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We introduce an adiabatic perturbation theory for quantum systems with degenerate energy spectra. This perturbative series enables one to rigorously establish conditions for the validity of the adiabatic theorem of quantum mechanics for…

Quantum Physics · Physics 2015-05-18 Gustavo Rigolin , Gerardo Ortiz

We establish adiabatic theorems with and without spectral gap condition for general -- typically dissipative -- linear operators $A(t): D(A(t)) \subset X \to X$ with time-independent domains $D(A(t)) = D$ in some Banach space $X$. Compared…

Mathematical Physics · Physics 2019-06-26 Jochen Schmid

We extend Jarzynski's work relation and the second law of thermodynamics to a heat conducting system which is operated by an external agent. These extensions contain a new non equilibrium contribution expressed as the violation of the…

Statistical Mechanics · Physics 2012-09-25 Naoko Nakagawa

In this short communication, I give a very simple derivation of the Jarzynski equality, which allows to compute the free energy difference of a body, which is driven between two equilibrium states $A$ and $B$ by an external (time-dependent)…

Statistical Mechanics · Physics 2016-08-16 Frédéric Douarche

Recently, Marzlin and Sanders (2004) demonstrated an inconsistency when the adiabatic approximation was applied to specific, "inverse" time-evolving systems. Following that, Tong et al. (2005) showed that the widely used traditional…

Quantum Physics · Physics 2009-11-11 T. Vértesi , R. Englman

By stating the adiabatic theorem of quantum mechanics in a clear and rigorous way, we establish a necessary condition and a sufficient condition for its validity, where the latter is obtained employing our recently developed adiabatic…

Quantum Physics · Physics 2012-06-19 Gustavo Rigolin , Gerardo Ortiz

The connection between work and changes in the Hamiltonian for a system with a time-dependent Hamiltonian has recently been called into question, casting doubt on the usefulness of the Jarzynski equality for calculating free energy changes.…

Statistical Mechanics · Physics 2015-05-13 Eric N. Zimanyi , Robert J. Silbey

A consensus that questions the perfunctory use of the quantum adiabatic theorem has emerged since Marzlin and Sanders [Phys. Rev. Lett. {\bf 93}, 160408 (2004)] showed the existence of an inconsistency in the applicability of the theorem.…

Quantum Physics · Physics 2012-10-18 Juan Ortigoso

A gapped quantum system that is adiabatically perturbed remains approximately in its eigenstate after the evolution. We prove that, for constant gap, general quantum processes that approximately prepare the final eigenstate require a…

Quantum Physics · Physics 2010-04-02 S. Boixo , R. D. Somma

We analyze the validity of the adiabatic approximation, and in particular the reliability of what has been called the "standard criterion" for validity of this approximation. Recently, this criterion has been found to be insufficient. We…

Quantum Physics · Physics 2007-10-30 R. MacKenzie , A. Morin-Duchesne , H. Paquette , J. Pinel

The adiabatic theorem states that if we prepare a quantum system in one of the instantaneous eigenstates then the quantum number is an adiabatic invariant and the state at a later time is equivalent to the instantaneous eigenstate at that…

Quantum Physics · Physics 2007-05-23 A. K. Pati , A. K. Rajagopal

Numerous sufficient conditions for adiabaticity of the evolution of a driven quantum system have been known for quite a long time. In contrast, necessary adiabatic conditions are scarce. A practicable necessary condition well-suited for…

Quantum Physics · Physics 2020-02-18 Oleg Lychkovskiy

In a recent work, Jarzynski and Wojcik (2004 Phys. Rev. Lett. 92, 230602) have shown by using the properties of Hamiltonian dynamics and a statistical mechanical consideration that, through contact, heat exchange between two systems…

Statistical Mechanics · Physics 2008-05-29 Yuki Sughiyama , Sumiyoshi Abe

Marzlin and Sanders \cite{marzlin} have shown rigorously that the adiabatic approximation can be very inaccurate when applied to a Hamiltonian $H(t)$ that generates the evolution $U^{\dagger} (t)$ even if it gives an excellent approximation…

Quantum Physics · Physics 2007-05-23 Solomon Duki , H. Mathur , Onuttom Narayan

Fluctuation theorems impose constraints on possible work extraction probabilities in thermodynamical processes. These constraints are stronger than the usual second law, which is concerned only with average values. Here, we show that such…

Quantum Physics · Physics 2020-02-21 Paul Boes , Rodrigo Gallego , Nelly H. Y. Ng , Jens Eisert , Henrik Wilming

The adiabatic criterion, widely used in astronomical dynamics, is based on the harmonic oscillator. It asserts that the change in action under a slowly varying perturbation is exponentially small. Recent mathematical results precisely…

Astrophysics · Physics 2009-10-22 Martin D. Weinberg

When a thermally isolated system performs a driving process in the quasistatic regime, its variation of average energy is equal to its quasistatic work. Even though presenting this simple definition, few attempts have been made to describe…

Statistical Mechanics · Physics 2025-02-17 Pierre Nazé

We derive an adiabatic theorem for Markov chains using well known facts about mixing and relaxation times. We discuss the results in the context of the recent developments in adiabatic quantum computation.

Probability · Mathematics 2009-02-02 Yevgeniy Kovchegov

The Jarzynski equality equates the mean of the exponential of the negative of the work (per fixed temperature) done by a changing Hamiltonian on a system, initially in thermal equilibrium at that temperature, to the ratio of the final to…

High Energy Physics - Theory · Physics 2012-07-17 Don N. Page

The quantum adiabatic theorem states that if a quantum system starts in an eigenstate of the Hamiltonian, and this Hamiltonian varies sufficiently slowly, the system stays in this eigenstate. We investigate experimentally the conditions…

Quantum Physics · Physics 2008-01-03 Jiangfeng Du , Lingzhi Hu , Ya Wang , Jianda Wu , Meisheng Zhao , Dieter Suter