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A first-principles-derived approach is developed to study the effects of uncompensated depolarizing electric fields on the properties of Pb(Zr,Ti)O$_3$ ultrathin films for different mechanical boundary conditions. A rich variety of…

Materials Science · Physics 2009-11-10 Igor Kornev , Huaxiang Fu , L. Bellaiche

The boundary conditions, customarily used in the Landau-type approach to ferroelectric thin films and nanostructures, have to be modified to take into account that a surface of a ferroelectric (FE) is a defect of the ``field'' type. The…

Materials Science · Physics 2009-11-10 A. M. Bratkovsky , A. P. Levanyuk

The spectacular metal-to-insulator transition of V2O3 can be progressively suppressed in thin film samples. Evidence for phase separation was observed using microbridges as a mesoscopic probe of transport properties where the same film…

Materials Science · Physics 2009-11-13 C. Grygiel , A. Pautrat , W. C. Sheets , W. Prellier , B. Mercey , L. Mechin

The electric coupling between surface ions and bulk ferroelectricity gives rise to a continuum of mixed states in ferroelectric thin films, exquisitely sensitive to temperature and external factors, such as applied voltage and oxygen…

Materials Science · Physics 2017-05-24 Anna N. Morozovska , Eugene A. Eliseev , Nicholas V. Morozovsky , Sergei V. Kalinin

All non-interacting two-dimensional electronic systems are expected to exhibit an insulating ground state. This conspicuous absence of the metallic phase has been challenged only in the case of low-disorder, low density, semiconducting…

A thermodynamic theory is developed for dense laminar domain structures in epitaxial ferrolectric films. It is found that, at some critical misfit strain between the film and substrate, the 90 degrees c/a/c/a domain structure becomes…

Materials Science · Physics 2009-10-31 N. A. Pertsev , V. G. Koukhar

Recent experimental results demonstrate that in thin films ferroelectricity persists down to film thickness of a few unit cells. This finding opens an avenue for novel electronic devices based on ultathin ferroelectrics, but also raises…

Materials Science · Physics 2015-06-25 Chun-Gang Duan , Renat F. Sabirianov , Wai-Ning Mei , Sitaram S. Jaswal , Evgeny Y. Tsymbal

We studied the phase diagram of thin ferroelectric films with incommensurate phases and semiconductor properties within the framework of Landau-Ginzburg-Devonshire theory. We performed both analytical calculations and phase-field modelling…

The equilibrium domain structure and its evolution under an electric field in ferroelectric bilayers and graded multilayers are considered. The equilibrium bilayer is self-poled and contains a single-domain and a polydomain (with 180…

Materials Science · Physics 2009-11-11 A. L. Roytburd , J. Slutsker

We theoretically explore mechanisms that can potentially give rise to the steady-state and transient negative capacitance in a uniaxial ferroelectric film stabilized by a dielectric layer. The analytical expressions for the steady-state…

Materials Science · Physics 2022-06-01 Eugene. A. Eliseev , Mykola E. Yelisieiev , Sergei V. Kalinin , Anna N. Morozovska

For over 70 years, ferroelectric materials have been remaining one of the central research topics for condensed matter physics and material science, the interest driven both by fundamental science and applications. However, ferroelectric…

Materials Science · Physics 2016-12-28 Sergei V. Kalinin , Yunseok Kim , Dillon Fong , Anna Morozovska

The structural evolution of a polydomain ferroelectric Pb(Zr0.2Ti0.8)O3 film was studied by temperature dependent X-ray diffraction. Two critical temperatures were evidenced: T*=740K, corresponding to a change in the domain structure…

In spite of being highly relevant for the development of a new generation of information storage devices, not many single-phase materials displaying magnetic and ferroelectric orders above room temperature are known. Moreover, these…

Phase fluctuations in finite thickness layered superconducting films are studied theoretically. The model consists of a set of layers, coupled to each other via a gradient-like term in the phase-only action. It is shown that the effective…

Disordered Systems and Neural Networks · Physics 2010-12-23 Y. Dubi , R. R. Biswas , A. V. Balatsky

We consider phase separated states in magnetic oxides (MO) thin films. We show that these states have a non-zero electric polarization. Moreover, the polarization is intimately related to a spatial distribution of magnetization in the film.…

Strongly Correlated Electrons · Physics 2019-10-09 O. G. Udalov , I. S. Beloborodov

Magnetic materials hosting stable topological spin textures have demonstrated energy efficiency and potential as information carriers in novel logic and memory devices, offering an alternative to magnetic tunnel junction technology. While…

Mesoscale and Nanoscale Physics · Physics 2025-09-18 Jacob Mankenberg , Artem Abanov

Finite size effects in ferroelectric thin films have been probed in a series of epitaxial perovskite c-axis oriented PbTiO3 films grown on thin La0.67Sr0.33MnO3 epitaxial electrodes. The film thickness ranges from 480 down to 28 A (7 unit…

The existence of ferroelectricity in {$\mathrm{BiMnO}_3$} has been a long-standing question for both experimentalists and theorists. In addition to a highly distorted bulk structure, the ionic crystal planes cause a large roughness in thin…

Materials Science · Physics 2017-04-11 Yun-Peng Wang , J. N. Fry , Hai-Ping Cheng

General features of finite size effects in the ferroelectric-semiconductor film under open-circuited electric boundary conditions are analyzed using Landau-Ginzburg-Devonshire theory and continuum media electrostatics. The temperature…

Materials Science · Physics 2015-06-19 Eugene A. Eliseev , Sergei V. Kalinin , Anna N. Morozovska

In this paper we use a Ginzburg-Landau approach to show that a suitably strong electric field can drive a phase transition from a superconductor to a normal metal. The transition is induced by taking into account corrections to the…