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We briefly discuss our recent field-theoretic study of polyelectrolyte complexation, which occurs in solutions of two oppositely charged polyelectrolytes. Charged systems require theoretical methods beyond the mean-field (or self-consistent…

Soft Condensed Matter · Physics 2015-05-13 Yuri O. Popov , Jonghoon Lee , Glenn H. Fredrickson

We develop a model free energy from an expansion that basically includes graphs without loops. From this calculation, we derive the temperature dependence of the density (or specific volume), the typical time scale of the…

Disordered Systems and Neural Networks · Physics 2016-10-28 Henrich Frielinghaus

We analyze the simplest problem of electrochemical relaxation in more than one dimension - the response of an uncharged, ideally polarizable metallic sphere (or cylinder) in a symmetric, binary electrolyte to a uniform electric field. In…

Materials Science · Physics 2009-11-11 Kevin T. Chu , Martin Z. Bazant

The structural relaxations of a dense, binary mixture of charged hard spheres are studied using the Mode Coupling Theory (MCT). Qualitative differences to non--ionic systems are shown to result from the long--range Coulomb interaction and…

Condensed Matter · Physics 2007-05-23 Matthias Fuchs

We investigate the effect of adsorption-desorption phenomenon of ions in an asymmetric electrolytic cell at open circuit conditions. Our approach is based on the Poisson-Nernst-Planck theory for electrolytes and the kinetic model of…

Chemical Physics · Physics 2017-12-06 S. Bousiadi , I. Lelidis

Quantum fluctuations, through quantum corrections, have the potential to lead to irreversibility in quantum field theory. We consider the virtual ``charge" distribution generated by quantum corrections in the leading log, short range…

High Energy Physics - Theory · Physics 2007-05-23 J. Perez-Mercader

We propose a formalism to take account of the correction of the spatial fluctuations to the local self-energy obtained by the dynamical mean-field approximation. For this purpose, the approximate dynamical susceptibility in the framework of…

Strongly Correlated Electrons · Physics 2009-11-11 Hiroaki Kusunose

The classical (i.e. non-quantum) equilibrium statistical mechanics of a Coulomb fluid living on a pseudosphere (an infinite surface of constant negative curvature) is considered. The Coulomb fluid occupies a large disk communicating with a…

Statistical Mechanics · Physics 2009-11-10 B. Jancovici , G. Téllez

Uncompensated charges do not occur in Nature and any local charge should be a result of charge separation. Dissociable chemical groups at interfaces in contact with ions in solution, whose chemical equilibrium depends both on short-range…

Soft Condensed Matter · Physics 2019-02-21 Yael Avni , David Andelman , Rudolf Podgornik

We develop a stochastic model for the charge fluctuations on a microscopic dust particle resting on a surface exposed to plasma. We find in steady state that the fluctuations are normally distributed with a standard deviation that is…

Plasma Physics · Physics 2015-05-27 T. E. Sheridan , A. Hayes

We study the spontaneous charging and the crystallization of spherical micron-sized water-droplets dispersed in oil by numerically solving, within a Poisson-Boltzmann theory in the geometry of a spherical cell, for the density profiles of…

Soft Condensed Matter · Physics 2013-06-06 Joost de Graaf , Jos Zwanikken , Markus Bier , Arjen Baarsma , Yasha Oloumi , Mischa Spelt , Rene van Roij

We develop a field theory formalism for the disordered interacting electron liquid in the dynamical Keldysh formulation. This formalism is an alternative to the previously used replica technique. In addition it naturally allows for the…

Disordered Systems and Neural Networks · Physics 2009-10-31 Alex Kamenev , Anton Andreev

Recent experimental results suggest that a particular hydrodynamic theory describes charge fluctuations at long wavelengths in the square-lattice Hubbard model. Due to the continuity equation, the correlation functions for the charge and…

Strongly Correlated Electrons · Physics 2025-02-05 J. Vucicevic , S. Predin , M. Ferrero

We study the fluctuations and correlations of conserved charges, i.e. the baryon number, electric charge and the strangeness at finite temperature and nonzero baryon chemical potential with an effective model. The fluctuations are…

High Energy Physics - Phenomenology · Physics 2010-10-27 Wei-jie Fu , Yue-liang Wu

In small systems where relevant energies are comparable to thermal agitation, fluctuations are of the order of average values. In systems in thermodynamical equilibrium, the variance of these fluctuations can be related to the dissipation…

Statistical Mechanics · Physics 2007-05-23 Nicolas Garnier , Ciliberto Sergio

We investigate active electrolytes within the mean-field level of description. The focus is on how the double-layer structure of passive, thermalized charges is affected by active dynamics of all constituting ions. One feature of active…

Soft Condensed Matter · Physics 2018-05-23 Derek Frydel , Rudolf Podgornik

Dispersion forces between neutral material bodies are due to fluctuations of the polarization of the bodies. For bodies in equilibrium these forces are often referred to as Casimir-Lifshitz forces. For bodies in relative motion, in addition…

Quantum Physics · Physics 2022-09-12 Iver Brevik , Boris Shapiro , Mário Silveirinha

In this work we show how to calculate the equilibrium and non-equilibrium charge fluctuations in a gated normal mesoscopic conductor which is attached to one normal lead and one superconducting lead. We then consider an example where the…

Superconductivity · Physics 2009-10-31 Andrew M. Martin , Thomas Gramespacher , Markus Buttiker

There are good indications that fundamental physics gives rise to a modified space-momentum uncertainty relation that implies the existence of a minimum length scale. We implement this idea in the scalar field theory that describes density…

High Energy Physics - Theory · Physics 2010-04-05 S. F. Hassan , Martin S. Sloth

Conserved-charge densities are very special observables in quantum many-body systems as, by construction, they encode information about the dynamics. Therefore, their evolution is expected to be of much simpler interpretation than that of…

Statistical Mechanics · Physics 2024-05-30 Bruno Bertini , Katja Klobas , Mario Collura , Pasquale Calabrese , Colin Rylands
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