. The approach remains…

Chemical Physics · Physics 2020-02-05 Luning Zhao , Eric Neuscamman

We consider two charged semipermeable membranes, which bound bulk electrolyte solutions and are separated by a thin film of salt-free liquid. Small counter-ions permeate into the gap, which leads to a steric charge separation in the system.…

Soft Condensed Matter · Physics 2016-11-23 Salim R. Maduar , Olga I. Vinogradova

We present a simulation method to study electrolyte solutions in a dielectric slab geometry using a modified 3D Ewald summation. The method is fast and easy to implement, allowing us to rapidly resum an infinite series of image charges. In…

Soft Condensed Matter · Physics 2015-08-12 Alexandre P. dos Santos , Yan Levin

Ion partitioning between different compartments (\emph{e.g.} a porous material and a bulk solution reservoir), known as Donnan equilibrium, plays a fundamental role in various contexts such as energy, environment, or water treatment. The…

Chemical Physics · Physics 2026-02-10 Jeongmin Kim , Benjamin Rotenberg

The structure of dilute electrolyte solutions close to a surface carrying a spatially inhomogeneous surface charge distribution is investigated by means of classical density functional theory (DFT) within the approach of fundamental measure…

Soft Condensed Matter · Physics 2020-06-23 Maximilian Mußotter , Markus Bier , S. Dietrich

We present a novel microfield approach for studying the dependence of the orientational polarization of the water in aqueous electrolyte solutions upon the salt concentration and temperature. The model takes into account the orientation of…

Chemical Physics · Physics 2016-07-15 Nir Gavish , Keith Promislow

Similarly and highly charged plates in the presence of multivalent counter ions attract each other, leading to electrostatically bound states. Using Monte-Carlo simulations we obtain the inter-plate pressure in the global parameter space.…

Soft Condensed Matter · Physics 2007-05-23 Andre G. Moreira , Roland R. Netz