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In a recent article (cond-mat/0510119) it has been argued that the Jarzynski equation is violated for adiabatic stretching processes of a three dimensional rotor system. Here we want to show that the reasoning is not correct. Rather, the…

Statistical Mechanics · Physics 2007-05-23 Markus Bier

We perform a theoretical test of Jarzynski relation for an adiabatic stretching of an isotropic spring, which is an exactly solvable model. It turns out that Jarzynski relation does not hold even when the entire infinite momentum space of…

Statistical Mechanics · Physics 2007-05-23 Jaeyoung Sung

Recently, Jarzynski suggested a striking thermodynamic equation that relates free energy change of a system and work done on the system during arbitrary nonequilibrium processes, which has been believed to hold irrespective of detailed…

Statistical Mechanics · Physics 2016-08-31 Jaeyoung Sung

Jarzynski equality [Phys. Rev. E {\bf 56}, 5018 (1997)] is found to be valid with slight modefication for the transitions between nonequilibrium stationary states, as well as the one between equilibrium states. Also numerical results…

Statistical Mechanics · Physics 2007-05-23 Takahiro Hatano

The Jarzynski Equality relates the free energy difference between two equilibrium states of a system to the average of the work over all irreversible paths to go from one state to the other. We claim that the derivation of this equality is…

Statistical Mechanics · Physics 2009-11-10 E. G. D. Cohen , David Mauzerall

We prove the Jarzynski relation for general stochastic processes including non-Markovian systems with memory. The only requirement for our proof is the existence of a stationary state, therefore excluding non-ergodic systems. We then show…

Statistical Mechanics · Physics 2007-09-27 Thomas Speck , Udo Seifert

The validity of the Jarzynski equation for a very simple, exactly solvable quantum system is analyzed. The implications of two different definitions of work proposed in the literature are investigated. The first one derives from…

Statistical Mechanics · Physics 2009-11-11 A. Engel , R. Nolte

The interest in active matter stimulates the need to generalize thermodynamic description and relations to active matter systems, which are intrinsically out of equilibrium. One important example is the Jarzynski relation, which links the…

Statistical Mechanics · Physics 2023-05-31 Grzegorz Szamel

The Jarzynski equality relates the free energy difference between two equilibrium states to the fluctuating irreversible work afforded to switch between them. The prescribed fixed temperature for the equilibrium states implicitly constrains…

Statistical Mechanics · Physics 2020-09-03 Tobias Thalheim , Marco Braun , Gianmaria Falasco , Klaus Kroy , Frank Cichos

The condition for adiabatic approximation are of basic importance for the applications of the adiabatic theorem. The traditional quantitative condition was found to be necessary but not sufficient, but we do not know its physical meaning…

Quantum Physics · Physics 2011-02-02 Qian-Heng Duan , Ping-Xing Chen , Wei Wu

We present an analysis of the adiabatic approximation to understand when it applies, in view of the recent criticisms and studies for the validity of the adiabatic theorem. We point out that this approximation is just the leading order of a…

Quantum Physics · Physics 2012-01-31 Marco Frasca

The Jarzynski equality (JE) is analyzed in regard to its validity for both quasi-static transformations in the thermodynamic limit and Hamiltonian evolutions of the work protocol. In the first case, we show that the JE holds for isothermal…

Statistical Mechanics · Physics 2020-05-15 Amilcare Porporato , Salvatore Calabrese

The adiabatic theorem provides the basis for the adiabatic model of quantum computation. Recently the conditions required for the adiabatic theorem to hold have become a subject of some controversy. Here we show that the reported violations…

Quantum Physics · Physics 2013-05-29 M. H. S. Amin

Using methods of phenomenological non-equilibrium thermodynamics, the proof is performed that Jarzynski's equality is only valid in the reversible limit and that a conclusion to non-equilibrium inequalities concerning free energy and work…

Mathematical Physics · Physics 2013-07-02 Wolfgang Muschik

Conditions for the validity of the quantum adiabatic approximation are analyzed. For the case of linear Hamiltonians, a simple and general sufficient condition is derived, which is valid for arbitrary spectra and any kind of time variation.…

Quantum Physics · Physics 2015-05-13 V. I. Yukalov

The adiabatic theorem states that an initial eigenstate of a slowly varying Hamiltonian remains close to an instantaneous eigenstate of the Hamiltonian at a later time. We show that a perfunctory application of this statement is problematic…

Quantum Physics · Physics 2009-11-10 Karl-Peter Marzlin , Barry C. Sanders

Recently, the authors of Ref.1[arXiv:1004.3100] claimed that they have proven the traditional adiabatic condition is a necessary condition. Here, it is claimed that there are some mistakes and an artificial over-strong constraint in [1],…

Quantum Physics · Physics 2011-04-05 Meisheng Zhao , Jianda Wu

We show how Jarzynski relation can be exploited to analyze the nature of order-disorder and a bifurcation type dynamical transition in terms of a response function derived on the basis of work distribution over non-equilibrium paths between…

Chemical Physics · Physics 2015-06-05 Pulak Kumar Ghosh , Deb Shankar Ray

We consider a generalization of the Jarzynski relation to the case where the system interacts with a bath for which the temperature is not kept constant but can vary during the transformation. We suggest to use this relation as a…

Statistical Mechanics · Physics 2011-02-16 Christophe Chatelain

Jarzynski equality and related fluctuation theorems can be formulated for various setups. Such an equality was recently derived for nonunitary quantum evolutions described by unital quantum operations, i.e., for completely positive,…

Quantum Physics · Physics 2014-01-24 Alexey E. Rastegin , Karol Życzkowski
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