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From magnetic susceptibility, dielectric permittivity, electric polarization and specific heat measurements, we discover spin-induced ferroelectricity and magnetoelectric coupling in Mn3TeO6 and observe two successive magnetic transitions…

Materials Science · Physics 2015-12-01 L. Zhao , Z. Hu , C. Y. Kuo , T. -W. Pi , M. -K. Wu , L. H. Tjeng , A. C. Komarek

Two novel room-temperature phase transitions are observed, via synchrotron x-ray diffraction and Raman spectroscopy, in the Pb(Zr0.52Ti0.48)O3 alloy under hydrostatic pressures up to 16 GPa. A monoclinic (M)-to-rhombohedral (R1) phase…

Condensed Matter · Physics 2009-11-10 A. Sani , B. Noheda , I. A. Kornev , L. Bellaiche , P. Bouvier , J. Kreisel

Identification of novel multiferroic materials with high-ordering temperatures remains at the forefront of condensed matter physics research. In this regard, the antiferromagnetic RCrO$_3$ compounds (like GdCrO$_3$) constitute a promising…

We have investigated multiple caloric effects in multiferroic Y2CoMnO6. Polycrystalline sample prepared by solid state method has shown a ferromagnetic Curie temperature 75 K with second order phase transition; a maximum magneto entropy…

Materials Science · Physics 2014-10-14 J. Krishna Murthy , A. Venimadhav

The controversy regarding the ferroelectric behavior of hexagonal InMnO$_3$ is resolved by using a combination of x-ray diffraction (XRD), piezoresponse force microscopy (PFM), second harmonic generation (SHG), and density functional theory…

Materials Science · Physics 2013-05-30 Yu Kumagai , Alexei A. Belik , Martin Lilienblum , Naëmi Leo , Manfred Fiebig , Nicola A. Spaldin

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

We used inelastic neutron scattering to show that well below its N\'{e}el temperature, $T_{\rm N}$, the two-dimensional (2D) XY nearly-triangular antiferromagnet YMnO$_{3}$ has a prominent {\it central peak} associated with 2D…

Materials Science · Physics 2009-11-10 T. J. Sato , S. -H. Lee , T. Katsufuji , M. Masaki , S. Park , J. R. D. Copley , H. Takagi

The coexistence of multiple ferroic orders, i.e. multiferroicity, is a scarce property to be found in materials. Historically, this state has been found mainly in 3-dimensional complex oxides, but so far this state has still been elusive…

The intermediate valence compound YbAl$_3$ is known to undergo a hybridization process between itinerant and localized electrons. The resulting heavy Fermi liquid remains non-magnetic and non-superconducting. A microscopic understanding of…

Strongly Correlated Electrons · Physics 2014-11-27 W. K. Park , S. M. Narasiwodeyar , M. Dwyer , P. C. Canfield , L. H. Greene

The limited operational range of phase transition-based luminescence thermometers necessitates the exploration of new host materials exhibiting first-order structural phase transitions to broaden the applicability of this approach.…

Materials Science · Physics 2025-04-03 M. Tahir Abbas , M. Szymczak , V. Kinzhybalo , D. Szymanski , M. Drozd , L. Marciniak

Ferroelectric films usually have phase states and physical properties very different from those of bulk ferroelectrics. Here we propose free-standing ferroelectric-elastic multilayers as a bridge between these two material systems. Using a…

Materials Science · Physics 2011-10-18 S. Prokhorenko , N. A. Pertsev

Piezoelectric and ferroelectric ceramics with a high Curie temperature (Tc) have attracted a growing attention owning to their applications under severe environments. In this work, phase structure, dielectric, ferroelectric and…

BiMnO3 (BMO), ferromagnetic (FM) below Tc = 100 K, was believed to be also ferroelectric (FE) due to a non-centro-symmetric C2 structure, until diffraction data indicated that its space group is the centro-symmetric C2/c. Here we present…

Strongly Correlated Electrons · Physics 2016-02-12 W. S. Mohamed , A. Nucara , G. Calestani , F. Mezzadri , E. Gilioli , F. Capitani , P. Postorino , P. Calvani

High real-space-resolution atomic pair distribution functions of La_(1-x)Ca_(x)MnO_3 (x=0.12, 0.25 and 0.33) have been measured using high-energy x-ray powder diffraction to study the size and shape of the MnO_6 octahedron as a function of…

Materials Science · Physics 2009-10-31 S. J. L. Billinge , Th. Proffen , V. Petkov , J. L. Sarrao , S. Kycia

The interaction of coexisting structural instabilities in multiferroic materials gives rise to intriguing coupling phenomena and extraordinarily rich phase diagrams, both in bulk materials and strained thin films. Here we investigate the…

We have measured the photoemission spectra of Nd$_{1-x}$Sm$_{x}$NiO$_{3}$, where the metal-insulator transition and the N\'{e}el ordering occur at the same temperature for $x \lesssim 0.4$ and the metal-insulator transition temperature…

Strongly Correlated Electrons · Physics 2009-11-07 K. Okazaki , T. Mizokawa , A. Fujimori , E. V. Sampathkumaran , M. J. Martinez-Lope , J. A. Alonso

Iron-pnictides Ca(Fe1-xRhx)2As2 (x = 0, 0.035, and 0.19) were studied across the tetragonal-orthorhombic and uncollapsed to collapsed tetragonal phase transitions using Raman spectroscopy. The effect of the phase separation was observed in…

Superconductivity · Physics 2023-08-21 V. P. Gnezdilov , A. Yu. Glamazda , P. Lemmens , K. Kudo , M. Nohara

LiCu_2O_2 single crystals were studied in the temperature range 300-1100 K by means of heating-cooling curves of differential thermal analysis (DTA), thermogravimetry (TG), X-ray powder diffraction and electrical measurements. A reversible…

Materials Science · Physics 2013-09-19 S. A. Ivanov , A. A. Bush , K. E. Kamentsev , E. A. Tishchenko , M. Ottosson , R. Mathieu , P. Nordblad

The perovskite (1-x)YMnO$_3$-xBiFeO$_3$ binary system is very promising because of its multiferroic end members. Nanocrystalline phases have been recently obtained by mechanosynthesis across the system, and the perovskite structural…

We present direct evidence of above room temperature magneto-electricity in single-phase Li0.05Ti0.02Ni0.93O with above-ambient antiferromagnetic ordering. Temperature-hysteresis in warming/cooling heat-flow thermograms establishes a…

Materials Science · Physics 2015-09-15 Jitender Kumar , Pankaj K. Pandey , A. M. Awasthi