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We measure the colloidal interaction between two silica microspheres in aqueous solution in the distance range from $0.2\,\mu$m to $0.5\,\mu$m with the help of optical tweezers. When employing a sample with a low salt concentration, the…

We use Molecular Dynamics simulations to study attractive interactions and the underlying ionic correlations between parallel like-charged rods in the absence of additional salt. For a generic bulk system of rods we identify a reduction of…

Soft Condensed Matter · Physics 2009-11-07 Markus Deserno , Axel Arnold , Christian Holm

The fundamental role of hydrophobic interactions in nature and technology has motivated decades long research aimed at measuring the distance-dependent hydrophobic force and identifying its origin. This quest has nevertheless proved more…

Soft Condensed Matter · Physics 2016-03-29 Itai Schlesinger , Uri Sivan

We propose a mean-field analytical model to account for the observed asymmetry in the ability to form long-range attraction by the negatively charged colloidal particles and not their equivalently charged positive counterpart. We conjecture…

Soft Condensed Matter · Physics 2009-11-13 William Kung , Monica Olvera de la Cruz

In solution, electrically like-charged particles can experience a strong and long-ranged attraction that leads to the formation of stable, slowly reorganizing clusters. The attractive force underpinning this spontaneous organization process…

Soft Condensed Matter · Physics 2026-01-14 Sida Wang , Angela Le , Rowan Walker-Gibbons , Madhavi Krishnan

It is known that in a water solution with multivalent counterions (Z-ions), two likely charged macroions can attract each other due to correlations of Z-ions adsorbed on their surfaces. This "correlation" attraction is short-ranged and…

Soft Condensed Matter · Physics 2009-11-10 Rui Zhang , B. I. Shklovskii

The bare Coulomb interaction between two like-charges is repulsive. When these charges are immersed in an electrolyte, the thermal fluctuations of the ions turn the bare Coulomb interaction into an effective interaction between the two…

Statistical Mechanics · Physics 2023-03-15 Gabriel Tellez

We predict the nature (attractive or repulsive) and range (exponentially screened or long-range power law) of the electrostatic interactions of oppositely charged and planar plates as a function of the salt concentration and surface charge…

Soft Condensed Matter · Physics 2012-01-31 Dan Ben-Yaakov , Yoram Burak , David Andelman , S. A. Safran

Interactions between silica surfaces across isopropanol solutions are measured with colloidal probe technique based on atomic force microscope. In particular, the influence of 1:1 electrolytes on the interactions between silica particles is…

Soft Condensed Matter · Physics 2020-07-01 Biljana Stojimirovic , Marco Galli , Gregor Trefalt

The behavior of polyelectrolytes between charged surfaces immersed in semi-dilute solutions is investigated theoretically. A continuum mean field approach is used for calculating numerically concentration profiles between two electrodes…

Soft Condensed Matter · Physics 2007-05-23 I. Borukhov , D. Andelman , H. Orland

Over the past few decades the experimental literature has consistently reported observations of attraction between like-charged colloidal particles and macromolecules in solution. Examples include nucleic acids and colloidal particles in…

Soft Condensed Matter · Physics 2020-04-22 Alzbeta Kubincova , Philippe H. Hunenberger , Madhavi Krishnan

The interaction force between likely charged particles/surfaces is usually repulsive due to the Coulomb interaction. However, the counterintuitive like-charge attraction in electrolytes has been frequently observed in experiments, which has…

Soft Condensed Matter · Physics 2016-11-08 Pei Liu , Manman Ma , Zhenli Xu

We examine the effective force between two nanometer scale solutes in water by Molecular Dynamics simulations. Macroscopic considerations predict a strong reduction of the hydrophobic attraction between solutes when the latter are charged.…

Statistical Mechanics · Physics 2009-11-10 J. Dzubiella , J. -P. Hansen

Long-ranged attractions across water between two surfaces that are randomly covered with (mobile) positive and negative charge domains have been attributed to induced correlation of the charges (positive lining up with negative) as the…

Soft Condensed Matter · Physics 2012-10-30 Gilad Silbert , Dan Ben-Yaakov , Yael Dror , Susan Perkin , Nir Kampf , Jacob Klein

Recent experiments and a series of subsequent theoretical studies suggest the occurrence of universal underscreening in highly concentrated electrolyte solutions. We performed a set of systematic Atomic Force Spectroscopy measurements for…

We show that hydrophilic ions present in a confined, near-critical aqueous mixture can lead to an attraction between like charge surfaces with opposing preferential adsorption of the two species of the mixture, even though the corresponding…

Soft Condensed Matter · Physics 2016-03-27 Faezeh Pousaneh , Alina Ciach , Anna Maciołek

Using video-microscopy imaging we demonstrate the existence of a short-ranged equilibrium attraction between heavy silica colloids diffusing on soft surfaces of cross-linked polymer gels. The inter-colloid potential can be tuned by changing…

Soft Condensed Matter · Physics 2013-05-29 Lorenzo Di Michele , Taiki Yanagishima , Anthony R. Brewer , Jurij Kotar , Seth Fraden , Erika Eiser

We present a simple model for the possible mechanism of appearance of attraction between like charged polyions inside a polyelectrolyte solution. The attraction is found to be short ranged, and exists only in presence of multivalent…

Soft Condensed Matter · Physics 2009-10-31 Jeferson J. Arenzon , Juergen F. Stilck , Yan Levin

The forces between colloidal particles at a decane-water interface, in the presence of low concentrations of a monovalent salt (NaCl) and of the surfactant sodium dodecylsulfate (SDS) in the aqueous subphase, have been studied using laser…

Soft Condensed Matter · Physics 2008-07-11 B. J. Park , J. P. Pantina , E. Furst , M. Oettel , S. Reynaert , J. Vermant

Effective attraction between like-charged walls mediated by counterions is studied using local molecular field (LMF) theory. Monte Carlo simulations of the "mimic system'' given by LMF theory, with short-ranged "Coulomb core" interactions…

Statistical Mechanics · Physics 2009-11-11 Jocelyn M. Rodgers , Charanbir Kaur , Yng-Gwei Chen , John D. Weeks
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